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Chemical Physics Letters

Exact solution of time-dependent Schrodinger equation for two state problem in Laplace domain

Diwaker, Aniruddha Chakraborty

Published Aug 28, 2015• 4 citations
Publisher
DOI
10.1016/j.cplett.2015.07.020

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Quantum mechanics has about a dozen exactly solvable potentials. Normally, the time-independent Schrödinger equation for them is solved by using a generalized series solution for the bound states (using the Fröbenius method) and then an analytic continuation for the continuum states (if present). In this work, we present an alternative way to solve these problems, based on the Laplace method. This technique uses a similar procedure for the bound states and for the continuum states. It was originally used by Schrödinger when he solved the wave functions of hydrogen. Dirac advocated using this method too. We discuss why it is a powerful approach to solve all problems whose wave functions are represented in terms of confluent hypergeometric functions, especially for the continuum solutions, which can be determined by an easy-to-program contour integral.