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arXiv:cond-mat/0105359 · Journal of Physics B Atomic Molecular and Optical Physics

Finite-size scaling and the role of the thermodynamic ensemble in the transition temperature of a dilute Bose gas

Erich J. Mueller, Gordon Baym, Markus Holzmann

Published Nov 23, 2001• 14 citations
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Abstract

We study the Bose-Einstein condensation phase transition in a weakly interacting gas through a perturbative analysis of finite systems. In both the grand canonical and the canonical ensembles, perturbation theory suffers from infrared divergences and cannot directly determine the transition temperature in the thermodynamic limit. However, in conjunction with finite-size scaling, perturbation theory provides a powerful calculation tool. Here we use this combination of perturbation theory and scaling to estimate a shift in the transition temperature in the canonical ensemble consistent with grand canonical calculations.

DOI
10.1088/0953-4075/34/23/303

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We study the Bose-Einstein condensation phase transition in a weakly interacting gas through a perturbative analysis of finite systems. In both the grand canonical and the canonical ensembles, perturbation theory suffers from infrared divergences and cannot directly determine the transition temperature in the thermodynamic limit. However, in conjunction with finite-size scaling, perturbation theory provides a powerful calculation tool. Here we use this combination of perturbation theory and scaling to estimate a shift in the transition temperature in the canonical ensemble consistent with grand canonical calculations.
The thermodynamic properties and finite-size scaling of weakly interacting Bose gases with a finite number of particles confined in a cubic box of volume L3{L}^{3}L3 with periodic boundary conditions are investigated theoretically based on an exact recursion relation for the canonical-ensemble partition function. In a similar manner to the case of an ideal Bose gas, the recursive scheme of the interacting finite system at any temperatures is established in the framework of the Bogoliubov theory. The temperature dependence of the condensate fraction and specific heat with different particles and interactions is obtained numerically. By defining two different transition temperatures of the finite systems, the effect of interactions on the transition temperatures yields the different and nonmonotonous behaviors. The finite-size scaling condensate fraction at the transition temperature for the systems is also discussed. It is shown that the calculated finite-size scaling is universally independent on the various system sizes and transition temperatures.
We show that the critical temperature of a uniform dilute Bose gas increases linearly with the sss-wave scattering length describing the repulsion between the particles. Because of infrared divergences, the magnitude of the shift cannot be obtained from perturbation theory, even in the weak coupling regime; rather, it is proportional to the size of the critical region in momentum space. By means of a self-consistent calculation of the quasiparticle spectrum at low momenta at the transition, we find an estimate of the effect in reasonable agreement with numerical simulations.
We report on the computation of the shift of the Bose-Einstein condensation temperature for a homogenous weakly interacting Bose gas in leading order in the diluteness parameter a n^(1/3), where `a' is the scattering length and `n' is the particle density. The perturbative series, which is afflicted by infrared divergences, is resummed by means of variational perturbation theory. Using coefficients through seven loops, we arrive at Delta T_c/T_c = 1.27 +/- 0.11 a n^(1/3), which compares favorably with recent Monte-Carlo data.
We compute the critical temperature T_c of a weakly interacting uniform Bose gas in the canonical ensemble, extending the criterion of condensation provided by the counting statistics for the uniform ideal gas. Using ordinary perturbation theory, we find in first order (Tc−Tc0)/Tc0=−0.93aρ1/3(T_c-T_c^0)/T_c^0 = -0.93 aρ^{1/3}(Tc​−Tc0​)/Tc0​=−0.93aρ1/3, where T_c^0 is the transition temperature of the corresponding ideal Bose gas, a is the scattering length, and ρρρ is the particle number density.
We investigate the convergence properties of optimized perturbation theory, or linear $\ensuremath{\delta}$ expansion (LDE), within the context of finite temperature phase transitions. Our results prove the reliability of these methods, recently employed in the determination of the critical temperature Tc{T}_{c}Tc​ for a system of a weakly interacting homogeneous dilute Bose gas. We carry out explicit LDE optimized calculations and also the infrared analysis of the relevant quantities involved in the determination of Tc{T}_{c}Tc​ in the large-NNN limit, when the relevant effective static action describing the system is extended to O(N)\mathrm{O}(N)O(N) symmetry. Then, using an efficient resummation method, we show how the LDE can already exactly reproduce the known large-NNN result for Tc{T}_{c}Tc​ at the first nontrivial order. Next, we consider the finite N=2N=2N=2 case where, using similar resummation techniques, we improve the analytical results for the nonperturbative terms involved in the expression for the critical temperature, allowing comparison with recent Monte Carlo estimates of them. To illustrate the method, we have considered a simple geometric series showing how the procedure as a whole works consistently in a general case.
We re-examine the way in which Bogoliubov's theory of a dilute Bose gas at T=0T=0T=0 has been extended to describe the statistical mechanics of interacting bosons at finite temperature. We show explicitly that the field-theoretic calculation of the grand partition function in this formulation amounts to a canonical trace over the eigenfunctions of the Bogoliubov Hamiltonian at fixed total number of bosons NNN, and that the additional trace over NNN that is required in the grand-canonical formalism is never carried out. This implies that what usually passes as the grand-canonical treatment of the Bogoliubov Hamiltonian is not quite grand-canonical, and is in fact a canonical one. We also show that the discontinuity in the condensate density predicted by previous formulations of this theory as the temperature TTT goes past the critical transition temperature TcT_cTc​ is a direct consequence of an inappropriate generalization of the Bogoliubov prescription to finite temperatures, and that this discontinuity disappears when this prescription is either used as a zero temperature approximation or avoided altogether. Armed with the above findings, we reformulate the statistical mechanics of interacting bosons in the canonical ensemble and derive the thermodynamics of the system. We then show how the canonical treatment can be used to setup a truly grand-canonical description of the statistical mechanics of a weakly interacting Bose gas where the average number of bosons in the system varies with temperature, unlike existing formulations where the total number of bosons NNN is taken to be a constant that does not depend on TTT. Consequences on the physics of interacting bosons are briefly discussed.