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The exact meaning of the angular-momentum and spin operators in quantum mechanics

G. Coddens

Published Sep 11, 2021• 0 citations
OpenAlex

Abstract

The theory of angular momentum and spin in quantum mechanics seems to defy common-sense intuition.We render the theory intelligible again by pointing out that this apparent impenetrability merely stems from an {\em undue} parallel interpretation of the algebraic expressions for the angular-momentum and spin operators in the group representation theory of SO(3) and SU(2). E.g. the correct meaning of the quantumoperator ${\hat{L}}_{z} = {\hbar\over{\imath}}\,(x{\partial\over{\partial y}} - y{\partial\over{\partial x}} )$ is not that it is the operatorfor the $z$-component $L_{z}$ of the angular momentum ${\mathbf{L}}$, but rather the expression of the operator for the angular momentum ${\mathbf{L}}$ when it is aligned with the $z$-axis. Hence what we are used to note (erroneously) as ${\hat{L}}_{z}$ is not a scalar but a vector operator.The same applies{\em mutatis mutandis} for the spin operators. In the correct interpretation, the wholealgebraic formalism is just the group representation theory for the rotationsof three-dimensional Euclidean geometry. It is thus mere,elementary high-school mathematics (in a less usual, more technical guise) and as such totally exempt of any physics, let alone quantum mysteries.The change of interpretation has no impact on the algebraic results, such that they remain in agreement with experimental data and the algebra quantum mechanics remains correct. It is all only a matter of the correct geometrical meaning of the algebra.All these statements are proved within the framework of the group representation theory for SO(3) and SU(2) which is the basic tool used to describe rotational motion in quantum mechanics.

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The theory of angular momentum and spin in quantum mechanics seems to defy common-sense intuition.We render the theory intelligible again by pointing out that this apparent impenetrability merely stems from an {\em undue} parallel interpretation of the algebraic expressions for the angular-momentum and spin operators in the group representation theory of SO(3) and SU(2). E.g. the correct meaning of the quantumoperator L^z=ℏı (x∂∂y−y∂∂x){\hat{L}}_{z} = {\hbar\over{\imath}}\,(x{\partial\over{\partial y}} - y{\partial\over{\partial x}} )L^z​=ℏ​(x∂y∂​−y∂x∂​) is not that it is the operatorfor the zzz-component LzL_{z}Lz​ of the angular momentum L{\mathbf{L}}L, but rather the expression of the operator for the angular momentum L{\mathbf{L}}L when it is aligned with the zzz-axis. Hence what we are used to note (erroneously) as L^z{\hat{L}}_{z}L^z​ is not a scalar but a vector operator.The same applies{\em mutatis mutandis} for the spin operators. In the correct interpretation, the wholealgebraic formalism is just the group representation theory for the rotationsof three-dimensional Euclidean geometry. It is thus mere,elementary high-school mathematics (in a less usual, more technical guise) and as such totally exempt of any physics, let alone quantum mysteries.The change of interpretation has no impact on the algebraic results, such that they remain in agreement with experimental data and the algebra quantum mechanics remains correct. It is all only a matter of the correct geometrical meaning of the algebra.All these statements are proved within the framework of the group representation theory for SO(3) and SU(2) which is the basic tool used to describe rotational motion in quantum mechanics.
Abstract In this chapter we introduce the concept of orbital angular momentum into the mathematical language of quantum mechanics. We discuss the commutation relations of the corresponding operators and their roles as generators of rotations in the context of the theory of Lie groups and Lie algebras, focusing on the three-dimensional rotation group SO(3). We further examine how scalar and vector-valued operators transform under spatial rotations. We then turn to the derivation of the eigenfunctions and eigenvalues of the angular-momentum operators, for which we follow a dual approach in analogy to that employed for the harmonic oscillator in Chapter 5. Using both the algebraic ladder-operator method and an analytical method using spherical polar coordinates we discover the relevant azimuthal and magnetic quantum numbers and their relation to the spherical harmonics and the Legendre polynomials
Spin-s systems Angular momentum is one of the fundamental quantities of Newtonian physics, and in quantum physics its importance is at least as great. In quantum mechanics we often distinguish between two types of angular momentum: orbital angular momentum , which a system of particles possesses due to particle motion through space; and spin angular momentum , which is an intrinsic property of a particle. The distinction will be important later, but for now we will ignore it. We will here refer to angular momentum of any sort as “spin” and develop general-purpose mathematical tools for its description. We have already dealt with spin systems, particularly the example of a spin-½ particle. Our approach began with the empirical observation that a measurement of any spin component of a spin-½ particle could yield only the results +ħ/2 or −ħ/2. We introduced the basis states | z ±〉 for the two-dimensional Hilbert space ℋ. We also gave other basis states such as {| x ±〉} and {| y ±〉} in terms of the | z ±〉 states. From basis states and measurement values we constructed operators for the spin components S x , S y , and S z . With the operators in hand, we could then examine the algebraic relations between them (such as the commutation relation in Exercise 3.56). Our job here is to generalize our analysis to systems of arbitrary spin. To do this, we will reverse our chain of logic.
As in classical mechanics, rotation in quantum mechanics is a transformation which deals with angular momentum. The difference with classical mechanics comes from the fact that angular momentum is a vector operator and not a usual vector and its components do not commute. As for any transformation in quantum mechanics, to each rotation we can associate an operator which acts in state space. The expression of this operator depends on whether the rotation is passive, that is we do a rotation of the coordinate axes and the physical system is left unchanged, or active, in which case the coordinate axes are unchanged and the rotation is performed on the physical system. In the first part (Chaps. 1 and 2) of this book, details concerning both aspects are given. Following the definition of the geometrical transformation associated with the most general rotation, we give the expression of the rotation operator for specific cases. Transformation laws for scalar fields, vector fields and spinor fields are given as well as transformation laws for scalar operators, vector operators and more generally, for operators of any rank. The second part (Chaps. 3 and 4) deals with angular momentum algebra. We define the coupling coefficients of 2, 3 and 4 angular momenta as well as the recoupling coefficients. The definition of the irreductible tensor operator, which is a generalisation of scalar and vector operators, is given as well as the Wigner-Eckart theorem. The application of this theorem to more complex cases is studied.
The various representations of rotations in physical space and Hilbert space are developed in detail. This leads to an in-depth treatment of the representation of states of well-defined spin and angular momentum in quantum systems. The peculiarities of the physics of spin— systems (spinors) is outlined. The tensorial character of representations is implicit in the treatment. The Schwinger and Bargmann representations are introduced in some detail; and this leads to SU(2) coherent states (which are important for more advanced group representation theory).
For pedagogical purposes it is demonstrated that with little effort the customary discussion of rotations in introductory courses can be extended to naturally produce a number of angular momentum operator properties, if coordinate-free rotation operators are used in their exponential form. This form gives rise to a particularly useful coordinate-free representation of the generators of rotations in three-space, from which the student can derive the usual angular momentum formalism for the case j=1 by elementary vector algebra alone. Since in this approach the j=1 formalism appears as a set of relations among simple geometric objects in ordinary space, it admits of a geometric interpretation and will leave the student better prepared for a more profound appreciation of the abstract concepts of the full theory.
The angular momentum plays an important role in quantum mechanics. It is no longer an ordinary vector, instead it is a vector operator, whose three components do not commute with each other. In quantum mechanics, the angular momentum becomes a vector operator. A general angular momentum is defined as a vector operator whose components are Hermitian operators satisfying the commutation relations similar to those for the orbital angular momentum. In order to obtain the eigenvalues and eigenfunctions, it is more convenient to express the orbital angular momentum operators in spherical polar coordinates. Spin angular momentum is an intrinsic property of elementary particles. In quantum computing, a qubit or quantum bit is a quantum version of the classical binary bit physically realized in a two-state quantum-mechanical system.