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The Quantum theory of damping and the Raman Effect

K. J. McNeil

Published Jan 1, 1973• 0 citations
OpenAlex

Abstract

The basis of this dissertation is a review of the quantum mechanical formulation of damping and stimulation, particularly in non-linear optical processes. The basic problems of the quantum theory of damping are discussed, and the formalism for the quantum theory is introduced. The study of a particular example, that of a damped simple harmonic oscillator, provides an introduction to the handling of the basic tool, the master equation. The physical aspects of the non-linear processes are contained in the systems' photon statistics, and the master equation provides several approaches for obtaining these. This theory is then used to formulate a quantum mechanical model of Raman scattering by phonons, and to thus obtain the photon statistics of the scattered radiation.

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A master equation approach to the Raman effect

Daniel F. Walls

A quantum-mechanical model of Raman scattering from a phonon bath is formulated. A master equation is derived for the density operator of the light fields alone. This model correctly describes the stochastic coupling of Stokes and anti-Stokes radiation through the phonon bath. Since quantum fluctuations are included, this treatment contains the spontaneous and stimulated Raman effects in one self-consistent formalism. The photon statistics of the light fields are obtained by the solution of a Fokker-Planck equation.

Journal of Physics A Mathematical Nuclear and General•Apr 1, 1973•36 citations

Quantum-statistical theory of Raman scattering processes

Adam Miranowicz, S. Kielich

Raman scattering from a great number of phonon modes is described from a quantum-statistical point of view within the standing-wave model. The master equation for the completely quantum case, including laser pump depletion and stochastic coupling of Stokes and anti-Stokes modes, is derived and converted to classical equations: either into a generalized Fokker-Planck equation and an equation of motion for the characteristic function or into the master equation in Fock representation. These two approaches are developed both in linear and nonlinear regime. A detailed analysis of scattering into Stokes and anti-Stokes modes in linear regime, i.e., under parametric approximation, is presented. The existence of s-parametrized quasiprobability distributions, in particular the Glauber-Sudarshan P-function, is investigated. An analysis of Raman scattering into separate Stokes and anti-Stokes modes in nonlinear regime, thus including pump depletion, is given. The master equation in Fock representation is solved exactly for the complete density matrix using the Laplace transform method. Short-time solutions, steady-state solutions and approximate compact form solutions are obtained. Relations between the quasidistribution approach based on the Fokker-Planck equation and the density matrix approach based on the master equation in Fock representation are presented. The photocount distribution and its factorial moments as well as variances and extremal variances of quadratures are calculated in both approaches giving the basis for the analysis of the quantum properties of radiation such as sub-Poissonian photon-counting statistics and squeezing. Various statistical moments obtained from numerical calculations utilizing our exact solutions, from the approximate relations for short times, and those obtained under parametric approximation are compared.

arXiv:1110.4959•Oct 22, 2011•3 citations

Quantum optics and damping

William C. Schieve, Lawrence Paul Horwitz

Introduction In this chapter we will turn to the arena of quantum optics for illustrative examples of the use of the master equation discussed in Chapters 3 and 6. In fact, quantum optics examples have already been utilized in Chapter 2 as introduction to the density matrix. The principal focus here will be quantum damping in these systems, that is, the damping effect on an atom in interaction with the electromagnetic field as a reservoir. Damping is discussed extensively in Chapter 17 in connection with decay-scattering systems. For this system general phase space distribution functions will be reexamined. To some degree, this has already been done in Chapter 2 with the introduction of the Glauber–Sudarshan P (α a * ) function. The micromaser will be discussed as a modern and interesting example of the dynamic interaction of an atom with an electromagnetic cavity not in equilibrium. For use of the student, an appendix to this chapter will briefly review the quantization of the free electromagnetic field and its atomic interaction. There is no possibility of reviewing this extensive and growing field here. Our desire in this chapter is to connect the general topics of this book to this example. The books of Louisell (1973) and Scully and Zubairy (1997) are excellent. We are also indebted to the work of Nussenzweig, Schleich, and Mandel and Wolf (Nussenzweig, 1973; Mandel and Wolf, 1995; Schleich, 2001). We also recall the fine early introduction to this topic by Agarwal (1973). Atomic damping: atomic master equation In this section we shall consider the so-called quantum optics master equation for the reduced atomic density operator, ρ A ( t ), in the Born approximation. The elements of this derivation have already been discussed in Chapter 3 with the derivation of the Pauli equation for 〈α| ρ A |α〉. Here the generalization to off-diagonal contributions only adds complication.

Cambridge University Press eBooks•Apr 16, 2009•0 citations

OPEN QUANTUM SYSTEMS

Аурелиан Исар, A. Sãndulescu, Horia Scutaru +2 more

The damping of the harmonic oscillator is studied in the framework of the Lindblad theory for open quantum systems. A generalization of the fundamental constraints on quantum mechanical diffusion coefficients which appear in the master equation for the damped quantum oscillator is presented; the Schrödinger, Heisenberg and Weyl-Wigner-Moyal representations of the Lindblad equation are given explicitly. On the basis of these representations it is shown that various master equations for the damped quantum oscillator used in the literature are particular cases of the Lindblad equation and that not all of these equations are satisfying the constraints on quantum mechanical diffusion coefficients. Analytical expressions for the first two moments of coordinate and momentum are obtained by using the characteristic function of the Lindblad master equation. The master equation is transformed into Fokker-Planck equations for quasiprobability distributions and a comparative study is made for the Glauber P representation, the antinormal ordering Q representation, and the Wigner W representation. The density matrix is represented via a generating function, which is obtained by solving a timedependent linear partial differential equation derived from the master equation. Illustrative examples for specific initial conditions of the density matrix are provided. The solution of the master equation in the Weyl-Wigner-Moyal representation is of Gaussian type if the initial form of the Wigner function is taken to be a Gaussian corresponding (for example) to a coherent wavefunction. The damped harmonic oscillator is applied for the description of the charge equilibration mode observed in deep inelastic reactions. For a system consisting of two harmonic oscillators the time dependence of expectation values, Wigner function and Weyl operator, are obtained and discussed. In addition models for the damping of the angular momentum are studied. Using this theory to the quantum tunneling through the nuclear barrier, besides Gamow’s transitions with energy conservation, additional transitions with energy loss are found. The tunneling spectrum is obtained as a function of the barrier characteristics. When this theory is used to the resonant atom-field interaction, new optical equations describing the coupling through the environment of the atomic observables are obtained. With these equations, some characteristics of the laser radiation absorption spectrum and optical bistability are described.

arXiv:quant-ph/0411189•International Journal of Modern Physics E•Jun 1, 1994•215 citations

Quantization of the linearly damped harmonic oscillator

H. Dekker

A previously developed novel theory for the formal canonical quantization of classically dissipating systems will be the starting point for a detailed discussion of the quantum statistical aspects of the simple linearly damped harmonic oscillator. The formalism essentially involves complex classical canonical coordinates and momenta, and thus quite naturally leads to the possibility of creation and annihilation operators. Furthermore, the occurrence of quantal noise operators appears to be of principal importance for the conservation of the fundamental commutator in the course of time, as will be expressed in a simple fluctuation-dissipation relation. Making a canonical transformation back to the real, Cartesian Hermitian position and momentum an "effective" Hermitian Hamiltonian will be derived, with which a transformation is made from the Heisenberg frame to the Schr\"odinger frame where the density operator equation will be computed. This will make it obvious that no proper Schr\"odinger equation exists for the dissipative subsystem on its own, thus reflecting an incomplete knowledge. The master equation will then be translated into its Wigner representation. The intimate connection between the diffusion coefficients in the resulting Fokker-Planck equation and the uncertainty relation will be demonstrated in a clear fashion.

Physical Review A•Nov 1, 1977•167 citations

The Theory of Open Quantum Systems

Heinz‐Peter Breuer, Francesco Petruccione

Abstract This book treats the central physical concepts and mathematical techniques used to investigate the dynamics of open quantum systems. To provide a self-contained presentation, the text begins with a survey of classical probability theory and with an introduction to the foundations of quantum mechanics, with particular emphasis on its statistical interpretation and on the formulation of generalized measurement theory through quantum operations and effects. The fundamentals of density matrix theory, quantum Markov processes, and completely positive dynamical semigroups are developed. The most important master equations used in quantum optics and condensed matter theory are derived and applied to the study of many examples. Special attention is paid to the Markovian and non-Markovian theory of environment induced decoherence, its role in the dynamical description of the measurement process, and to the experimental observation of decohering electromagnetic field states. The book includes the modern formulation of open quantum systems in terms of stochastic processes in Hilbert space. Stochastic wave function methods and Monte Carlo algorithms are designed and applied to important examples from quantum optics and atomic physics. The fundamentals of the treatment of non-Markovian quantum processes in open systems are developed on the basis of various mathematical techniques, such as projection superoperator methods and influence functional techniques. In addition, the book expounds the relativistic theory of quantum measurements and the density matrix theory of relativistic quantum electrodynamics.

•Jan 25, 2007•5,936 citations
The basis of this dissertation is a review of the quantum mechanical formulation of damping and stimulation, particularly in non-linear optical processes. The basic problems of the quantum theory of damping are discussed, and the formalism for the quantum theory is introduced. The study of a particular example, that of a damped simple harmonic oscillator, provides an introduction to the handling of the basic tool, the master equation. The physical aspects of the non-linear processes are contained in the systems' photon statistics, and the master equation provides several approaches for obtaining these. This theory is then used to formulate a quantum mechanical model of Raman scattering by phonons, and to thus obtain the photon statistics of the scattered radiation.
A quantum-mechanical model of Raman scattering from a phonon bath is formulated. A master equation is derived for the density operator of the light fields alone. This model correctly describes the stochastic coupling of Stokes and anti-Stokes radiation through the phonon bath. Since quantum fluctuations are included, this treatment contains the spontaneous and stimulated Raman effects in one self-consistent formalism. The photon statistics of the light fields are obtained by the solution of a Fokker-Planck equation.
Raman scattering from a great number of phonon modes is described from a quantum-statistical point of view within the standing-wave model. The master equation for the completely quantum case, including laser pump depletion and stochastic coupling of Stokes and anti-Stokes modes, is derived and converted to classical equations: either into a generalized Fokker-Planck equation and an equation of motion for the characteristic function or into the master equation in Fock representation. These two approaches are developed both in linear and nonlinear regime. A detailed analysis of scattering into Stokes and anti-Stokes modes in linear regime, i.e., under parametric approximation, is presented. The existence of s-parametrized quasiprobability distributions, in particular the Glauber-Sudarshan P-function, is investigated. An analysis of Raman scattering into separate Stokes and anti-Stokes modes in nonlinear regime, thus including pump depletion, is given. The master equation in Fock representation is solved exactly for the complete density matrix using the Laplace transform method. Short-time solutions, steady-state solutions and approximate compact form solutions are obtained. Relations between the quasidistribution approach based on the Fokker-Planck equation and the density matrix approach based on the master equation in Fock representation are presented. The photocount distribution and its factorial moments as well as variances and extremal variances of quadratures are calculated in both approaches giving the basis for the analysis of the quantum properties of radiation such as sub-Poissonian photon-counting statistics and squeezing. Various statistical moments obtained from numerical calculations utilizing our exact solutions, from the approximate relations for short times, and those obtained under parametric approximation are compared.
Introduction In this chapter we will turn to the arena of quantum optics for illustrative examples of the use of the master equation discussed in Chapters 3 and 6. In fact, quantum optics examples have already been utilized in Chapter 2 as introduction to the density matrix. The principal focus here will be quantum damping in these systems, that is, the damping effect on an atom in interaction with the electromagnetic field as a reservoir. Damping is discussed extensively in Chapter 17 in connection with decay-scattering systems. For this system general phase space distribution functions will be reexamined. To some degree, this has already been done in Chapter 2 with the introduction of the Glauber–Sudarshan P (α a * ) function. The micromaser will be discussed as a modern and interesting example of the dynamic interaction of an atom with an electromagnetic cavity not in equilibrium. For use of the student, an appendix to this chapter will briefly review the quantization of the free electromagnetic field and its atomic interaction. There is no possibility of reviewing this extensive and growing field here. Our desire in this chapter is to connect the general topics of this book to this example. The books of Louisell (1973) and Scully and Zubairy (1997) are excellent. We are also indebted to the work of Nussenzweig, Schleich, and Mandel and Wolf (Nussenzweig, 1973; Mandel and Wolf, 1995; Schleich, 2001). We also recall the fine early introduction to this topic by Agarwal (1973). Atomic damping: atomic master equation In this section we shall consider the so-called quantum optics master equation for the reduced atomic density operator, ρ A ( t ), in the Born approximation. The elements of this derivation have already been discussed in Chapter 3 with the derivation of the Pauli equation for 〈α| ρ A |α〉. Here the generalization to off-diagonal contributions only adds complication.
The damping of the harmonic oscillator is studied in the framework of the Lindblad theory for open quantum systems. A generalization of the fundamental constraints on quantum mechanical diffusion coefficients which appear in the master equation for the damped quantum oscillator is presented; the Schrödinger, Heisenberg and Weyl-Wigner-Moyal representations of the Lindblad equation are given explicitly. On the basis of these representations it is shown that various master equations for the damped quantum oscillator used in the literature are particular cases of the Lindblad equation and that not all of these equations are satisfying the constraints on quantum mechanical diffusion coefficients. Analytical expressions for the first two moments of coordinate and momentum are obtained by using the characteristic function of the Lindblad master equation. The master equation is transformed into Fokker-Planck equations for quasiprobability distributions and a comparative study is made for the Glauber P representation, the antinormal ordering Q representation, and the Wigner W representation. The density matrix is represented via a generating function, which is obtained by solving a timedependent linear partial differential equation derived from the master equation. Illustrative examples for specific initial conditions of the density matrix are provided. The solution of the master equation in the Weyl-Wigner-Moyal representation is of Gaussian type if the initial form of the Wigner function is taken to be a Gaussian corresponding (for example) to a coherent wavefunction. The damped harmonic oscillator is applied for the description of the charge equilibration mode observed in deep inelastic reactions. For a system consisting of two harmonic oscillators the time dependence of expectation values, Wigner function and Weyl operator, are obtained and discussed. In addition models for the damping of the angular momentum are studied. Using this theory to the quantum tunneling through the nuclear barrier, besides Gamow’s transitions with energy conservation, additional transitions with energy loss are found. The tunneling spectrum is obtained as a function of the barrier characteristics. When this theory is used to the resonant atom-field interaction, new optical equations describing the coupling through the environment of the atomic observables are obtained. With these equations, some characteristics of the laser radiation absorption spectrum and optical bistability are described.
A previously developed novel theory for the formal canonical quantization of classically dissipating systems will be the starting point for a detailed discussion of the quantum statistical aspects of the simple linearly damped harmonic oscillator. The formalism essentially involves complex classical canonical coordinates and momenta, and thus quite naturally leads to the possibility of creation and annihilation operators. Furthermore, the occurrence of quantal noise operators appears to be of principal importance for the conservation of the fundamental commutator in the course of time, as will be expressed in a simple fluctuation-dissipation relation. Making a canonical transformation back to the real, Cartesian Hermitian position and momentum an "effective" Hermitian Hamiltonian will be derived, with which a transformation is made from the Heisenberg frame to the Schr\"odinger frame where the density operator equation will be computed. This will make it obvious that no proper Schr\"odinger equation exists for the dissipative subsystem on its own, thus reflecting an incomplete knowledge. The master equation will then be translated into its Wigner representation. The intimate connection between the diffusion coefficients in the resulting Fokker-Planck equation and the uncertainty relation will be demonstrated in a clear fashion.
Abstract This book treats the central physical concepts and mathematical techniques used to investigate the dynamics of open quantum systems. To provide a self-contained presentation, the text begins with a survey of classical probability theory and with an introduction to the foundations of quantum mechanics, with particular emphasis on its statistical interpretation and on the formulation of generalized measurement theory through quantum operations and effects. The fundamentals of density matrix theory, quantum Markov processes, and completely positive dynamical semigroups are developed. The most important master equations used in quantum optics and condensed matter theory are derived and applied to the study of many examples. Special attention is paid to the Markovian and non-Markovian theory of environment induced decoherence, its role in the dynamical description of the measurement process, and to the experimental observation of decohering electromagnetic field states. The book includes the modern formulation of open quantum systems in terms of stochastic processes in Hilbert space. Stochastic wave function methods and Monte Carlo algorithms are designed and applied to important examples from quantum optics and atomic physics. The fundamentals of the treatment of non-Markovian quantum processes in open systems are developed on the basis of various mathematical techniques, such as projection superoperator methods and influence functional techniques. In addition, the book expounds the relativistic theory of quantum measurements and the density matrix theory of relativistic quantum electrodynamics.