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Journal of Yili Normal University

Frequently Used Integrals in Quantum Mechanics

Yan Li

Published Jan 1, 2007• 0 citations
OpenAlex

Abstract

.This paper introduces the definition and calculating nature of two integral frequently used in Quantum Mechanics,and presents the methods and formularized results of Quantum Mechanics by using integral.

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A kink-based expression for the canonical partition function is developed using Feynman’s path integral formulation of quantum mechanics and a discrete basis set. The approach is exact for a complete set of states. The method is tested on the 3×3 Hubbard model and overcomes the sign problem seen in traditional path integral studies of fermion systems. Kinks correspond to transitions between different N-electron states, much in the same manner as occurs in configuration interaction calculations in standard ab initio methods. The different N-electron states are updated, based on which states occur frequently during a Monte Carlo simulation, giving better estimates of the true eigenstates of the Hamiltonian.
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I show that frequentism, as an explanation of probability in classical statistical mechanics, can be extended in a natural way to a decoherent quantum history space, the analogue of a classical phase space. The result is a form of finite frequentism, in which the Gibbs concept of an infinite ensemble of gases is replaced by the quantum state expressed as a superposition of a finite number of decohering microstates. It is a form of finite and actual (as opposed to hypothetical) frequentism insofar as all the microstates exist, even though they may differ macroscopically, in keeping with the decoherence-based Everett interpretation of quantum mechanics.