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Quantum work and the informational cost of projective measurements

Sebastian Deffner, Juan Pablo Paz, Wojciech Hubert Zurek

Published Mar 21, 2016• 0 citations
OpenAlex

Abstract

Quantum work is usually determined from two projective measurements of the energy at the beginning and at the end of a thermodynamic process. However, this paradigm cannot be considered thermodynamically consistent as it does not account for the thermodynamic cost of these measurements. To remedy this conceptual inconsistency we introduce a novel paradigm that relies only on the expected change of the average energy given the initial energy eigenbasis. In particular, we completely omit quantum measurements in the definition of quantum work, and hence quantum work is identified as a thermodynamic quantity of only the system. As main results we derive a modified quantum Jarzynski equality and a sharpened maximum work theorem in terms of the information free energy. Comparison of our results with the standard approach allows to quantify the informational cost of projective measurements.

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Quantum work is usually determined from two projective measurements of the energy at the beginning and at the end of a thermodynamic process. However, this paradigm cannot be considered thermodynamically consistent as it does not account for the thermodynamic cost of these measurements. To remedy this conceptual inconsistency we introduce a novel paradigm that relies only on the expected change of the average energy given the initial energy eigenbasis. In particular, we completely omit quantum measurements in the definition of quantum work, and hence quantum work is identified as a thermodynamic quantity of only the system. As main results we derive a modified quantum Jarzynski equality and a sharpened maximum work theorem in terms of the information free energy. Comparison of our results with the standard approach allows to quantify the informational cost of projective measurements.
Quantum work is usually determined from two projective measurements of the energy at the beginning and at the end of a thermodynamic process. However, this paradigm cannot be considered thermodynamically consistent as it does not account for the thermodynamic cost of these measurements. To remedy this conceptual inconsistency we introduce a paradigm that relies only on the expected change of the average energy given the initial energy eigenbasis. In particular, we completely omit quantum measurements in the definition of quantum work, and hence quantum work is identified as a thermodynamic quantity of only the system. As main results we derive a modified quantum Jarzynski equality and a sharpened maximum work theorem in terms of the information free energy. A comparison of our results with the standard approach allows one to quantify the informational cost of projective measurements.
An open question of fundamental importance in thermodynamics is how to describe the fluctuations of work for quantum coherent processes. In the standard approach, based on a projective energy measurement both at the beginning and at the end of the process, the first measurement destroys any initial coherence in the energy basis. Here we seek for extensions of this approach which can possibly account for initially coherent states. We therefore consider all measurement schemes to estimate work and require that (i) they agree with the standard two-measurement scheme for states with no coherence in the energy basis, and (ii) the expected value of the measurement outcomes is equal to the average energy difference of the unmeasured process for all states. We first show that such a scheme does not exist. Next, we consider the possibility of performing collective measurements on several copies of the state and prove that it still impossible to satisfy simultaneously requirements (i) and (ii). Nevertheless, improvements do appear, and in particular we develop a measurement scheme which acts simultaneously on two copies of the state and allows to describe a whole class of coherent transformations.
In this Letter we investigate the concept of quantum work and its measurability from the viewpoint of quantum measurement theory. Very often, quantum work and fluctuation theorems are discussed in the framework of projective two-point measurement (TPM) schemes. According to a well-known no-go theorem, there is no work observable which satisfies both (i) an average work condition and (ii) the TPM statistics for diagonal input states. Such projective measurements represent a restrictive class among all possible measurements. It is desirable, both from a theoretical and experimental point of view, to extend the scheme to the general case including suitably designed unsharp measurements. This shifts the focus to the question of what information about work and its fluctuations one is able to extract from such generalized measurements. We show that the no-go theorem no longer holds if the observables in a TPM scheme are jointly measurable for any intermediate unitary evolution. We explicitly construct a model with unsharp energy measurements and derive bounds for the visibility that ensure joint measurability. In such an unsharp scenario a single work measurement apparatus can be constructed that allows us to determine the correct average work and to obtain free energy differences with the help of a Jarzynski equality.
The validity of the Jarzynski equation for a very simple, exactly solvable quantum system is analyzed. The implications of two different definitions of work proposed in the literature are investigated. The first one derives from measurements of the system energy at the beginning and at the end of the process under consideration making the work a classical stochastic variable with transition probabilities derived from quantum-mechanics. In the second definition an operator of work is introduced and the average in the Jarzynski equation is a quantum expectation value. For the first definition a general quantum-mechanical version of the Jarzynski equation is known to hold. For the second one the Jarzynski equation fails to yield the free energy difference at low temperature.
An open question of fundamental importance in thermodynamics is how to describe the fluctuations of work for quantum coherent processes. In the standard approach, based on a projective energy measurement both at the beginning and at the end of the process, the first measurement destroys any initial coherence in the energy basis. Here we seek extensions of this approach which can possibly account for initially coherent states. We consider all measurement schemes to estimate work and require that (i) the difference of average energy corresponds to average work for closed quantum systems and that (ii) the work statistics agree with the standard two-measurement scheme for states with no coherence in the energy basis. We first show that such a scheme cannot exist. Next, we consider the possibility of performing collective measurements on several copies of the state and prove that it is still impossible to simultaneously satisfy requirements (i) and (ii). Nevertheless, improvements do appear, and in particular, we develop a measurement scheme that acts simultaneously on two copies of the state and allows us to describe a whole class of coherent transformations.
We derive a general information–theoretic equality for a system undergoing two projective measurements separated by a general temporal evolution. The equality implies the non-negativity of the mutual information between the measurement outcomes of the earlier and later projective measurements. We show that it also contains the Jarzynski relation between the average exponential of the thermodynamical work and the exponential of the difference between the initial and final free energy. Our result elucidates the information–theoretic underpinning of thermodynamics and explains why the Jarzynski relation holds identically both quantumly as well as classically.