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Quantum simulation with dopant atoms in a semiconductor

Joe Salfi, Jan A. Mol, Rajib Rahman, Gerhard Klimeck, Michelle Yvonne Simmons, Lloyd C. L. Hollenberg, Sven M. J. Rogge

Published Jul 22, 2015• 1 citation
OpenAlex

Abstract

In quantum simulation, many-body phenomena are probed in controllable quantum systems. Recently, single-site measurements in cold-atom quantum simulations of bosons revealed previously hidden local correlations. However, interacting Fermi-Hubbard systems, connected to canonical open many-body physics problems, are more difficult to simulate using cold atoms. To date, only ensemble measurements have been achieved, while the required single-site measurements and cooling remain formidable challenges. Here we demonstrate quantum simulation of a two-impurity Fermi system using subsurface Coulomb-coupled dopant atoms in silicon. Quasiparticle tunneling maps of individually identifiable coupled-spin states were obtained by scanning tunneling spectroscopy, at low effective temperatures, and resolving individual dopants. From the maps we quantified the two-body probability amplitudes and the entanglement of the overlapping (indistinguishable) fermions, enabling quantum simulation of a thought-experiment on a stretched covalent bond. Entanglement, determined by spin and orbital components, was found to increase with increasing dopant displacement, as interactions overcome tunneling, localizing spin. Looking ahead, we extracted the effective Hubbard interaction strength, which follows a hydrogenic, separation-tunable trend appropriate to simulate emergent Fermi-Hubbard phenomena in larger sets of dopants. These results pave the way for quantum simulation of larger scale correlated Fermi-Hubbard systems, exploiting atomic-scale fabrication to engineer interactions atom-by-atom.

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In quantum simulation, many-body phenomena are probed in controllable quantum systems. Recently, single-site measurements in cold-atom quantum simulations of bosons revealed previously hidden local correlations. However, interacting Fermi-Hubbard systems, connected to canonical open many-body physics problems, are more difficult to simulate using cold atoms. To date, only ensemble measurements have been achieved, while the required single-site measurements and cooling remain formidable challenges. Here we demonstrate quantum simulation of a two-impurity Fermi system using subsurface Coulomb-coupled dopant atoms in silicon. Quasiparticle tunneling maps of individually identifiable coupled-spin states were obtained by scanning tunneling spectroscopy, at low effective temperatures, and resolving individual dopants. From the maps we quantified the two-body probability amplitudes and the entanglement of the overlapping (indistinguishable) fermions, enabling quantum simulation of a thought-experiment on a stretched covalent bond. Entanglement, determined by spin and orbital components, was found to increase with increasing dopant displacement, as interactions overcome tunneling, localizing spin. Looking ahead, we extracted the effective Hubbard interaction strength, which follows a hydrogenic, separation-tunable trend appropriate to simulate emergent Fermi-Hubbard phenomena in larger sets of dopants. These results pave the way for quantum simulation of larger scale correlated Fermi-Hubbard systems, exploiting atomic-scale fabrication to engineer interactions atom-by-atom.
In quantum simulation, many-body phenomena are probed in controllable quantum systems. Recently, simulation of Bose-Hubbard Hamiltonians using cold atoms revealed previously hidden local correlations. However, fermionic many-body Hubbard phenomena such as unconventional superconductivity and spin liquids are more difficult to simulate using cold atoms. To date the required single-site measurements and cooling remain problematic, while only ensemble measurements have been achieved. Here we simulate a two-site Hubbard Hamiltonian at low effective temperatures with single-site resolution using subsurface dopants in silicon. We measure quasi-particle tunnelling maps of spin-resolved states with atomic resolution, finding interference processes from which the entanglement entropy and Hubbard interactions are quantified. Entanglement, determined by spin and orbital degrees of freedom, increases with increasing valence bond length. We find separation-tunable Hubbard interaction strengths that are suitable for simulating strongly correlated phenomena in larger arrays of dopants, establishing dopants as a platform for quantum simulation of the Hubbard model.
The Hubbard model is an essential tool for understanding many-body physics in condensed matter systems. Artificial lattices of dopants in silicon are a promising method for the analog quantum simulation of extended Fermi-Hubbard Hamiltonians in the strong interaction regime. However, complex atom-based device fabrication requirements have meant emulating a tunable two-dimensional Fermi-Hubbard Hamiltonian in silicon has not been achieved. Here, we fabricate 3 × 3 arrays of single/few-dopant quantum dots with finite disorder and demonstrate tuning of the electron ensemble using gates and probe the many-body states using quantum transport measurements. By controlling the lattice constants, we tune the hopping amplitude and long-range interactions and observe the finite-size analogue of a transition from metallic to Mott insulating behavior. We simulate thermally activated hopping and Hubbard band formation using increased temperatures. As atomically precise fabrication continues to improve, these results enable a new class of engineered artificial lattices to simulate interactive fermionic models.
Obtaining a microscopic understanding of the dynamics in strongly correlated electronic systems has remained a challenge for many decades. The interplay between the spin and charge degrees of freedom in these materials at different temperatures and dopant concentrations is not well understood and is still an area of intense scientific research. Recently, quantum simulators based on ultracold atoms in optical lattices have emerged as a promising platform to probe strongly correlated fermionic systems. This thesis reports on the work carried out with a quantum gas microscope of ultracold fermionic Li-6, where Fermi-Hubbard systems are prepared and imaged with single site spin and density resolution. The main results of the thesis explore the microscopic dynamics underlying one-dimensional materials, where individual constituents such as the electron with charge e and spin-1/2 are not relevant to the description of the system anymore and are instead replaced by spin and charge excitations that can propagate independent of one another - a phenomenon called spin-charge separation. In our quantum simulator, we use analogous one-dimensional Fermi-Hubbard chains of Li-6, to perform time- and space-resolved microscopy of the spin and charge excitations following a local quench. By extracting their strikingly different velocities and showing an absence of binding between the excitations, we demonstrate spin-charge separation. Our microscopic technique also allows us to quantitatively extract the excess spin carried by the spin excitiation, connecting our results to the phenomenon of fractionalization. In another set of experiments, Fermi-Hubbard chains are probed at equilibrium and incommensurate spin correlations arising in the presence of both density doping and spin polarization are observed. The wavevector of these incommensurate correlations are found to have a linear dependence on doping and polarization. Finally, the effect of the spin-charge interplay is probed in the crossover from one to two dimensions. The spin correlations across dopants are seen to be dramatically different in two dimensions, and the strong antiferromagnetic correlations across dopants present in one dimension disappear. For a single dopant in a fully two dimensional system, the spin-charge interplay manifests as a distorted spin cloud surrounding the dopant, indicating the formation of a magnetic polaron. The experiments reported here demonstrate the power of a quantum simulator; by probing the physics of strongly correlated systems in real space with unprecedented resolution, we can zoom into emergent phenomena, validate theories and access regimes that are not possible in other experimental settings.
Quantum simulators have made a remarkable progress towards exploring the dynamics of many-body systems, many of which offer a formidable challenge to both theoretical and numerical methods.While state-of-the-art quantum simulators are, in principle, able to simulate quantum dynamics well outside the domain of classical computers, they are noisy and limited in the variability of the initial state of the dynamics and the observables that can be measured.Despite these limitations, here we show that such a quantum simulator can be used to in effect solve for the dynamics of a many-body system.We develop an efficient numerical technique that facilitates classical simulations in regimes not accessible to exact calculations or other established numerical techniques.The method is based on approximations that are well suited to describe localized one-dimensional Fermi-Hubbard systems.Since this new method does not have an error estimate and the approximations do not hold in general, we use a neutral-atom Fermi-Hubbard quantum simulator with L exp 290 lattice sites to benchmark its performance in terms of accuracy and convergence for evolution times up to 700 tunneling times.We then use these approximations in order to derive a simple prediction of the behavior of interacting Bloch oscillations for spin-imbalanced Fermi-Hubbard systems, which we show to be in quantitative agreement with experimental results.Finally, we demonstrate that the convergence of our method is the slowest when the entanglement depth developed in the many-body system we consider is neither too small nor too large.This represents a promising regime for near-term applications of quantum simulators.
Among the most compelling targets for quantum simulation are strongly correlated phases and electronic-structure problems, where interactions organize electrons into collective states and produce intricate low-temperature phase diagrams. Cuprate superconductors are a canonical example: at low doping, superconductivity emerges from a metallic regime that exhibits a pseudogap above the critical temperature. Ultracold atoms in optical lattices provide a well-controlled, tunable setting to probe the microscopic mechanisms behind this behavior and, in fermion-native architectures, to implement electronic structure dynamics directly. This thesis demonstrates both large scale systematic analog quantum simulations in the most interesting regime of doped antiferromagnets and elementary high-fidelity gates as the basis for a digital or hybrid fermionic quantum processors in an optical lattice. Working with ultracold Lithium-6 in a two–dimensional optical superlattice, we first map the parameter space of the Fermi–Hubbard model over a wide range of temperatures and dopings. More than 40000 single-site spin- and density-resolved snapshots, spanning over a dense grid of doping levels and temperatures in a numerically challenging parameter space, reveal antiferromagnetic correlations extending across the system size and into the pseudogap regime. Temperatures down to T/t=0.2 are realized, determined by benchmarking the data to state-of-the-art numerical methods. By evaluating spin–charge correlators up to fifth order, we experimentally uncover a universal scaling behavior across the pseudogap crossover, governed by a single, doping-dependent temperature scale. These findings provide the first microscopic evidence of universal scaling in multi-point correlators and establish stringent benchmarks for future theoretical developments. On the same apparatus, we demonstrate that the controlled motion of fermions in double wells enables high-fidelity entanglement. Double-well potentials are used to engineer coherent pair-tunnelling and spin-exchange interactions that act as native SWAP^α operations. We demonstrate the collisional gate fidelities up to 99.8% and Bell-state lifetimes exceeding ten seconds, limited mainly by residual inhomogeneities in the optical potential. A composite pulse sequence isolates the pair-exchange channel, realizing the elementary building block required for fermionic quantum-chemistry algorithms. With the addition of site-selective addressing, our results mark a key step towards a fully digital, scalable fermionic quantum computer based on the controlled motion and entanglement of fermionic neutral atoms. The work establishes a hybrid analog-digital architecture: analog evolution under the Hubbard Hamiltonian yields thermodynamic states whose magnetic properties match and extend theoretical benchmarks, while digital collisional gates provide building blocks for error-corrected quantum computation and complex state preparation.
An outstanding problem in physics is how to understand strongly interacting quantum many-body systems such as the quark-gluon plasma, neutron stars, superfluid 4He, and the high-temperature superconducting cuprates. The physics approach to this problem is to reduce these complex systems to minimal models that are believed to retain relevant phenomenology. For example, the Hubbard model — the focus of this thesis — describes quantum particles tunneling between sites of a lattice with on-site interactions. The Hubbard model is conjectured to describe the low-energy charge and spin properties of high-temperature superconducting cuprates. Thus far, there are no analytic solutions to the Hubbard model, and numerical calculations are difficult and even impossible in some regimes (e.g., the Fermi-Hubbard model away from half-filling). Therefore, whether the Hubbard model is a minimal model for the cuprates remains unresolved. In the face of these difficulties, a new approach has emerged — quantum simulation. The premise of quan-tum simulation is to perform experiments on a quantum system that is well-described by the model we are trying to study, has tunable parameters, and is easily probed. Ultracold atoms trapped in optical lattices are an ideal candidate for quantum simulation of the Hubbard models. This thesis describes work on two such systems: a 87Rb (boson) optical lattice experiment in the group of Brian DeMarco at the University