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BENTHAM SCIENCE PUBLISHERS eBooks

Microscopic open quantum physics

Published Dec 17, 2014• 0 citations
Publisher

Abstract

In this chapter, we derive quantum master equations with explicit, microscopic coefficients, for the systems of interest of a superradiant semiconductor structure: the active electrons, the electromagnetic field, and the optical crystal vibrations. These vibrations determine an important retardation in the field propagation (refractive index), and a spectrum splitting (the Raman effect). For the active electrons we consider three environmental systems: the quasi-free electrons/holes of the conduction regions, the crystal lattice vibrations excited by electron transitions, and the free electromagnetic field. For the electromagnetic field, we consider the absorption by coupling to the conduction electrons/holes, and to the optical vibrations of the crystal, while these vibrations are damped by coupling with the valence electron transitions to thermally released states. For the electron-field coupling we consider the potential derived in chapter 2 from the Lorentz force, while the momentum difference is supposed to be taken by the crystal lattce. For the coupling of the crystal vibrations to the electromagnetic field and electron transitions we consider potentials obtained from the momentum conservation. For the active electrons, we find a quantum master equation with a Markovian term describing correlated transitions with the environmental particles, and a non-Markovian term given by the self-consistent field of the environmental particles. Since the dissipative environment of the electromagnetic field is contained inside the quantization volume of this field, which is taken as a unit volume, its quantum master equation includes a dissipative term of a space integral form. For the field mean values, the dissipation integral, of propagation through the dissipative environment, can be divided in two parts: an integral from the initial coordinate up to the boundary of the quantum uncertainty region, taken for a coherent wave, which describes dephasing, and an integral over the uncertainty region, which describes absorption. Similar equations are obtained for the optical vibration field. When the vibrational field is eliminated from these equations, we obtain a frequency splitting, corresponding to the Raman effect, and an absorption rate, including the absorption of the electromagnetic waves by conduction electrons/holes, and the absorption of the vibrational waves by the valence electrons, excited by the crystal deformations in the thermally released states.

DOI
10.2174/9781608059867114010010

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In this chapter, we derive quantum master equations with explicit, microscopic coefficients, for the systems of interest of a superradiant semiconductor structure: the active electrons, the electromagnetic field, and the optical crystal vibrations. These vibrations determine an important retardation in the field propagation (refractive index), and a spectrum splitting (the Raman effect). For the active electrons we consider three environmental systems: the quasi-free electrons/holes of the conduction regions, the crystal lattice vibrations excited by electron transitions, and the free electromagnetic field. For the electromagnetic field, we consider the absorption by coupling to the conduction electrons/holes, and to the optical vibrations of the crystal, while these vibrations are damped by coupling with the valence electron transitions to thermally released states. For the electron-field coupling we consider the potential derived in chapter 2 from the Lorentz force, while the momentum difference is supposed to be taken by the crystal lattce. For the coupling of the crystal vibrations to the electromagnetic field and electron transitions we consider potentials obtained from the momentum conservation. For the active electrons, we find a quantum master equation with a Markovian term describing correlated transitions with the environmental particles, and a non-Markovian term given by the self-consistent field of the environmental particles. Since the dissipative environment of the electromagnetic field is contained inside the quantization volume of this field, which is taken as a unit volume, its quantum master equation includes a dissipative term of a space integral form. For the field mean values, the dissipation integral, of propagation through the dissipative environment, can be divided in two parts: an integral from the initial coordinate up to the boundary of the quantum uncertainty region, taken for a coherent wave, which describes dephasing, and an integral over the uncertainty region, which describes absorption. Similar equations are obtained for the optical vibration field. When the vibrational field is eliminated from these equations, we obtain a frequency splitting, corresponding to the Raman effect, and an absorption rate, including the absorption of the electromagnetic waves by conduction electrons/holes, and the absorption of the vibrational waves by the valence electrons, excited by the crystal deformations in the thermally released states.
An open quantum system is a quantum system that interacts with some environment whose degrees of freedom have been coarse grained away. This model describes non-equilibrium processes more general than scattering-matrix formulations. Furthermore, the microscopically-derived environment provides a model of noise, dissipation and decoherence far more general than Markovian (white noise) models. The latter are fully characterized by Lindblad equations and can be motivated phenomenologically. Non-Markovian processes consistently account for backreaction with the environment and can incorporate effects such as finite temperature and spatial correlations. We consider linear systems with bilinear coupling to the environment, or quantum Brownian motion, and nonlinear systems with weak coupling to the environment. For linear systems we provide exact solutions with analytical results for a variety of spectral densities. Furthermore, we point out an important mathematical subtlety which led to incorrect master-equation coefficients in earlier derivations, given nonlocal dissipation. For nonlinear systems we provide perturbative solutions by translating the formalism of canonical perturbation theory into the context of master equations. It is shown that unavoidable degeneracy causes an unfortunate reduction in accuracy between perturbative master equations and their solutions. We also extend the famous theorem of Lindblad, Gorini, Kossakowski and Sudarshan on completely positivity to non-Markovian master equations. Our application is primarily to model atoms interacting via a common electromagnetic field. The electromagnetic field contains correlations in both space and time, which are related to its relativistic (photon-mediated) nature. As such, atoms residing in the same field experience different environmental effects depending upon their relative position and orientation. Our more accurate solutions were necessary to assess sudden death of entanglement at zero temperature. In contrast to previous claims, we found that all initial states of two-level atoms undergo finite-time disentanglement. We were also able to access regimes which cannot be described by Lindblad equations and other simpler methods, such as near resonance. Finally we revisit the infamous Abraham-Lorentz force, wherein a single particle in motion experiences backreaction from the electromagnetic field. This leads to a number of well-known problems including pre-acceleration and runaway solutions. We found a more a more-suitable open-system treatment of the nonrelativistic particle to be perfectly causal and dissipative without any extraneous requirements for finite size of the particle, weak coupling to the field, etc..
This thesis is concerned with modelling the dynamics of open quantum systems in several different contexts. Of principal interest is the manner in which the environment can modify, or even dominate, a system’s quantum behaviour in order to facilitate the transport of energetic excitations. In the first research chapter, a time-local, non-Markovian quantum master equation is derived in a variationally defined reference frame, for networks of two-level systems coupled to bosonic environments. The predictions of this master equation are then compared with those derived using both weak-coupling and polaron approximations. The variational master equation is found to agree with these standard approaches in their regimes of validity, whilst interpolating between them in intermediate parameter regimes. The second research chapter focusses on the dynamics of a superconducting double quantum dot embedded in a resonant circuit. The device is considered in a regime where the ground state consists of a coherent spatial superposition of a single Cooper pair, which can be excited by a variety of interactions with the environment. The relevant transition rates are calculated and the processes responsible are identified. A numerical simulation of the system is then used to explain experimental data, and show that for certain parameters a significant fraction of excitations occur via absorption of photons from the environment. The final chapter considers a model for an olfactory receptor, in which odorant molecules are recognised by their vibrational modes. Electron transfer occurs in the receptor, dependent on the presence of a vibrational mode of the right frequency. A quantum master equation for the system is derived, and the resulting dynamics is compared to earlier semi-classical treatments. The behaviour of the receptor is found to be sensitive not only to the frequency of the vibrational mode, but also to the character of the surrounding environment. Increased dissipation on the odorant mode, as well as the presence of higher frequencies in the environment is found to improve the frequency resolution of the receptor.
The damping of the harmonic oscillator is studied in the framework of the Lindblad theory for open quantum systems. A generalization of the fundamental constraints on quantum mechanical diffusion coefficients which appear in the master equation for the damped quantum oscillator is presented; the Schrödinger, Heisenberg and Weyl-Wigner-Moyal representations of the Lindblad equation are given explicitly. On the basis of these representations it is shown that various master equations for the damped quantum oscillator used in the literature are particular cases of the Lindblad equation and that not all of these equations are satisfying the constraints on quantum mechanical diffusion coefficients. Analytical expressions for the first two moments of coordinate and momentum are obtained by using the characteristic function of the Lindblad master equation. The master equation is transformed into Fokker-Planck equations for quasiprobability distributions and a comparative study is made for the Glauber P representation, the antinormal ordering Q representation, and the Wigner W representation. The density matrix is represented via a generating function, which is obtained by solving a timedependent linear partial differential equation derived from the master equation. Illustrative examples for specific initial conditions of the density matrix are provided. The solution of the master equation in the Weyl-Wigner-Moyal representation is of Gaussian type if the initial form of the Wigner function is taken to be a Gaussian corresponding (for example) to a coherent wavefunction. The damped harmonic oscillator is applied for the description of the charge equilibration mode observed in deep inelastic reactions. For a system consisting of two harmonic oscillators the time dependence of expectation values, Wigner function and Weyl operator, are obtained and discussed. In addition models for the damping of the angular momentum are studied. Using this theory to the quantum tunneling through the nuclear barrier, besides Gamow’s transitions with energy conservation, additional transitions with energy loss are found. The tunneling spectrum is obtained as a function of the barrier characteristics. When this theory is used to the resonant atom-field interaction, new optical equations describing the coupling through the environment of the atomic observables are obtained. With these equations, some characteristics of the laser radiation absorption spectrum and optical bistability are described.
One of the most intriguing quantum phenomena of light is the wave–particle duality which is related to the inability of the classical wave and particle concepts to fully describe the behavior of quantum objects. Theoretically, the wave features of the electromagnetic field, such as interference, follow from the solution of Maxwell's equations while particle features are a consequence of the field quantization, in which the electromagnetic field is described to consist of discrete energy packets, photons. Due to the wave–particle duality, for example, simultaneous description of optical absorption, emission, and interference of propagating fields has conventionally not been considered feasible using local optical models but has required using Maxwell's equations with stochastic source terms accounting for the wave–particle duality. Also the description of the momentum of light in a medium has been problematic. In the research described in this thesis, the quantized fluctuational electrodynamics (QFED) model is derived based on combining the electromagnetic Green's functions to the field quantization to describe the position dependence of the photon number and local thermal balance in general non-equilibrium conditions, and to separate the electromagnetic field into parts propagating in different directions in resonant structures, which has conventionally been problematic due to interference effects. The QFED method is shown to resolve the previously found anomalies in the canonical commutation relations of photon ladder operators. The QFED method is also used to derive quantum optical field–matter interaction parameters fully capturing the interference, emission, damping, and scattering of propagating photons in stratified media leading to an interference-exact radiative transfer equation (RTE) model. Therefore, the derived interaction parameters solve the problem of simultaneously describing interference and losses in the widely used RTE framework. The particle aspects of light are also studied by directly applying the conservation laws of nature and the special theory of relativity to show that light propagating in a medium must be described as mass-polariton (MP) quasiparticles, covariant coupled states of the field and matter. These quasiparticles are shown to have momentum of the Minkowski form and a nonzero mass that is carried by a mass density wave associated with light. The field–matter interaction related to the MP quasiparticles also leads to the dissipation of photon energy. These particle model results are also derived using a wave-based optoelastic continuum dynamics (OCD) approach following from the electrodynamics of continuous media and the continuum mechanics. The obtained results verify the full agreement between the wave and particle models when they are correctly applied. The key finding that a light pulse propagating in a medium is inevitably associated with an experimentally measurable mass implies a fundamental change in the prevailing perceptions of light.; Eras kiehtovimmista valon…
The theoretical description of materials' properties driven out of equilibrium has important consequences in various fields such as semiconductor spintronics, nonlinear optics, and continuous and discrete quantum information science and technology. The coupling of a quantum many-body system to an external bath can dramatically modify its dynamics compared to that of closed systems; new phenomena like relaxation and decoherence appear as a consequence of the non-unitary evolution of the quantum system. In addition, electron-electron correlations must be properly accounted for in order to go beyond a simple one-electron or mean-field description of the electronic system. Here, we discuss a first-principles methodology based on the evolution of the electronic density matrix capable of treating electron-environment interactions and electron-electron correlations at the same level of description. The effect of the environment is separated into a coherent contribution, like the coupling to applied external electromagnetic fields, and an incoherent contribution, like the interaction with lattice vibrations or the thermal background of radiation. Electron-electron interactions are included using the nonequilibrium Green's function plus the generalized Kadanoff-Baym ansatz. The obtained non-Markovian coupled set of equations reduces to the ordinary Lindblad quantum master equation form in the Markovian limit.
We have developed a unified quantum optical master equation that includes the dissipative mechanisms of an impurity molecule in crystals. Our theory applies generally to polyatomic molecules where several vibrational modes give rise to intramolecular vibrational redistributions. The usual assumption on identical shapes of the nuclear potentials in ground and excited electronic states and the rotating wave approximation have been relaxed, i.e. the vibrational coordinates are different in the ground and excited states, with counter-rotating terms included for generality. Linear vibrational coupling to the lattice phonons accounts for dissipations via non-radiative transitions. The interaction of a molecule with photons includes Herzberg-Teller coupling as the first order non-Condon interaction where the transition dipole matrix elements depend linearly on vibrational coordinates. We obtain new cross terms as the result of mixing the terms from the zeroth-order (Condon) and first-order (non-Condon) approximations. The corresponding Lamb shifts for all Liouvilleans are derived explicitly including the contributions of counter-rotating terms. The computed absorption and emission spectra for carbon monoxide is in good agreement with experimental data. We use our unified model to obtain the spectra for nitrogen dioxide, demonstrating the capability of our theory to incorporate all typical dissipative relaxation and decoherence mechanisms for polyatomic molecules. The molecular quantum master equation is a promising theory for studying molecular quantum memory.