We discuss the motion of a particle which spin is 1/2 in a central force field in two different methods. We can get the wave function of a particle by matrix operating and vector coupling theory of the angular momentum. The results is the same, so that the coupling theory of the angular momentum is correct.
In this chapter, we develop the background needed to move our quantum mechanical formalism fully into three dimensions. We discuss angular momentum, which is the motional complement to spin angular momentum, that we developed earlier. There are some critical differences between orbital and spin angular momentum, and we need to carefully discuss how they relate and how they differ. Why is angular momentum so important? Because in problems where we have central forces (forces that depend only on the distance between two particles and act along the line connecting the two particles), the angular momentum is conserved. So, it becomes an integral part of how we solve the problem. The most important problem we have to solve, the hydrogen atom, is a central force problem; hence, we need this work before we can move forward to some really interesting physics that will come in Chap. 11 . We cover the angular momentum operators, eigenvalues, and eigenstates, their matrix representations, how to combine angular momentum, and spherical harmonics. We revisit the EPR experiment using our new formalism. We also discuss some unique representations of angular momentum by mapping to two-dimensional harmonic oscillators, as developed by Schwinger.
The theory of angular momentum and spin in quantum mechanics seems to defy common-sense intuition.We render the theory intelligible again by pointing out that this apparent impenetrability merely stems from an {\em undue} parallel interpretation of the algebraic expressions for the angular-momentum and spin operators in the group representation theory of SO(3) and SU(2). E.g. the correct meaning of the quantumoperator L^z=ℏ(x∂y∂−y∂x∂) is not that it is the operatorfor the z-component Lz of the angular momentum L, but rather the expression of the operator for the angular momentum L when it is aligned with the z-axis. Hence what we are used to note (erroneously) as L^z is not a scalar but a vector operator.The same applies{\em mutatis mutandis} for the spin operators. In the correct interpretation, the wholealgebraic formalism is just the group representation theory for the rotationsof three-dimensional Euclidean geometry. It is thus mere,elementary high-school mathematics (in a less usual, more technical guise) and as such totally exempt of any physics, let alone quantum mysteries.The change of interpretation has no impact on the algebraic results, such that they remain in agreement with experimental data and the algebra quantum mechanics remains correct. It is all only a matter of the correct geometrical meaning of the algebra.All these statements are proved within the framework of the group representation theory for SO(3) and SU(2) which is the basic tool used to describe rotational motion in quantum mechanics.
Abstract In order to prepare for the discussion of quantum many-particle Hamiltonians, for example the Heisenberg quantum spin chain Hamiltonian, this chapter examines the concept of angular momentum in quantum mechanics, especially the coupling of spin-2 operators for several quantum spins. It begins with the general theory of angular momentum for a single quantum particle, especially for a single spin-1, described by Pauli spin matrices, and then extends to the theory of angular momentum for several particles, again especially for several spins1.
Abstract Angular momentum in classical mechanics is given by a vector. The plane perpendicular to this vector, in accordance to central field theory, determines the space in which particle motion takes place. No such simple picture exists in quantum mechanics. The states of a particle in a central field are proportional to spherical harmonics which do not define any plane of motion. In the first part of this paper we discuss the angular distribution of particle position and compare it to the classical probabilistic approach. In the second part, the matter of addition of angular momenta is discussed. In classical mechanics this means addition of vectors, while in quantum mechanics Clebsch–Gordan coefficients have to be used. We have found classical approximations to quantum coefficients and the limit of their applicability. This analysis gives a basis for the so-called ‘vector addition model’ used in some elementary textbooks on atomic physics. It can help to better understand the addition of angular momenta in quantum mechanics.
When a classical particle moves in a central field the energy and the three components of angular momentum are all constants of the motion. The motion is an orbit whose orientation in space is fixed. To discuss the corresponding situation in quantum mechanics we must examine the commutation properties of the associated operators: If they all commute, then the quantities which they represent may all simultaneously be constants of the motion; if not, we must find as many mutually commuting operators as we can and obtain a maximal set of constants of the motion.
The problem of the motion of a particle in an inverse-cube central force field is fully treated by quantum mechanics and the results compared with the classical theory. Taking the effective radial potential energy as r2S, although the solutions for negative energy for $0\ensuremath{\geqq}S\ensuremath{\geqq}\frac{\ensuremath{-}{h}^{2}}{32{\ensuremath{\pi}}^{2}\ensuremath{\mu}}$ satisfy the usual boundary conditions, they can not be admitted because the Hamiltonian is not Hermitian in these solutions. This corresponds to taking (l+21)2 in place of l(l+1) as the analogue of the square of the classical angular momentum. If we do this, we get a complete analogy between the classical and quantum mechanically allowed solutions, with no quantization. The solutions involve Bessel functions of both real and imaginary orders with both real and imaginary arguments.