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Inorganic chemistry concepts

Harmonic Oscillator Wavefunctions

Charles W. Struck, William H. Fonger

Published Jan 1, 1991• 0 citations
Publisher
DOI
10.1007/978-3-642-48629-6_2

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We present a full algebraic derivation of the wavefunctions of a simple harmonic oscillator. This derivation illustrates the abstract approach to the simple harmonic oscillator by completing the derivation of the coordinate-space or momentum-space wavefunctions from the energy eigenvectors. It is simple to incorporate into the undergraduate and graduate curricula. We provide a summary of the history of operator-based methods as they are applied to the simple harmonic oscillator. We present the derivation of the energy eigenvectors along the lines of the standard approach that was first presented by Dirac in 1947 (and is modified slightly here in the spirit of the Schrödinger factorization method). We supplement it by employing the appropriate translation operator to determine the coordinate-space and momentum-space wavefunctions algebraically, without any derivatives.
We write a computer program that uses the recursion relation to calculate wave function in the harmonic-oscillator potential for specified values of E/hv (with its deviation 0.001) containing only even numbers of v (0,2,4,...). In this work, differential equations are solved by power series methods, i.e. the Schrodinger equation stationary state wavefunction of the harmonic-oscillator. This technique is applied to obtain the wavefunction of the quantum harmonic oscillator and is at a more sophisticated level than elsewhere in the course of quantum physics. For the able student this can be a worthwhile extension to the work on the harmonic-oscillator.