The characteristics of the nuclear magnetic resonance (NMR), the contributions to the spin-lattice relaxation rate, and Knight shift of the resonance position are calculated exactly for a model spin-1/2XY chain with the magnetic impurity. It is shown that the deviations of the impurity's coupling to the chain and the effective impurity's g factor from the values in the host spin chain yield special features in the temperature and magnetic field behavior for these NMR characteristics. The role of impurity-induced local levels in the NMR low-energy spin dynamics of spin chains is determined.
Anomalous polarization characteristics of magnetic resonance in CuGeO3 doped with 2% of Co impurity are reported. For the Faraday geometry this mode is damped for the microwave field Bw aligned along a certain crystallographic direction showing that the character of magnetic oscillation differs from the standard spin precession. The observed resonance coexists with the ESR on Cu2+ chains and argued not to be caused by "impurity" EPR, as previously claimed, but to correspond to a previously unknown collective mode of magnetic oscillations in S=1/2 AF quantum spin chain.