With the central role played by scattering in any measurement on a quantum system, in this chapter we introduce the basic formulation of scattering theory for a central potential. As a simple application we consider scattering by a square-well, as well as the scattering by a Coulomb potential.
We consider central-potential scattering and determine a path-integral representation for the S matrix in polar coordinates. This is obtained by transforming to polar coordinates a Cartesian form of the nonrelativistic S matrix given by Campbell et al., and implementing an idea of Faddeev to obtain the appropriate asymptotic conditions. Our results are applied to scattering in an inverse-square potential to determine the correct phase shifts as well as the S matrix.
Most of our knowledge about the structure of matter and interaction between particles is derived from scattering experiments. From a theoretical point of view, scattering problems are concerned with the continuous (and positive) energy eigenvalues and unbound eigenfunctions of the Schro¨dinger equation. We have already encountered one-dimensional examples of scattering in Chapter 4, in the discussion of reflection and transmission of an incident particle with definite momentum from a potential step or barrier. In this chapter we consider scattering from a more formal point of view. We will confine our discussion to elastic scattering (scattering without loss or gain of energy by the projectile) from central potentials although many of the concepts and results are applicable to inelastic scattering.
In this chapter we discuss the quantum theory of scattering of incident particles from the target where an incident beam has point particles, scattering is elastic, the scattering potential is time independent, there is no multiple scattering, and the interaction between an incident particle and a scattering center is described by the potential that depends only on relative positions of particles. Scattering cross-section and frame of reference, asymptotic expansion of wave function and formal expression for scattering amplitude, partial wave analysis, integral equation, and the Born approximation are covered in the chapter, in a broader sense. Free particle and asymptotic solutions, scattering amplitude and phase shift, optical theorem, scattering length, phase shift and its interpretation, scattering by a square well potential and by hard sphere potential, and interpretation of the phase shift and its expression are explained with the use of partial wave analysis. Scattering from bare and screened potentials within the Born approximation, validity of the Born approximation, and the transformation from the center of a mass coordinate system to a laboratory coordinate system are written towards the end of the chapter.
Scattering theory studies the behaviour of (quantum) systems over time and length scales which are very large, compared with the time or length that are characteristic of the interaction which affects them. The chapter begins with an outline of the basic problems of scattering theory, i.e. the existence of scattering states, their uniqueness, weak asymptotic completeness the existence of the scattering transformation, S , the reduction of S due to symmetries, the analyticity of S , asymptotic completeness and the existence of wave operators. After considering the Schrödinger equation for stationary states, the integral equation for scattering problems is derived and studied. The Born approximation and the Born series are presented, and the conditions which ensure convergence of the Born series are also discussed. Further topics are partial wave expansion, its convergence and the uniqueness of the solution satisfying the asymptotic condition, the Levinson theorem. Lastly, in the first part of the chapter, scattering theory from singular potentials is introduced, with emphasis on the polydromy of the wave function, following early work in the literature, and the general problems in the theory of resonances are studied. In the second part, we examine in detail a separable potential model, the occurrence of bound states in the completeness relationship, an excitable potential model and the unitarity of the Möller wave operator. Lastly, we study the survival amplitude associated with quantum decay transitions. Aims and problems of scattering theory Scattering theory is the branch of physics that is concerned with interacting systems on a scale of time and/or distance that is large compared with the scale of the interaction itself, and it provides the most powerful tool for studying the microscopic nature of the world.
We give a pedagogical introduction to time-independent scattering theory in one dimension focusing on the basic properties and recent applications of transfer matrices. In particular, we begin surveying some basic notions of potential scattering such as transfer matrix and its analyticity, multidelta-function and locally periodic potentials, Jost solutions, spectral singularities and their time-reversal, and unidirectional reflectionlessness and invisibility. We then offer a simple derivation of the Lippmann-Schwinger equation and the Born series, and discuss the Born approximation. Next, we outline a recently developed dynamical formulation of time-independent scattering theory in one dimension. This formulation relates the transfer matrix and therefore the solution of the scattering problem for a given potential to the solution of the time-dependent Schrodinger equation for an effective nonunitary two-level quantum system. We provide a self-contained treatment of this formulation and some of its most important applications. Specifically, we use it to devise a powerful alternative to the Born series and Born approximation, derive dynamical equations for the reflection and transmission amplitudes, discuss their application in constructing exact tunable unidirectionally invisible potentials, and use them to provide an exact solution for single-mode inverse scattering problems. The latter, which has important applications in designing optical devices with a variety of functionalities, amounts to providing an explicit construction for a finite-range complex potential whose reflection and transmission amplitudes take arbitrary prescribed values at any given wavenumber.