International Journal of Quantum Chemistry
Enhanced probability for the photoelectric effect in a Faraday cage
John Avery
Abstract
Abstract The cross section for the photoelectric effect is calculated for the case where the photoionization takes place within a Faraday cage held at a constant electrostatic potential. When the geometry has spherical symmetry, and when the potential is repulsive, the cross section is enhanced by a factor E/(E − V0). The predicted effect is a purely quantum mechanical one, since according to classical electrodynamics, no forces due to the potential of the cage will act on a charged particle in the fieldfree region inside it. In quantum theory, the effect arises because the continuum states extend to the region outside the cage.