The interaction between matter and radiation has fascinated physicists for a long time. On the material side, the most detailed investigations of these processes concentrate on atoms, the basic constituents of matter. The radiation that is involved in these processes is primarily light, i.e., radiation whose wavelength is in the range of a few tenths of a micron to a few microns. Under today's laboratory conditions, this radiation is generally produced by a laser. This introduction outlines our picture of these constituents and presents some of the concepts and models that we will use throughout this book. Atoms Historical Early models: atoms as building blocks The term “atom” was coined by the Greek philosopher Democritus of Abdera (460–370 B.C.), who tried to reconcile change with eternal existence. His solution to this dilemma was that matter was not indefinitely divisible, but consisted of structureless building blocks that he called atoms. According to Democritus and other proponents of this idea, the diverse aspects of matter, as we know it, are a result of different arrangements of the same building blocks in empty space (Melsen 1957; Simonyi 1990). The most important opponent of this theory was Aristotle (384–322 B.C.), and his great influence is probably the main reason that the atomic hypothesis was not widely accepted, but lay dormant for two thousand years. It reappeared only in the eighteenth century, when the emerging experimental science found convincing evidence that matter does indeed consist of elementary building blocks.
The interaction between matter and radiation has fascinated physicists for a long time. On the material side, the most detailed investigations of these processes concentrate on atoms, the basic constituents of matter. The radiation that is involved in these processes is primarily light, i.e., radiation whose wavelength is in the range of a few tenths of a micron to a few microns. Under today's laboratory conditions, this radiation is generally produced by a laser. This introduction outlines our picture of these constituents and presents some of the concepts and models that we will use throughout this book. Atoms Historical Early models: atoms as building blocks The term “atom” was coined by the Greek philosopher Democritus of Abdera (460–370 B.C.), who tried to reconcile change with eternal existence. His solution to this dilemma was that matter was not indefinitely divisible, but consisted of structureless building blocks that he called atoms. According to Democritus and other proponents of this idea, the diverse aspects of matter, as we know it, are a result of different arrangements of the same building blocks in empty space (Melsen 1957; Simonyi 1990). The most important opponent of this theory was Aristotle (384–322 B.C.), and his great influence is probably the main reason that the atomic hypothesis was not widely accepted, but lay dormant for two thousand years. It reappeared only in the eighteenth century, when the emerging experimental science found convincing evidence that matter does indeed consist of elementary building blocks.
From prehistoric times has come recognition that sunlight and firelight provide warmth, and that such illumination casts shadows. Expressed in more contemporary terms one would say that light travels in rays, and that this radiation has the potential to provide heat energy to absorbing material. From the time of Newton it has been known that light sources emit radiation comprising a distribution of colors. During the nineteenth century it was recognized that radiation had characteristics of transverse waves (with wavelength associated to color) but until the late twentieth century, when lasers became laboratory tools, it was hardly necessary to delve into the equations of electromagnetic theory to treat such experiments as were then possible; interest lay primarily with thermodynamic considerations of energy flow or with measurements of the dark or bright lines seen in the distribution of light that, after passing through a slit, was dispersed by a prism or grating into constituent colors. Although laser light sources are essential for the types of atomic excitation considered in this monograph, the legacy from thermal radiation still influences many interpretations of the interaction between radiation and matter, and it is therefore useful to summarize some of those concepts. The mathematics needed for describing laser radiation, or polarized light in general, has much in common with the mathematics of quantum theory discussed starting in Sec. 3.5 and specialized to two-level atoms in Sec. 5.6. In both cases one deals with two complex-valued functions – independent electric field amplitudes or probability amplitudes – whose absolute squares are measurable.
Introduction It is believed that the basic physical building blocks forming the world we live in may be categorized into particles of matter and carriers of force between matter. All known elementary constituents of matter and transmitters of force are quantized. For example, energy, momentum, and angular momentum take on discrete quantized values. The electron is an example of an elementary particle of matter, and the photon is an example of a transmitter of force. Neutrons, protons, and atoms are composite particles made up of elementary particles of matter and transmitters of force. These composite particles are also quantized. Because classical mechanics is unable to explain quantization, we must learn quantum mechanics in order to understand the microscopic properties of atoms – which, for example, make up solids such as crystalline semiconductors. Historically, the laws of quantum mechanics have been established by experiment. The most important early experiments involved light. Long before it was realized that light waves are quantized into particles called photons, key experiments on the wave properties of light were performed. For example, it was established that the color of visible light is associated with different wavelengths of light. Table 2.1 shows the range of wavelengths corresponding to different colors. The connection between optical and electrical phenomena was established by Maxwell in 1864. This extended the concept of light to include the complete electromagnetic spectrum. A great deal of effort was, and continues to be, spent gathering information on the behavior of light.
The description of the physical and chemical properties of matter is a central issue that has occupied the minds of scientists since the age of the ancient Greeks. In their route to dissect matter down to what cannot be divided any further, they coined the term atom , the indivisible . Matter became then a collection of atoms. More than twenty centuries had to pass until the development of a more precise concept of atom, thanks, amongst others, to the systematic studies of Mendeleyev and the establishment in 1869 of the periodic table of the elements (Mendeleyev, 1869). The discovery of the electron in 1897 and the first modern model of the atomic structure by Sir Joseph Thomson were soon refined by his student, Sir Ernest Rutherford, who in 1910 showed that an atom was made of a positively charged small nucleus and a number of negatively charged electrons that neutralize the nuclear charge. Much in the spirit of planetary systems, and drawing from the analogy between gravitational and electrostatic interactions, scientists in the beginning of the twentieth century built an image of the atom that consisted of a number Z of electrons – of elementary charge – e – orbiting around the nucleus of charge Ze . A number of experimental observations, though, were incompatible with this idea of orbiting electrons. In particular, according to the successful electromagnetic theory, charged electrons in orbital (radially accelerated) motion should radiate energy, thus decelerating and eventually collapsing onto the nucleus. Clearly, such a picture would imply that matter is essentially unstable, in flagrant contradiction with our everyday experience of the very existence of matter.
Light and matter are very closely linked in our modelling of the physical world. From the formulation of quantum theory to the invention of laser, the interaction between atoms and radiation has played a crucial role in the development of today’s science and technology. By controlling this interaction, the lowest temperatures ever recorded are now reached. Cooling atomic gases with laser light produces “quantum matter” with radically different properties from those of ordinary fluids. These cold atoms are the cornerstone of a new metrology of time and space, with applications in a wide variety of fields, including navigation, telecommunication and geophysics.
The idea of the photon has stirred the imaginations of physicists ever since 1905 when Einstein originally proposed the use of light quanta to explain the photoelectric effect. This concept is formalized in the quantum theory of radiation, which has had unfailing success in explaining the interaction of electromagnetic radiation with matter, seemingly limited only by the ability of physicists to perform the indicated calculations. Nevertheless, it has its conceptual problems—various infinities and frequent misinterpretations. Consequently an increasing number of workers are asking, “to what extent is the quantized field really necessary and useful?” In fact the experimental results of the photoelectric effect were explained by G. Wentzel in 1927 without the quantum theory of radiation. Similarly most electro-optic phenomena such as stimulated emission, reaction of the emitted field on the emitting atom, resonance fluorescence, and so on, do not require the quantization of the field for their explanation. As we will see, these processes can all be quantitatively explained and physically understood in terms of the semiclassical theory of the matter–field interaction in which the electric field is treated classically while the atoms obey the laws of quantum mechanics. The quantized field is fundamentally required for accurate descriptions of certain processes involving fluctuations in the electromagnetic field: for example, spontaneous emission, the Lamb shift, the anomalous magnetic moment of the electron, and certain aspects of blackbody radiation. (The Compton effect also fits here, but see later under references 8b and c.) Here we will outline how the photon concept originated and developed, where it is not required and is often misused, and finally where it plays an essential role in the understanding of physical phenomena. In our discussion we will attempt to give a logically consistent definition of the word “photon”—a statement far more necessary than one might think, for so many contradictory uses exist of this elusive beast. In particular consider the original coining of the word by G. N. Lewis: “[because it appears to spend] only a minute fraction of its existence as a carrier of radiant energy, while the rest of the time it remains an important structural element within the atom…, I therefore take the liberty of proposing for this hypothetical new atom which is not light but plays an essential part in every process of radiation, the name photon!” (our exclamation point). Clearly the present usage of the word is very different.
One group of physicists simply assumed that atoms exist, picturing them as tiny particles bouncing around in accordance with Newton's laws. The arrival of quantum mechanics gave new insights into the behaviour of matter, and it is now apparent that many important and useful properties of materials are due to quantum mechanical effects. In this course, our discussion of the physics of matter is split into two parts. The central importance of atoms has been emphasized by Richard Feynman, Nobel laureate and one of the greatest physicists of recent times. Ironically, just as the existence of atoms was being demonstrated beyond any reasonable doubt at the beginning of the twentieth century, the foundations of Newtonian mechanics were being shaken by the first glimmerings of quantum theory.