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International Journal of Quantum Chemistry

The living state

Albert Szent‐Györgyi, Jane A. McLaughlin

Published Jun 18, 2009• 37 citations
Publisher
DOI
10.1002/qua.560140715

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A method has been proposed for the direct detection and study of long-lived excited states of singly and multiply charged ions of transition and rare earth metals. It allows both the measurement of the photon spectra from the decay of long-lived states of ions with a given charge, as well as the lifetimes of such states, and the investigation of the influence of an electric field on the characteristics of long-lived states. The fast electric-field-induced decay of long-lived states has been found for the first time.
NMR spectroscopy relies on the fact that nuclear spin ensembles in bulk samples under ambient conditions sustain quantum superpositions for durations long enough to implement intricate quantum dynamics. The discovery of long-lived nuclear spin order further enhanced the scope of NMR experiments paving the way for novel applications. In this chapter, we look at the long-lived singlet state (LLSS) from the perspectives of NMR quantum information, wherein the two Zeeman eigenstates of a spin-1/2 nucleus are treated as 0 and 1 states of a quantum bit. In particular, we discuss the following topics: density matrix tomography of the LLSS, initialization of a quantum register via the LLSS, noise spectroscopy of the LLSS, and numerical optimization methods to prepare the LLSS.