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Cambridge University Press eBooks

Mathematical Background

F. S. Levin

Published Dec 3, 2001• 0 citations
Publisher

Abstract

The quantities in physics that can be measured are conventionally denoted observables : entities that can be observed (directly or indirectly) and to which a value in appropriate units can be assigned. Examples include position, momentum, and energy. Unlike in classical physics, the concept of an observable in quantum theory possesses a significance beyond that of the measurable: to each observable there corresponds a unique operator in an abstract, linear vector space. These operators (and others) govern all aspects of quantum systems. Quantum operators act on abstract vectors in the linear space. Especially important are the eigenvectors and eigenvalues of these operators, in particular because some of the eigenvectors are the quantum states mentioned in the preceding chapters. Furthermore, for any operator that is the mathematical image of an observable, its eigenvalues constitute the entire set of values that measurement of the observable can yield . Finally, from the quantum states one can obtain the probabilities for the occurrence of events in the microscopic world, for example, the most likely value that measurement of an observable will yield. The concepts of operators and eigenvalue problems, as well as those of quantal probabilities, of Hermiticity, and of complete sets, were encountered and exemplified in the preceding chapter using the language of differential equations. While much of quantum mechanics could be presented in terms of this language alone, certain fundamental concepts (spin, for instance) cannot be, and it eventually becomes necessary to consider quantum mechanics as a theoretical framework embedded in that abstract linear vector space known as a Hilbert space.

DOI
10.1017/cbo9781139164177.005

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Classical and Quantum Gravity•Mar 1, 1996•69 citations
The quantities in physics that can be measured are conventionally denoted observables : entities that can be observed (directly or indirectly) and to which a value in appropriate units can be assigned. Examples include position, momentum, and energy. Unlike in classical physics, the concept of an observable in quantum theory possesses a significance beyond that of the measurable: to each observable there corresponds a unique operator in an abstract, linear vector space. These operators (and others) govern all aspects of quantum systems. Quantum operators act on abstract vectors in the linear space. Especially important are the eigenvectors and eigenvalues of these operators, in particular because some of the eigenvectors are the quantum states mentioned in the preceding chapters. Furthermore, for any operator that is the mathematical image of an observable, its eigenvalues constitute the entire set of values that measurement of the observable can yield . Finally, from the quantum states one can obtain the probabilities for the occurrence of events in the microscopic world, for example, the most likely value that measurement of an observable will yield. The concepts of operators and eigenvalue problems, as well as those of quantal probabilities, of Hermiticity, and of complete sets, were encountered and exemplified in the preceding chapter using the language of differential equations. While much of quantum mechanics could be presented in terms of this language alone, certain fundamental concepts (spin, for instance) cannot be, and it eventually becomes necessary to consider quantum mechanics as a theoretical framework embedded in that abstract linear vector space known as a Hilbert space.
With the postulates already formulated in the language of an abstract inner product spaces, this chapter shows how an observable can be naturally expressed as a linear Hermitian operator acting on the inner product space where the states live. We start by introducing linear operators acting on vector spaces and their representations. Next, we discuss the systems of eigenvalues and eigenvectors associated with such operators. The important case of Hermitian operator and the properties of their eigenvalues and eigenvectors, relevant to quantum mechanics, are introduced. After developing the necessary background in linear algebra, the connection of Hermitian operators with quantum observables is established. We then proceed to explain what this connection actually accomplishes. In particular, we show how it translates the target questions of quantum mechanics into an eigenvalue problem. This makes it evident what the nature of the input to a quantum theory should be. This input enters the formalism through what are known as “quantization rules”. I discuss this in the last section of this chapter. An illustration using a disguised spin-half system winds up the chapter.
Vectors and operators in a Hilbert space are independent quantities and there is no obvious link between them. The mathematical description of the states and observables of a quantum system given by Postulates 25.1(PS) and 26.1(OV) in terms of vectors and operators does not tell us how a given state would determine the value of an observable. Physically the relationship between states and observables is about how the measurable values of an observable is related to a state. This relationship should lead to the quantum properties QMP5.3(1) to QMP5.3(3). First we must know how a state can give rise to a probability distribution of measurable values of an observable. This would require a prescription to relate a unit vector to the spectrum of selfadjoint operators. The discussion in Chapter 22 tells us how to obtain such a prescription. Because of the intricacy of the relationship both physically and mathematically we shall set out the relationship for discrete and continuous observables separately.
Shall I refuse my dinner because I do not fully understand the process of digestion? No, not if I am satisfied with the result. O. Heaviside, Electromagnetic Theory , vol. 2, 1899 Basic notions of quantum mechanics Quantum axioms Let us start with a brief recapitulation of quantum mechanics on the “how to” level. According to the standard lore, the instantaneous state of any quantum system (that is, everything that can be known about it at a given moment of time) is given by its wave function (state vector) – a complex-valued vector in some abstract Hilbert space; the nature of this space is determined by the system. All the observables (i.e., physical quantities defined for the system and determined by its state – e.g., the position or momentum of a free particle, the energy of an oscillator) are described by Hermitian operators defined in the same Hilbert space. All three elements – the Hilbert space, the state vector, and the set of observables – are necessary to describe the outcome of any experiment one could perform with the system. Since humans cannot directly observe the behaviour of quantum objects, these outcomes are also called measurements , being the result of using some classical apparatus in order to translate the state of a quantum system into the state of the apparatus, which can then be read out by the experimentalist. The classical (i.e., non-quantum) nature of the apparatus is essential, as we shall see in a moment.
Abstract Chapter 9 begins laying a foundation for quantum statistical mechanics with a discussion of relevant topics in quantum mechanics. The fundamental postulates of quantum mechanics are reviewed, beginning with the definition of a quantum state and the introduction of the concept of a state vector in a Hilbert space. The representation of observables as Hermitian operators on Hilbert space vectors is described; it is shown that the eigenvalues of Hermitian operators are real and, therefore, constitute possible outcomes of measurements made on these observables. The notions compatible and non-compatible observables and implication for the measurement problem are presented. The time-dependent Schrödinger equation is introduced as generating the time-evolution of the state vector, and it is shown how to cast the Schrödinger equation into a coordinate basis to yield the wave equation of quantum mechanics. Coordinate and momentum bases and their properties are desribed. Several analytically solvable quantum systems are presented as illustrative examples. The chapter concludes with a discussion of spin and the treatment identical particles
Operators represent physically observable quantities, as discussed in Section 2.5. The structure and property of operators depend on the nature of the degree of freedom; operators act on the state space and in particular on the state vector of a given degree of freedom. The significance of operators in the interpretation of quantum mechanics has been discussed in Baaquie (2013e). The operators discussed in this chapter are mostly based on the continuous degree of freedom, which is analyzed in Section 3.1. Hermitian operators represent physically observable properties of a degree of freedom and their mathematical properties are defined in Section 3.3. The coordinate and momentum operators are the leading exemplar of a pair of noncommuting Hermitian operators and these are studied in some detail in Section 3.4. The Weyl operators yield, as in Section 3.5, a finite-dimensional example of the shift and scaling operators; Section 3.8 provides a unitary representation of the coordinate and momentum operators. The term self-adjoint operator is used for Hermitian operators when there is a need to emphasize the importance of the domain of the Hilbert space on which the operators act – a topic not usually discussed in most books on quantum mechanics. Sections 3.10 and 3.11 discuss the concept of self-adjoint operators, in particular the crucial role played by the domain for realizing the property of self-adjointness. It is shown in Section 3.12 how the requirement of self-adjointness yields a non-trivial extension of Hamiltonians that include singular interactions.
This tome is a formal presentation of the unsharp observable approach to quantum mechanics using the positive operator valued (POV) concept of an observable. It is intended for philosophers and mathematicians as well as physicists. This is a very formalistic book. There are, however, portions that should be read by all experimentalists performing quantum mechanical studies as well as graduate students completing their first graduate year quantum mechanics course. If we interpret quantum mechanics as making statistical predictions on the results of states prepared in identical fashions, we will often find that the observed probabilities are nearly, but not exactly, the expected 1 or 0 for measurements that are expected to always give the same result. Hence, rather than demanding sharp measures with probabilities of exactly 1 or 0, quantum mechanics allows a reasonable interpretation of unsharp results of nearly 1 or nearly 0. As the authors point out in chapter II, POV measures and the associated unsharp measures are not essential for an interpretation of quantum mechanical results. However, more sharp variables, and hence a larger Hilbert space, will be needed than are required by the unsharp approach. Also, the theoretical interpretation will often not be as straightforward with only sharp observables. As I have previously stated, all graduate students, both those of a theoretical and those of an experimental bent, should read parts of this book (after they have completed a normal introduction using sharp variables). They should at least read the first chapter which explains the unsharp variable measure concept as well as giving some examples, one of which is the Stern - Gerlach experiment. In chapter VII, the last chapter, the Stern - Gerlach experiment photon polarization and other quantum optical experiments and wave-particle duality experiments for photons are examined in detail using the POV formalism. This would also be an excellent chapter for all graduate students to read. Some sections may send them back to some of the intermediate chapters, hopefully to peruse in greater detail. The intermediate chapters contain the formal development of the POV formalism and compare it to the normal method. There is also a brief introduction to measurement theory using unsharp observables. As the authors state, this is not intended to be a complete solution to the problem of measurement theory. The next two chapters deal with uncertainty and phase space formalism as considered by the unsharp observables. Philosophers of physics and mathematicians will find this an excellent introduction to the POV formalism and the distinction between sharp and unsharp measurements. Many texts will gloss over both the philosophical and mathematical consequences inherent in the full statistical formalism of quantum mechanics. This monograph is not, by the authors' admission, a full treatment of quantum measurement theory. Also, although in the introduction the authors discuss the importance of applying quantum mechanics to individual objects, this book mainly considers the interpretations as statistical measures. There is little attempt to deal with the quantum mechanical interpretations of the behaviour of a single particle. That is, questions about measurements on a single particle or the interpretation of the wavefunction for a single particle are not fully covered. The authors claim that the POV approach is also the best for individual systems, but do little in applications. The major example given is in the last chapter where they consider interference measurements for single photons. They might have referenced more of the current alternative approaches to measurement theory of single particle wavefunctions. The readers of this journal will be disappointed, but not surprised, that the covariant nature of observables is restricted almost entirely to the Galilei group. The only Poincare group material is the example of photon localization in the last chapter. This is a reflection of the great difficulty of applying the special or the general theories of relativity to the Hilbert space formalism.