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IEEE Transactions on Applied Superconductivity

Fabrication of Nb/Al-N/sub x//NbTiN junctions for SIS mixer applications

B. Bumble, Henry George LeDuc, Jeff A. Stern, Koko G. Megerian

Published Mar 1, 2001• 53 citations
Publisher

Abstract

We discuss fabrication and characteristics of superconductor-insulator-superconductor (SIS) junctions which typically exhibit a 3.5 mV sum-gap voltage. Junctions have a sub-gap to normal state resistance ratio of R/sub SG//R/sub N/=27 for resistance-area products down to R/sub N/A=8 /spl Omega/ /spl mu/m/sup 2/ and high quality junctions have been produced with RNA products as low as 4 /spl Omega/ /spl mu/m/sup 2/. The device structure incorporates a Nb base electrode, a tunnel barrier formed by plasma nitridation of a thin Al proximity layer, and a NbTiN counter-electrode. Results for all Nb junctions with high current density aluminum-nitride barriers are also shown. Nitridation of the aluminum layer is investigated by control of the dc floating potential on a separate rf driven electrode in the vacuum process chamber. Devices are integrated to a mixer antenna structure incorporating NbTiN as a ground plane. The wire circuit layer can be either normal metal or NbTiN. Annealing results show improved I-V characteristics with increased RNA products. Recent receiver measurements employing these junctions exhibit low noise performance up to 900 GHz.

DOI
10.1109/77.919288

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High-quality small-area Nb-AlO/sub x/-Nb junctions have been fabricated by the selective niobium anodization process (SNAP). The influence of the preparation conditions on the junction properties were investigated. Numerical calculations based on I-V (current-voltage) characteristics measured by a data acquisition system were used to simulate the mixer performance. It has been shown that the knee-shaped structure on the I-V curve of refractory material junctions significantly affects the signal properties of the mixer. The signal and noise properties for different types of integrated SIS (superconductor-insulator-superconductor) mixing elements have been investigated experimentally in the frequency range of 37-53 GHz; the mixer conversion loss was as low as 4 dB at 45 GHz. The mixing elements consist of an odd number of SIS junctions connected in series for RF and in parallel for DC biasing. The DC bias wiring and IF (intermediate frequency) filters of these structures were designed to provide tuning out of junction capacitance and thin-film-electrode inductance.>

IEEE Transactions on Magnetics•Mar 1, 1989•7 citations
We discuss fabrication and characteristics of superconductor-insulator-superconductor (SIS) junctions which typically exhibit a 3.5 mV sum-gap voltage. Junctions have a sub-gap to normal state resistance ratio of R/sub SG//R/sub N/=27 for resistance-area products down to R/sub N/A=8 /spl Omega/ /spl mu/m/sup 2/ and high quality junctions have been produced with RNA products as low as 4 /spl Omega/ /spl mu/m/sup 2/. The device structure incorporates a Nb base electrode, a tunnel barrier formed by plasma nitridation of a thin Al proximity layer, and a NbTiN counter-electrode. Results for all Nb junctions with high current density aluminum-nitride barriers are also shown. Nitridation of the aluminum layer is investigated by control of the dc floating potential on a separate rf driven electrode in the vacuum process chamber. Devices are integrated to a mixer antenna structure incorporating NbTiN as a ground plane. The wire circuit layer can be either normal metal or NbTiN. Annealing results show improved I-V characteristics with increased RNA products. Recent receiver measurements employing these junctions exhibit low noise performance up to 900 GHz.
We have fabricated and tested submillimeter-wave superconductor–insulator–superconductor (SIS) mixers using very high-current-density Nb/AlN/Nb tunnel junctions (Jc≈30 kA cm−2). The junctions have low-resistance-area products (RNA≈5.6 Ω μm2), good subgap-to-normal resistance ratios Rsg/RN≈10, and good run-to-run reproducibility. From Fourier transform spectrometer measurements, we infer that ωRNC=1 at 270 GHz. This is a factor of 2.5 improvement over what is generally available with Nb/AlOx/Nb junctions suitable for low-noise mixers. The AlN-barrier junctions are indeed capable of low-noise operation: we measure an uncorrected double-sideband receiver noise temperature of TRX=110 K at 533 GHz for an unoptimized device. In addition to providing wider bandwidth operation at lower frequencies, the AlN-barrier junctions will considerably improve the performance of THz SIS mixers by reducing rf loss in the tuning circuits.
A description of the fabrication technology of high-quality tunnel SIS junctions is presented, with following characteristics: energy gap in superconductors Vg=3.2-3.4 mV, tunnel current density up to J 35 kA/cm2, quality factor Rj/Rn (ratio of subgap resistance to normal-state resistance) up to 30, junction area up to 1 μm2. The SIS junctions are integrated into the NbTiN|SiO2|Al microstrip line. Keywords: superconducting devices, superconductor--insulator--superconductor tunnel junction, plasma etching.
A modified SNIP process was used to fabricate high-quality 0.5, 2, and 4 mu m/sup 2/ small-area Nb/AlO/sub x//Nb trilayer tunnel junctions with current densities as large as 5000 A/cm/sup 2/. The average junction quality factors for the junctions at 4.4 K were V/sub m/(2 mV)=39 mV for J/sub c/=3000 A/cm/sup 2/ and V/sub m/ (2 mV)=27 mV for J/sub c/=5000 A/cm/sup 2/. The best values of V/sub m/ obtained were 50 mV for J/sub c/=3000 A/cm/sup 2/ and 41 mV for J/sub c/=5000 A/cm/sup 2/. These devices were designed and fabricated for use in a W-band mixer receiver. The substrate was 50- mu m-thick fused or crystal quartz. Special methods were developed for handling such thin insulating substrates and patterning films. The fabrication process was self-aligned and used SiO/sub 2/ instead of anodized Nb as the thick insulator. SiO/sub 2/ isolated the junction area and defined the opening for contact to the Nb wiring layer. The authors have fabricated series arrays of up to 12 junctions, with individual junction areas of 0.5 mu m/sup 2/. The array I-V quality was not degraded compared to that of an individual junction.
SIS mixers incorporating two-junction, NbTiN tuning-circuits have been designed and fabricated using two different types of tunnel-junctions. The first type of tunnel junction-NbTiN/MgO/NbTiN--has the advantage of a large gap voltage (5 mV), but has a relatively soft I-V characteristic and high specific capacitance as compared to Nb/Al-Ox/Nb tunnel-junctions. The second type of junction--Nb/Al-AlNx/NbTiN, is a hybrid structure, which has many of the advantages of Nb junctions, with a slightly larger energy gap voltage (3.5 mV) and more robust thermal properties. A detailed description of the deposition techniques used in making the AlNx devices will be given in a separate paper. In this paper, we discuss the deposition of high-quality NbTiN films, and the trade-off between stress and quality in these films. We also discuss the deposition details for the NbTiN/MgO/NbTiN junctions. We measured the magnetic-penetration-depth of our NbTiN films with SQUID circuits. Using long resonators coupled to Josephson junctions, we measured propagation velocities for our microstrip-line circuits; this measurement gave us an independent estimate of the NbTiN magnetic-penetration-depth and a qualitative measure of RF-losses in the microstrip-lines.
Two years ago, we have fabricated and tested superconductor-insulator-superconductor (SIS) mixers based on Nb/AlN/NbN twin tunnel junctions for waveguide receiver operating in frequency range of 790 - 950 GHz, which demonstrated noise temperature from 250 K at low frequencies to 500 K at the high end of the band. Due to high current density of the junctions (up to 30 kA/cm2 ), a wideband design was realized. Based on result for twin junction, a new mixer design with single SIS junction was proposed and produced. The single junction design is expected to have narrower frequency range than twin-based one, but still wide enough, and provide better coupling in the middle of the band. In addition, the critical current suppression will be much better, than for twin junction, which has an intrinsic problem of difference between areas of individual junctions. The SIS junction in new design is made by Nb/AlN/NbN technology and incorporated in a microstrip line consisting of a 300 nm thick bottom electrode (ground plane) made of NbTiN and a 500 nm thick top electrode made of Al. The top Al electrode is passivated by the SiO2 layer for protection. The DC tects of the fabricated wafer shows, that optimization of the technology allowed to realize gap voltage of 3.2 mV even for junctions of 0.5 square micron area fabricated on the NbTiN bottom layer. The FTS and noise temperature measurement of new mixers will be done in the nearest future and will be presented in comparison with the twin junction design results at the conference.
High-quality small-area Nb-AlO/sub x/-Nb junctions have been fabricated by the selective niobium anodization process (SNAP). The influence of the preparation conditions on the junction properties were investigated. Numerical calculations based on I-V (current-voltage) characteristics measured by a data acquisition system were used to simulate the mixer performance. It has been shown that the knee-shaped structure on the I-V curve of refractory material junctions significantly affects the signal properties of the mixer. The signal and noise properties for different types of integrated SIS (superconductor-insulator-superconductor) mixing elements have been investigated experimentally in the frequency range of 37-53 GHz; the mixer conversion loss was as low as 4 dB at 45 GHz. The mixing elements consist of an odd number of SIS junctions connected in series for RF and in parallel for DC biasing. The DC bias wiring and IF (intermediate frequency) filters of these structures were designed to provide tuning out of junction capacitance and thin-film-electrode inductance.>