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Journal of Eastchina Normal University

Condensation Temperature of Uniform Interacting Bose Gases

Shu Liu

Published Jan 1, 2001• 0 citations
OpenAlex

Abstract

The Bose-Einstein condensation (BEC) of weakly interacting Bose gases has been realized recently in experiment. The condensation temperature of a uniform interacting Bose gas is an important thermodynamic quantity fot the BEC. In this paper, the pseudopotential method and grand canonical ensemble are used to investigate the condensation temperature of the uniform interacting Bose gas. The results show that, due to the interaction between particles, the shift of the condensation temperature is δT c/T c=-2.9an 1/3 , where a and n are the two-particle scattering length of S- wave and the particle number density, respectively.

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The Bose-Einstein condensation (BEC) of weakly interacting Bose gases has been realized recently in experiment. The condensation temperature of a uniform interacting Bose gas is an important thermodynamic quantity fot the BEC. In this paper, the pseudopotential method and grand canonical ensemble are used to investigate the condensation temperature of the uniform interacting Bose gas. The results show that, due to the interaction between particles, the shift of the condensation temperature is δT c/T c=-2.9an 1/3 , where a and n are the two-particle scattering length of S- wave and the particle number density, respectively.
A uniform dilute Bose system with repulsive interactions is studied in the grand canonical ensemble formalism. We present a parametric equation of state that holds true from high temperatures down to below the transition temperature, thus providing a scheme for exploring the quantum-statistical nature of the Bose-Einstein condensation transition in interacting gases. As an application, the interaction-induced shift of the transition temperature is derived to be $\mathrm{\ensuremath{\Delta}}{T}_{c}∕{T}_{c}^{0}=2.83{n}^{1∕3}a$, where nnn is the density and aaa is the SSS-wave scattering length.
We compute the critical temperature T_c of a weakly interacting uniform Bose gas in the canonical ensemble, extending the criterion of condensation provided by the counting statistics for the uniform ideal gas. Using ordinary perturbation theory, we find in first order (Tc−Tc0)/Tc0=−0.93aρ1/3(T_c-T_c^0)/T_c^0 = -0.93 aρ^{1/3}(Tc​−Tc0​)/Tc0​=−0.93aρ1/3, where T_c^0 is the transition temperature of the corresponding ideal Bose gas, a is the scattering length, and ρρρ is the particle number density.
We report on the computation of the shift of the Bose-Einstein condensation temperature for a homogenous weakly interacting Bose gas in leading order in the diluteness parameter a n^(1/3), where `a' is the scattering length and `n' is the particle density. The perturbative series, which is afflicted by infrared divergences, is resummed by means of variational perturbation theory. Using coefficients through seven loops, we arrive at Delta T_c/T_c = 1.27 +/- 0.11 a n^(1/3), which compares favorably with recent Monte-Carlo data.
Using a finite-temperature path integral Monte Carlo simulation (PIMC) method and finite-size scaling, we have investigated the interaction-induced shift of the phase-transition temperature for Bose-Einstein condensation of homogeneous weakly interacting Bose gases in three dimensions, which is given by a proposed analytical expression ${T}_{c}={T}_{c}^{0}{1+{c}_{1}a{n}^{1∕3}+[{c}_{2}^{\ensuremath{'}}\phantom{\rule{0.2em}{0ex}}\mathrm{ln}(a{n}^{1∕3})+{c}_{2}^{\ensuremath{''}}]{a}^{2}{n}^{2∕3}+\mathrm{O}({a}^{3}n)}$, where Tc0{T}_{c}^{0}Tc0​ is the critical temperature for an ideal gas, aaa is the sss-wave scattering length, and nnn is the number density. We have used smaller number densities and more time slices than in the previous PIMC simulations [Gruter et al., Phys. Rev. Lett. 79, 3549 (1997)] in order to understand the difference in the value of the coefficient c1{c}_{1}c1​ between their results and the (apparently) other reliable results in the literature. Our results show that ${({T}_{c}\ensuremath{-}{T}_{c}^{0})∕{T}_{c}^{0}}∕(a{n}^{1∕3})$ depends strongly on the interaction strength an1∕3a{n}^{1∕3}an1∕3 while the previous PIMC results are considerably flatter and smaller than our results. We obtain ${c}_{1}=1.32\ifmmode\pm\else\textpm\fi{}0.14$, in agreement with results from recent Monte Carlo methods of three-dimensional O(2) scalar ${\ensuremath{\phi}}^{4}$ field theory and variational perturbation theory.
We study the Bose-Einstein condensation phase transition in a weakly interacting gas through a perturbative analysis of finite systems. In both the grand canonical and the canonical ensembles, perturbation theory suffers from infrared divergences and cannot directly determine the transition temperature in the thermodynamic limit. However, in conjunction with finite-size scaling, perturbation theory provides a powerful calculation tool. Here we use this combination of perturbation theory and scaling to estimate a shift in the transition temperature in the canonical ensemble consistent with grand canonical calculations.
The shift of the Bose-Einstein condensation temperature for a homogenous weakly interacting Bose gas in leading order in the scattering length aaa is computed for given particle density nnn. Variational perturbation theory is used to resum the corresponding perturbative series for $\ensuremath{\Delta}⟨{\ensuremath{\phi}}^{2}⟩∕Nu$ in a classical three-dimensional scalar field theory with coupling uuu and where the physical case of N=2N=2N=2 field components is generalized to arbitrary NNN. Our results for N=1,2,4N=1,2,4N=1,2,4 are in agreement with recent Monte Carlo simulations; for N=2N=2N=2, we obtain $\ensuremath{\Delta}{T}_{c}∕{T}_{0}=(1.27\ifmmode\pm\else\textpm\fi{}0.11)a{n}^{1∕3}$. We use seven-loop perturbative coefficients, extending earlier work by one loop order.