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Physica A Statistical Mechanics and its Applications

Exact solution of Schrodinger equation for two state problem with time dependent coupling

Diwaker, Bandhan Panda, Aniruddha Chakraborty

Published Sep 26, 2015• 3 citations
Publisher
DOI
10.1016/j.physa.2015.09.054

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Time-dependent unitary transformations are used to study the Schrödinger equation for explicitly time-dependent Hamiltonians of the form H(t)=R(t)⋅J, where R is an arbitrary real vector-valued function of time and J is the angular momentum operator. The solution of the Schrödinger equation for the most general Hamiltonian of this form is shown to be equivalent to the special case R=(1,0,ν(t)). This corresponds to the problem of a driven two-level atom for the spin half representation of J. It is also shown that by requiring the magnitude of R to depend on its direction in a particular way, one can solve the Schrödinger equation exactly. In particular, it is shown that for every Hamiltonian of the form H(t)=R(t)⋅J there is another Hamiltonian with the same eigenstates for which the Schrödinger equation is exactly solved. The application of the results to the exact solution of the parallel transport equation and exact holomony calculation for SU(2) principal bundles (Yang–Mills gauge theory) is also pointed out.
We propose a method to describe the evolution of two spins coupled by hyperfine i nteraction in an external time- dependent magnetic field. We apply the approach to the case of hyperfine interaction with axial symmetry, which can be solved exactly in a constant, appropriately oriented magnetic field. In order to t reat t he n onstationary d ynamical p roblem, we modify the time-dependent Schrödinger equation through a change of representation that, by exploiting an instantaneous (adiabatic) basis makes the time-dependent Hamiltonian diagonal at any time instant. The solution of the transformed time-dependent Schrödinger FRVBUJPO in the form of chronologically ordered exponents with transparent pre-exponential coefficients is reported. This solution is highly simplified when an adiabatically varying magnetic field perturbs the system. The approach here proposed may be used for the perturbative treatment of other dynamical problems with no exact solution.