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New Physics Sae Mulli

Magneto-optical Transitions of Mn2+ Ions in Single Crystals of LiNbO3

Jung-Il Park, Chang-Duk KIM, Sung-Youp Lee, Hyung-Geun CHO, Hyeong-Rag LEE

Published May 26, 2011• 0 citations
Publisher
DOI
10.3938/npsm.61.507

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Functional electro-optic (EO) tunable photonic integrated circuits are crucial to next-generation information processing and advanced computing, where ferroelectric materials such as lithium niobate (LiNbO3) provide outstanding optical properties and versatile tuning mechanisms. However, beyond achieving high-performance devices, practical deployment of LiNbO3 photonic integrated circuits requires rapid and cost-effective scale-up, which remains challenging because of the fabrication complexity and high costs of ion-sliced thin-film lithium niobate and wafer bonding processes. To address this gap, we demonstrate a fully monolithic photonic platform, amorphous silicon carbide (a-SiC) on bulk LiNbO3 crystal substrate, enabling scalable, CMOS-compatible, low-cost, and high-density photonic integrated circuits without relying on thin-film LiNbO3. This integration approach breaks the long-standing cost-performance-scalability tradeoff, and intrinsically eliminates the need for sophisticated fabrication processes, including ion slicing, wafer bonding, and LiNbO3 etching. It realizes high-density, low-loss, and record high EO tuning efficiency of VpiL = 2.87 Vcm on bulk LiNbO3 crystal substrate. Furthermore, leveraging slow-light effect near photonic crystal bandgap, an 8.5-fold EO tuning efficiency enhancement is achieved, highlighting the platform's capability in confinement control and dispersion engineering.

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The optical properties of defect-perturbed Er3+{\mathrm{Er}}^{3+}Er3+ and Mn2+{\mathrm{Mn}}^{2+}Mn2+ ions in RbMgF3{\mathrm{F}}_{3}F3​ crystals have been investigated. Previous research has shown that Mn2+{\mathrm{Mn}}^{2+}Mn2+ optical transitions can be enhanced by as much as 105{10}^{5}105 through spin coupling with a nearby FFF center. This result has been further verified. Evidence is presented that radiation-defect---Er3+{\mathrm{Er}}^{3+}Er3+ complexes can be formed in RbMgF3{\mathrm{F}}_{3}F3​. Both the perturbed Mn2+{\mathrm{Mn}}^{2+}Mn2+ and Er3+{\mathrm{Er}}^{3+}Er3+ have detectable optical transitions. Our analysis suggests that, although the perturbed Er3+{\mathrm{Er}}^{3+}Er3+ transitions are shifted in energy, the oscillator strength of the ${\mathrm{Er}}^{3+}^{4}S_{\frac{3}{2}}\ensuremath{\rightarrow}^{4}I_{\frac{15}{2}}$ transition is increased by at most an order of magnitude by the presence of FFF centers. The $^{4}S_{\frac{3}{2}}\ensuremath{\rightarrow}^{4}I_{\frac{15}{2}}$ transition for the radiation-defect-perturbed Er3+{\mathrm{Er}}^{3+}Er3+ persists to room temperature and has a lifetime of 210 \ensuremath{\mu}s.
Functional electro-optic (EO) tunable photonic integrated circuits are crucial to next-generation information processing and advanced computing, where ferroelectric materials such as lithium niobate (LiNbO3) provide outstanding optical properties and versatile tuning mechanisms. However, beyond achieving high-performance devices, practical deployment of LiNbO3 photonic integrated circuits requires rapid and cost-effective scale-up, which remains challenging because of the fabrication complexity and high costs of ion-sliced thin-film lithium niobate and wafer bonding processes. To address this gap, we demonstrate a fully monolithic photonic platform, amorphous silicon carbide (a-SiC) on bulk LiNbO3 crystal substrate, enabling scalable, CMOS-compatible, low-cost, and high-density photonic integrated circuits without relying on thin-film LiNbO3. This integration approach breaks the long-standing cost-performance-scalability tradeoff, and intrinsically eliminates the need for sophisticated fabrication processes, including ion slicing, wafer bonding, and LiNbO3 etching. It realizes high-density, low-loss, and record high EO tuning efficiency of VpiL = 2.87 Vcm on bulk LiNbO3 crystal substrate. Furthermore, leveraging slow-light effect near photonic crystal bandgap, an 8.5-fold EO tuning efficiency enhancement is achieved, highlighting the platform's capability in confinement control and dispersion engineering.