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Journal of Xingjiang Normal University

Three Issues of The Quantum Mechanics

Zhao Xinjun

Published Jan 1, 2003• 0 citations
OpenAlex

Abstract

The paper discusses three issues, the first order derivative of wave function is not continuous if potential has a infinite observable, and the 5 function normalization of the eigenfunction with continuous eigenvalue, and the introduction of the zero value condition of the wave function. The first two issues are not detailed demonstrated and the third not rationally treated in current literature.

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We discuss the requirement of single valuedness and periodicity of eigenfunction of the third component of the operator of angular momentum. This condition, imposed on a non observable, is often used to derive that the eigenvalues of angular momentum could be only integer. We reexamine the arguments based on this requirement and alternate condition imposed by Pauli and show that they do not follow from the first principles and therefore these constraints can dropped. Consequently, we arrive to the same conclusion as in [1]: there exist regular, normalizable eigenfunctions with the non-integer eigenvalues thus a non-integer angular momentum is perfectly admissible from the theoretical viewpoint. The issue of the nature of eigenvalues forming the spectrum of the angular momentum remains open. What can be derived from the first principles is that to a fixed value of the angular momentum L corresponds a discrete spectrum of eigenvalues of the third component of the angular momentum, m, defined by the relation |m|=L-k, k=0,1,...,[L], where [L] is an integer part of L. As a mathematical byproduct of our analysis of eigenfunctions, we present an alternate definition of a power of a complex number allowing to retain initial translational invariance of a base.

arXiv:2004.10673•Apr 17, 2020•1 citation
The paper discusses three issues, the first order derivative of wave function is not continuous if potential has a infinite observable, and the 5 function normalization of the eigenfunction with continuous eigenvalue, and the introduction of the zero value condition of the wave function. The first two issues are not detailed demonstrated and the third not rationally treated in current literature.
Solution of the Schrödinger's equation in the zero order WKB approximation is analyzed. We observe and investigate several remarkable features of the WKB0_00​ method. Solution in the whole region is built with the help of simple connection formulas we derive from basic requirements of continuity and finiteness for the wave function in quantum mechanics. We show that, for conservative quantum systems, not only total energy, but also momentum is the constant of motion. We derive the quantization conditions for two and more turning point problems. Exact energy eigenvalues for solvable and some ``insoluble'' potentials are obtained. The eigenfunctions have the form of a standing wave, Ancos⁡(knx+δn)A_n\cos(k_nx+δ_n)An​cos(kn​x+δn​), and are the asymptote of the exact solution.
Part 1: the need for the quantum mechanics quantization of radiation the special theory of relativity wave-particle duality the nature of matter waves the uncertainty principle the Bohr atom. Part 2 Schrodinger's equation: the postulates of quantum mechanics the wave equation the wave equation in three dimensions the time-independent Schrodinger equation stationary states normalisation probability flux physical constraints on the wave-function wave packets Gaussian wave-packets and the uncertainty principle. Part 3 One-dimensional potential wells: potential wells the one-dimensional infinite square well discussion of infinite square-well results eigenvalue equations the finite square well finite square well eigenfunctions the control of the wave-function by the wave equation numerical integration of Schrodinger's equation continuum solutions of the square-well potential interpretation of unbound-particle wave functions the double potential well the quantum bouncer electric fields and the tilted well the harmonic oscillator - introduction the quantum oscillator discussion of harmonic oscillator eigenvalues and eigenfunctions the classical probability density more potential wells. Part 4 Schrodinger's equation in three dimensions: particle in a three dimensional box degeneracy Schrodingers equation in spherical polar coordinates - the hydrogen atom normalisation. Part 5 Formal development of quantum mechanics: eigenvalues equations, operators and measurements the momentum operator, eigenvalues and eigenfunctions the position operator and its eigenfunctions Hermitian operators orthogonality of eigenfunctions the expansion postulate example - the b-decay of tritium expectation values compatibility of observables - commutators non-commuting operators time-dependence of expectation values - Ehrenfest's theorem abstract operators - the parity operator, matrix mechanics. Part 6 Angular momentum: angular momentum operators angular momentum commutators angular momentum eigenvalues and eigenfunctions interpretation of angular momentum eigenvalues interpretation of angular momentum eigenfunctions the Stern-Gerlach apparatus and electron spin spin operators - the Pauli Spin matrices the Zeeman effect measurements in quantum mechanics. Part 7 Spherically symmetric potential wells: the rigid rotator the radial equation the hydrogen atom and hydrogen like ions the isotropic harmonic oscillator molecular vibrations - the Morse potential the spherical square well general properties of spherically symmetric potential wells. (Part contents)
We discuss the requirement of single valuedness and periodicity of eigenfunction of the third component of the operator of angular momentum. This condition, imposed on a non observable, is often used to derive that the eigenvalues of angular momentum could be only integer. We reexamine the arguments based on this requirement and alternate condition imposed by Pauli and show that they do not follow from the first principles and therefore these constraints can dropped. Consequently, we arrive to the same conclusion as in [1]: there exist regular, normalizable eigenfunctions with the non-integer eigenvalues thus a non-integer angular momentum is perfectly admissible from the theoretical viewpoint. The issue of the nature of eigenvalues forming the spectrum of the angular momentum remains open. What can be derived from the first principles is that to a fixed value of the angular momentum L corresponds a discrete spectrum of eigenvalues of the third component of the angular momentum, m, defined by the relation |m|=L-k, k=0,1,...,[L], where [L] is an integer part of L. As a mathematical byproduct of our analysis of eigenfunctions, we present an alternate definition of a power of a complex number allowing to retain initial translational invariance of a base.