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Journal de physique

Transport properties in a spin polarized gas, II

C. Lhuillier, Franck Laloë

Published Jan 1, 1982• 129 citations
Publisher

Abstract

The general results obtained in the preceding article are applied to the study of transport phenomena in a spin polarized gas at low temperatures, with particular emphasis on the particle indistinguishability effects in collisions. The effects of the nuclear orientation M are treated exactly (no M expansion). First, a simple theory of spin diffusion is presented and the response of the gas to a spin orientation gradient is calculated. The spin coherences and their evolution due to the « identical-spin rotation effect » are taken into account; it is found that they can play an important role, especially in the low temperature limit. The hydrodynamic equations of evolution of M are non-linear and anisotropic. Particle indistinguishability effects give an oscillatory character to the evolution of the transverse components of M (spin oscillations). Then, a more elaborate variational method is used to study the coupling between spin diffusion and heat conduction. This effect is, again, a sheer consequence of quantum interference phenomena introduced by particle indistinguishability. Finally, isotopic mixtures of 3He and 4He are considered In addition to coupling between isotopic diffusion and heat conduction, which exists for classical systems, quantum collision effects introduce a coupling between these two modes and spin diffusion.

DOI
10.1051/jphys:01982004302022500

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Transport properties in a spin polarized gas, III

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A complete quantum phase shift calculation of several transport coefficients in spin polarized quantum gases (3He, H↑ and D↑) has been carried out for temperatures ranging from 0.04 K to 10 K and nuclear polarizations M varying from 0 to 1. After a detailed analysis of the dynamical features of the collision, the various direct and exchange « cross sections » necessary to describe the collision between two spin-polarized atoms are studied Emphasis is then placed on some particle-indistinguishability consequences that could be seen in 3He or H↑ systems, such as the strong M dependence of the heat capacity, a mode coupling between heat capacity and longitudinal spin diffusion and the oscillatory character of the evolution of the transverse components of M.

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Hyperfine and electronic spin waves in atomic hydrogen : the role of the spin exchange process

J. P. Bouchaud, C. Lhuillier

The identical spin rotation effect is the quantum mechanical collisional effect underlying the transverse nuclear spin waves recently seen in dilute non degenerate gases in Paris [3He] and at Cornell University [H↓]. This mechanism could in principle give rise, at low enough temperatures, to hydrodynamic oscillatory modes associated with any non diagonal elements of the atomic internal density matrix (generalized spin waves or coherences waves). Starting from a quantum Boltzmann equation recently derived for the study of 4-component atomic hydrogen, we show that the current of any transverse quantity (hyperfine or Zeeman coherence) does indeed precess around molecular exchange fields. Unhappily, in most cases, the oscillatory modes associated with these transverse quantities are heavily damped. The first intrinsic cause of damping of these waves is spin exchange. We study the conditions under which this damping is minimized in both zero field and in high magnetic field. Numerical values of all relevant parameters for the description of spin transport properties in atomic hydrogen are given in the appendices.

Journal de physique•Jan 1, 1985•7 citations
The general results obtained in the preceding article are applied to the study of transport phenomena in a spin polarized gas at low temperatures, with particular emphasis on the particle indistinguishability effects in collisions. The effects of the nuclear orientation M are treated exactly (no M expansion). First, a simple theory of spin diffusion is presented and the response of the gas to a spin orientation gradient is calculated. The spin coherences and their evolution due to the « identical-spin rotation effect » are taken into account; it is found that they can play an important role, especially in the low temperature limit. The hydrodynamic equations of evolution of M are non-linear and anisotropic. Particle indistinguishability effects give an oscillatory character to the evolution of the transverse components of M (spin oscillations). Then, a more elaborate variational method is used to study the coupling between spin diffusion and heat conduction. This effect is, again, a sheer consequence of quantum interference phenomena introduced by particle indistinguishability. Finally, isotopic mixtures of 3He and 4He are considered In addition to coupling between isotopic diffusion and heat conduction, which exists for classical systems, quantum collision effects introduce a coupling between these two modes and spin diffusion.
A complete quantum phase shift calculation of several transport coefficients in spin polarized quantum gases (3He, H↑ and D↑) has been carried out for temperatures ranging from 0.04 K to 10 K and nuclear polarizations M varying from 0 to 1. After a detailed analysis of the dynamical features of the collision, the various direct and exchange « cross sections » necessary to describe the collision between two spin-polarized atoms are studied Emphasis is then placed on some particle-indistinguishability consequences that could be seen in 3He or H↑ systems, such as the strong M dependence of the heat capacity, a mode coupling between heat capacity and longitudinal spin diffusion and the oscillatory character of the evolution of the transverse components of M.
We carried out experiments on a spin polarized 3He- 4He mixture with 3He concentration x 3 = 6.26 × 10−4, and on pure 3He liquid. Spin polarization affects the transport properties of these Fermi systems. The effect on momentum transport was studied by using a vibrating-wire viscometer to measure viscosity of the 3He-4He mixture over the temperature range 6.09 mK–100 mK in 7.96 T and 1.00 T magnetic fields. A large viscosity increase was observed upon application of the 7.96 T magnetic field for temperature T < TF(TF = 19.5 mK is the Fermi temperature). The observed viscosity is in very good agreement with theoretical calculations for a dilute Fermi gas by Jeon and Mullin [1988, 1989] and Mullin and Jeon [1992]. The polarization effect on spin transport was investigated by measuring the transverse diffusion coefficient D ⊥ in pure 3He liquid at saturated vapor pressure and at 15.85 bar over the temperature range 4.5 mK–159 mK in a 7.96 T magnetic field. We used a pulsed NMR spin echo technique in a field gradient of 16.0 G/cm to do the measurements and fits to the Leggett equations [1970] to obtain D⊥. For T < 20 mK, we found D⊥ is less than measured in earlier experiments at lower magnetic fields. D⊥ does not increase with decreasing temperature as 1/T2, but appears to approach a constant as T → 0 while it is expected that the longitudinal spin diffusion coefficient D∥ ∝ 1/ T2. This is called spin diffusion anisotropy and it was observed for the first time in our 3He liquid experiments. The anisotropy temperature we determined for 3He liquid was Ta = 16.4 ± 2.2 mK at saturated vapor pressure and in a 7.96 T magnetic field. The transverse spin diffusion in 3 He results agree qualitatively with theories proposed by Meyerovich and Musaeflan [1992, 1994]. They also agree qualitatively with theories proposed by Golosov and Ruckenstein [1995, 1998] by extrapolation of the dilute theory to a strongly interacting system.
This article gives a theoretical study of the effects of weak magnetic field gradients on the spin relaxation of a dilute atomic gas. The theory is valid for low or moderate values of the field (the relevant correlation time of the gas is then the diffusion time across the container) as well as for high fields (the intercollision time then plays the most important role). Quantum effects due to particle indistinguishability are included. No consequences of the divergence of the atomic mean free path in a polarized gas at zero temperature are found, in contrast to the situation for viscosity and heat conductivity. On the other hand, substantial effects due to « identical spin rotation effects » are predicted.
The general results recently obtained for the Boltzmann collision term in a gas of atomic hydrogen are applied to the study of longitudinal spin diffusion in high magnetic fields. This phenomenon can be described as a diffusion of concentration in a four component reactive mixture (the reaction being here the electronic transfer between nuclei). A numerical discussion of all the coefficients of the diffusion matrix between 100 mK to 100 K is given in the text, together with a discussion of the nature of the hydrodynamic modes in such a situation. The variations of the diffusion coefficients with the internal state of the gas are important for temperatures lower than 500 mK or higher than 10 K, when the spin exchange process is not negligible compared to the direct process. Finally, the relative importance of these two processes determines the nature of the hydrodynamic modes in the system.
Diffusion plays a major role in describing how particles and heat move in any nonequilibrium system. The diffusion of quantum properties is not as well understood as the diffusion of classical properties, especially at low temperatures or high densities. Exploring the diffusion of the quantum property known as spin is beneficial for explaining quantum effects that arise at low temperatures or high densities, and this knowledge acquired could assist in the development of new ultra-low-power devices. This thesis examines spin diffusion at various temperatures and densities using the highly-tunable experimental platform of ultracold atoms. Around one million rubidium-87 atoms are cooled to nanokelvin temperatures to create an ultracold gas, where quantum interactions between atoms can significantly modify spin diffusion compared to classical diffusion. One-dimensional spin diffusion is observed for an initial two-domain spin profile. Remarkably, diffusion of this spin profile is slowed at temperatures above quantum degeneracy, where the ultracold gas is largely classical but with quantum collisions. We demonstrate that this slowing of spin diffusion is due to the presence of spin coherence between spin domains, and that the removal of coherence speeds up spin diffusion to classical timescales. Spin diffusion is further modified by applying a linear differential potential that can speed, slow, or stop spin diffusion of a two-domain spin profile. Differential potentials spatially alter the precession of spins, which then alters the spin-rotating quantum collisions that modify spin diffusion. For a linear differential potential with a specific sign and magnitude, stabilized spin domains in an ultracold gas are observed for 40 times longer than classical diffusion timescales. In addition to modifying spin diffusion with coherence and differential potentials, we demonstrate arbitrary control of one-dimensional spin diffusion using temporally varying differential potentials and three-domain spin profiles. These spin diffusion modifying techniques could be useful for manipulating spin in other nonequilibrium systems, and set the stage for simulating spin-based devices in ultracold atoms.
The identical spin rotation effect is the quantum mechanical collisional effect underlying the transverse nuclear spin waves recently seen in dilute non degenerate gases in Paris [3He] and at Cornell University [H↓]. This mechanism could in principle give rise, at low enough temperatures, to hydrodynamic oscillatory modes associated with any non diagonal elements of the atomic internal density matrix (generalized spin waves or coherences waves). Starting from a quantum Boltzmann equation recently derived for the study of 4-component atomic hydrogen, we show that the current of any transverse quantity (hyperfine or Zeeman coherence) does indeed precess around molecular exchange fields. Unhappily, in most cases, the oscillatory modes associated with these transverse quantities are heavily damped. The first intrinsic cause of damping of these waves is spin exchange. We study the conditions under which this damping is minimized in both zero field and in high magnetic field. Numerical values of all relevant parameters for the description of spin transport properties in atomic hydrogen are given in the appendices.