The high laser intensity is needed in traditional photoionization which shows intensive Rabi oscillations of population. The using of chirped laser pulse can restrain the Rabi oscillations and realize high efficiency of photoionization. This idea should be useful in the study of coherent transfer of population.
We study the possibility of transferring population between two bound atomic or molecular states via an autoionizing state. Conditions for efficient transfer are given and the effects of the AC Stark shifts, the Fano parameters and the incoherent channels of ionization are explored. An adiabatic analytic solution which helps in the understanding of the behaviour of the system is also given. Efficient transfer is realized by using both a counterintuitive pulse sequence and concurrent laser pulses.
We discuss electronic population transfer in diatomic molecules. By analyzing time-dependent wave packets on electronic potential-energy surfaces, we investigate the efficiency and robustness of population transfer with intense, chirped laser pulses. Recently, the magnitude of the population transfer was observed to have a remarkable dependence on the sign of the chirp [J. Cao, C. J. Bardeen, and K. R. Wilson, Phys. Rev. Lett. 80, 1406 (1998)]. In this work we explain the reason for this asymmetry, and show how the frequency detuning, intensity, and chirp rate affect the results. In particular, we demonstrate efficient, robust population transfer for both positive and negative chirps. A Landau-Zener model of multiple avoided crossings is invoked to model the results.
The ultrafast particle population transfer in a ■-type three-level atomic system driven by linearly polarized chirped Gauss femtosecond laser pulse is investigated by using numerical solution of the Schrdinger equation without the rotating wave approximation(RWA).It is shown that the population transfer is mainly determined by the Rabi frequency(intensity) of the driving laser field and chirp rate,and the ratio of two dipole moments and the pulse width also have obvious effect on the population transfer.By choosing suitable values of the above parameters,nearly complete population transfer(99.6%) can be realized.