Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Physica Scripta

Entropy of a quantum oscillator in a structured environment

Jishad Kumar

Published Aug 8, 2014• 0 citations
Publisher

Abstract

Entropy of a quantum oscillator in the presence of a quantum environment (or heat bath) is studied here. The spectral density, which comprises the environmental influences, here corresponds to a quasi-monochromatic thermal harmonic noise. This further implies that the environment is a structured one compared to the usually employed unstructured strictly ohmic environment. The entropy is found to be vanishing as the temperature approaches its absolute zero value, which thereby guarantees the third law of thermodynamics. At very high temperatures the classical behavior is observed. Similar to the usually employed ohmic-Drude bath model, the coefficient of the leading temperature dependent term in the entropy (at low temperatures) is proportional to the damping strength but not on other parameters of the spectral density characterising the bath.

DOI
10.1088/0031-8949/89/9/095702

Related papers

Quantum Brownian motion and the Third Law of thermodynamics

Peter Hänggi A, Gert‐Ludwig Ingold

The quantum thermodynamic behavior of small systems is investigated in presence of finite quantum dissipation. We consider the archetype cases of a damped harmonic oscillator and a free quantum Brownian particle. A main finding is that quantum dissipation helps to ensure the validity of the Third Law. For the quantum oscillator, finite damping replaces the zero-coupling result of an exponential suppression of the specific heat at low temperatures by a power-law behavior. Rather intriguing is the behavior of the free quantum Brownian particle. In this case, quantum dissipation is able to restore the Third Law: Instead of being constant down to zero temperature, the specific heat now vanishes proportional to temperature with an amplitude that is inversely proportional to the ohmic dissipation strength. A distinct subtlety of finite quantum dissipation is the result that the various thermodynamic functions of the sub-system do not only depend on the dissipation strength but depend as well on the prescription employed in their definition.

arXiv:quant-ph/0601056•Jan 10, 2006•21 citations

QUANTUM BROWNIAN MOTION AND THE THIRD LAW OF THERMODYNAMICS

P. Haenggi, Gert‐Ludwig Ingold

The quantum thermodynamic behavior of small systems is investigated in presence of finite quantum dissipation. We consider the archetype cases of a damped harmonic oscillator and a free quantum Brownian particle. A main finding is that quantum dissipation helps to ensure the validity of the Third Law. For the quantum oscillator, finite damping replaces the zero-coupling result of an exponential suppression of the specific heat at low temperatures by a power-law behavior. Rather intriguing is the behavior of the free quantum Brownian particle. In this case, quantum dissipation is able to restore the Third Law: Instead of being constant down to zero temperature, the specific heat now vanishes proportional to temperature with an amplitude that is inversely proportional to the ohmic dissipation strength. A distinct subtlety of finite quantum dissipation is the result that the various thermodynamic functions of the sub-system do not only depend on the dissipation strength but depend as well on the prescription employed in their definition.

Acta Physica Polonica B•May 1, 2006•46 citations

Anomalous Dissipative Quantum Harmonic Oscillator

Zhan-Wu Bai

We investigate the low-temperature statistical properties of a harmonic oscillator coupled to a heat bath, where the low-frequency spectrum vanishes. We obtain the exact result of the zero point energy. Due to the low frequency shortage of environmental oscillators' spectral density, the coordinate and momentum correlation functions decay as τ−4 and τ−6 respectively at zero temperature, where τ is the correlation time. The low-temperature behavior of the mean energy does not violate the third law of thermodynamics, but differs largely from the Ohmic spectrum case.

Communications in Theoretical Physics•Jan 1, 2008•2 citations

Quantum system under periodic perturbation: Effect of environment

Masahiro Hotta, I. Joichi, Sh. Matsumoto +1 more

In many physical situations the behavior of a quantum system is affected by interaction with a larger environment. We develop, using the method of an influence functional, how to deduce the density matrix of the quantum system incorporating the effect of environment. After introducing the characterization of the environment by spectral weight, we first devise schemes to approximate the spectral weight, and then a perturbation method in field theory models, in order to approximately describe the environment. All of these approximate models may be classified as extended Ohmic models of dissipation whose differences are in the high frequency part. The quantum system we deal with in the present work is a general class of harmonic oscillators with an arbitrary time-dependent frequency. The late time behavior of the system is well described by an approximation that employs a localized friction in the dissipative part of the correlation function appearing in the influence functional. The density matrix of the quantum system is then determined in terms of a single classical solution obtained with the time-dependent frequency. With this one can compute the entropy, the energy distribution function, and other physical quantities of the system in a closed form. A specific application is made to the case of a periodically varying frequency. This dynamical system has a remarkable property when the environmental interaction is switched off: The effect of the parametric resonance gives rise to an exponential growth of the populated number in higher excitation levels, or particle production in field theory models. The effect of the environment is investigated for this dynamical system and it is demonstrated that there exists a critical strength of the friction for the parametric effect. In the model of a periodically oscillating field coupled to a system quantum field, it is verified that the parametric effect occurs in medium, with a somewhat diminished rate, if the relaxation time scale of the system field towards thermalization given by the friction term is larger than the time scale of the coherent parametric amplification. The effect persists until the back reaction against the periodic oscillation stops particle production. The resulting energy distribution of produced particles described by a universal function deviates from the thermal one, having an average energy that exponentially increases with time. The dynamical system driven by the parametric oscillator thus maintains and does not lose its quantum nature even in thermal bath. In the present work analytic formulas of how physical quantities behave at late times both in the high and in the low temperature regions are given, along with the results of a numerical computation displaying time evolution.

arXiv:hep-ph/9608374•Physical review. D. Particles, fields, gravitation, and cosmology/Physical review. D. Particles and fields•Apr 15, 1997•12 citations

The Third Law of Quantum Thermodynamics in the Presence of Anomalous Couplings

Wang Chun-Yang, Bao Jing-Dong

The quantum thermodynamic functions of a harmonic oscillator coupled to a heat bath through velocity-dependent coupling are obtained analytically. It is shown that both the free energy and the entropy decay fast with the temperature in relation to that of the usual coupling from. This implies that the velocity-dependent coupling helps to ensure the third law of thermodynamics.

arXiv:0801.4057•Chinese Physics Letters•Feb 1, 2008•18 citations

Specific heat anomalies of open quantum systems

Gert‐Ludwig Ingold, Peter Hänggi A, Peter Talkner A

The evaluation of the specific heat of an open damped quantum system is a subtle issue. One possible route is based on the thermodynamic partition function which is the ratio of the partition functions of system plus bath and of the bath alone. For the free damped particle it has been shown, however, that the ensuing specific heat may become negative for appropriately chosen environments. Being an open system this quantity then naturally must be interpreted as the change in the specific heat obtained as the difference between the specific heat of the heat bath coupled to the system degrees of freedom and the specific heat of the bath alone. While this difference may become negative, the involved specific heats themselves are always positive; thus, the known thermodynamic stability criteria are perfectly guaranteed. For a damped quantum harmonic oscillator, instead of negative values, under appropriate conditions one can observe a dip in the difference of specific heats as a function of temperature. Stylized minimal models containing a single oscillator heat bath are employed to elucidate the occurrence of the anomalous temperature dependence of the corresponding specific heat values. Moreover, we comment on the consequences for the interpretation of the density of states based on the thermal partition function.

arXiv:0811.3509•Physical Review E•Jun 9, 2009•100 citations
Entropy of a quantum oscillator in the presence of a quantum environment (or heat bath) is studied here. The spectral density, which comprises the environmental influences, here corresponds to a quasi-monochromatic thermal harmonic noise. This further implies that the environment is a structured one compared to the usually employed unstructured strictly ohmic environment. The entropy is found to be vanishing as the temperature approaches its absolute zero value, which thereby guarantees the third law of thermodynamics. At very high temperatures the classical behavior is observed. Similar to the usually employed ohmic-Drude bath model, the coefficient of the leading temperature dependent term in the entropy (at low temperatures) is proportional to the damping strength but not on other parameters of the spectral density characterising the bath.
The quantum thermodynamic behavior of small systems is investigated in presence of finite quantum dissipation. We consider the archetype cases of a damped harmonic oscillator and a free quantum Brownian particle. A main finding is that quantum dissipation helps to ensure the validity of the Third Law. For the quantum oscillator, finite damping replaces the zero-coupling result of an exponential suppression of the specific heat at low temperatures by a power-law behavior. Rather intriguing is the behavior of the free quantum Brownian particle. In this case, quantum dissipation is able to restore the Third Law: Instead of being constant down to zero temperature, the specific heat now vanishes proportional to temperature with an amplitude that is inversely proportional to the ohmic dissipation strength. A distinct subtlety of finite quantum dissipation is the result that the various thermodynamic functions of the sub-system do not only depend on the dissipation strength but depend as well on the prescription employed in their definition.
The quantum thermodynamic behavior of small systems is investigated in presence of finite quantum dissipation. We consider the archetype cases of a damped harmonic oscillator and a free quantum Brownian particle. A main finding is that quantum dissipation helps to ensure the validity of the Third Law. For the quantum oscillator, finite damping replaces the zero-coupling result of an exponential suppression of the specific heat at low temperatures by a power-law behavior. Rather intriguing is the behavior of the free quantum Brownian particle. In this case, quantum dissipation is able to restore the Third Law: Instead of being constant down to zero temperature, the specific heat now vanishes proportional to temperature with an amplitude that is inversely proportional to the ohmic dissipation strength. A distinct subtlety of finite quantum dissipation is the result that the various thermodynamic functions of the sub-system do not only depend on the dissipation strength but depend as well on the prescription employed in their definition.
We investigate the low-temperature statistical properties of a harmonic oscillator coupled to a heat bath, where the low-frequency spectrum vanishes. We obtain the exact result of the zero point energy. Due to the low frequency shortage of environmental oscillators' spectral density, the coordinate and momentum correlation functions decay as τ−4 and τ−6 respectively at zero temperature, where τ is the correlation time. The low-temperature behavior of the mean energy does not violate the third law of thermodynamics, but differs largely from the Ohmic spectrum case.
In many physical situations the behavior of a quantum system is affected by interaction with a larger environment. We develop, using the method of an influence functional, how to deduce the density matrix of the quantum system incorporating the effect of environment. After introducing the characterization of the environment by spectral weight, we first devise schemes to approximate the spectral weight, and then a perturbation method in field theory models, in order to approximately describe the environment. All of these approximate models may be classified as extended Ohmic models of dissipation whose differences are in the high frequency part. The quantum system we deal with in the present work is a general class of harmonic oscillators with an arbitrary time-dependent frequency. The late time behavior of the system is well described by an approximation that employs a localized friction in the dissipative part of the correlation function appearing in the influence functional. The density matrix of the quantum system is then determined in terms of a single classical solution obtained with the time-dependent frequency. With this one can compute the entropy, the energy distribution function, and other physical quantities of the system in a closed form. A specific application is made to the case of a periodically varying frequency. This dynamical system has a remarkable property when the environmental interaction is switched off: The effect of the parametric resonance gives rise to an exponential growth of the populated number in higher excitation levels, or particle production in field theory models. The effect of the environment is investigated for this dynamical system and it is demonstrated that there exists a critical strength of the friction for the parametric effect. In the model of a periodically oscillating field coupled to a system quantum field, it is verified that the parametric effect occurs in medium, with a somewhat diminished rate, if the relaxation time scale of the system field towards thermalization given by the friction term is larger than the time scale of the coherent parametric amplification. The effect persists until the back reaction against the periodic oscillation stops particle production. The resulting energy distribution of produced particles described by a universal function deviates from the thermal one, having an average energy that exponentially increases with time. The dynamical system driven by the parametric oscillator thus maintains and does not lose its quantum nature even in thermal bath. In the present work analytic formulas of how physical quantities behave at late times both in the high and in the low temperature regions are given, along with the results of a numerical computation displaying time evolution.
The evaluation of the specific heat of an open damped quantum system is a subtle issue. One possible route is based on the thermodynamic partition function which is the ratio of the partition functions of system plus bath and of the bath alone. For the free damped particle it has been shown, however, that the ensuing specific heat may become negative for appropriately chosen environments. Being an open system this quantity then naturally must be interpreted as the change in the specific heat obtained as the difference between the specific heat of the heat bath coupled to the system degrees of freedom and the specific heat of the bath alone. While this difference may become negative, the involved specific heats themselves are always positive; thus, the known thermodynamic stability criteria are perfectly guaranteed. For a damped quantum harmonic oscillator, instead of negative values, under appropriate conditions one can observe a dip in the difference of specific heats as a function of temperature. Stylized minimal models containing a single oscillator heat bath are employed to elucidate the occurrence of the anomalous temperature dependence of the corresponding specific heat values. Moreover, we comment on the consequences for the interpretation of the density of states based on the thermal partition function.