The optical properties of defect-perturbed
Er3+ and
Mn2+ ions in RbMg
F3 crystals have been investigated. Previous research has shown that
Mn2+ optical transitions can be enhanced by as much as
105 through spin coupling with a nearby
F center. This result has been further verified. Evidence is presented that radiation-defect---
Er3+ complexes can be formed in RbMg
F3. Both the perturbed
Mn2+ and
Er3+ have detectable optical transitions. Our analysis suggests that, although the perturbed
Er3+ transitions are shifted in energy, the oscillator strength of the ${\mathrm{Er}}^{3+}^{4}S_{\frac{3}{2}}\ensuremath{\rightarrow}^{4}I_{\frac{15}{2}}$ transition is increased by at most an order of magnitude by the presence of
F centers. The $^{4}S_{\frac{3}{2}}\ensuremath{\rightarrow}^{4}I_{\frac{15}{2}}$ transition for the radiation-defect-perturbed
Er3+ persists to room temperature and has a lifetime of 210 \ensuremath{\mu}s.
Functional electro-optic (EO) tunable photonic integrated circuits are crucial to next-generation information processing and advanced computing, where ferroelectric materials such as lithium niobate (LiNbO3) provide outstanding optical properties and versatile tuning mechanisms. However, beyond achieving high-performance devices, practical deployment of LiNbO3 photonic integrated circuits requires rapid and cost-effective scale-up, which remains challenging because of the fabrication complexity and high costs of ion-sliced thin-film lithium niobate and wafer bonding processes. To address this gap, we demonstrate a fully monolithic photonic platform, amorphous silicon carbide (a-SiC) on bulk LiNbO3 crystal substrate, enabling scalable, CMOS-compatible, low-cost, and high-density photonic integrated circuits without relying on thin-film LiNbO3. This integration approach breaks the long-standing cost-performance-scalability tradeoff, and intrinsically eliminates the need for sophisticated fabrication processes, including ion slicing, wafer bonding, and LiNbO3 etching. It realizes high-density, low-loss, and record high EO tuning efficiency of VpiL = 2.87 Vcm on bulk LiNbO3 crystal substrate. Furthermore, leveraging slow-light effect near photonic crystal bandgap, an 8.5-fold EO tuning efficiency enhancement is achieved, highlighting the platform's capability in confinement control and dispersion engineering.