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Mathematical Proceedings of the Cambridge Philosophical Society

The Matrix Mechanics of the Spinning Electron

George Frederick James Temple

Published Oct 1, 1930• 1 citation
Publisher

Abstract

In three earlier papers the author has developed the theory of the operational wave equation, which was originally suggested by Professor Eddington as the most extensive generalisation possible of the linear wave equation devised by Dirac. The wave function,ψ, plays a very minor rô1e in the development of this theory and, in reality, it is introduced simply to provide an operand which shall be patient of the action of the wave operators, A1, A2, A3, A4. The object of this paper is to show that the wave function may be entirely eliminated from the theory, which then takes the form of a “ matrix mechanics,” i.e. a set of relations between matrices representing the coordinates, the momenta and the spin operators.

DOI
10.1017/s0305004100016273

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In three earlier papers the author has developed the theory of the operational wave equation, which was originally suggested by Professor Eddington as the most extensive generalisation possible of the linear wave equation devised by Dirac. The wave function,ψ, plays a very minor rô1e in the development of this theory and, in reality, it is introduced simply to provide an operand which shall be patient of the action of the wave operators, A1, A2, A3, A4. The object of this paper is to show that the wave function may be entirely eliminated from the theory, which then takes the form of a “ matrix mechanics,” i.e. a set of relations between matrices representing the coordinates, the momenta and the spin operators.
In two recent papers Dirac has shown how the “duplexity” phenomena of the atom can be accounted for without recourse to the hypothesis of the spinning electron. The investigation is carried out by the methods of non-commutative algebra, the wave function ψ being a matrix of the fourth order. An alternative presentation of the theory, using the methods of wave mechanics, has been given by Darwin. The four-rowed matrix ψ is replaced by four wave functions ψ1, ψ2, ψ3, ψ4 satisfying four linear differential equations of the first order. These functions are related to one particular direction, and the work can only be given invariance of form at the expense of much additional complication, the four wave functions being replaced by sixteen.
Abstract 1. In a recent paper Dirac* has brilliantly removed the defects before existing in the mechanics of the electron, and has shown how the phenomena usually called the “ spinning electron ” fit into place in the complete theory. He applies to he problem the method of q-numbers and, using non-commutative algebra, exhibits the properties of a free electron, and of an electron in a central field of electric force. In a second paper † he also discusses the rules of combination and the Zeeman effect. There are probably readers who will share the present writer’s feeling that the methods of non-commutative algebra are harder to follow, and certainly much more difficult to invent, than are operations of types long familiar to analysis. Wherever it is possible to do so, it is surely better to present the theory in a mathematical form that dates from the time of Laplace and Legendre, if only because the details of the calculus have been so much more thoroughly explored. So the object of the present work is to take Dirac’s system and treat it by the ordinary methods of wave calculus. The chief point of interest is perhaps the solution of the problem of the central field, which can be carried out exactly and leads to Sommerfeld’s original formula for the hydrogen levels. But it is also of some interest to exhibit the relationship of the new theory to the previous equations which were derived empirically by the present writer.* It appears that those equations were an approximation to the new ones, derived by an approximate elimination of two of Dirac’s four wave functions. We shall also review a few other points connected with the free electron, the emission of radiation from an atom and its magnetic moment, and shall outline a discussion of the Zeeman effect.
Abstract 1. There are two problems which are fundamental to wave mechanics— that of deducing from first principles the properties of the wave field of ψ, by means of which, on modern theory, the mechanical properties of matter are to be described, and that of formulating a logical description of the properties of matter in terms of ψ. The former only of these problems is discussed in this communication. In spite of many valuable papers that have been published on the subject of Dirac’s remarkable wave equation, the derivation of the equation still seemed (to the present writer, at any rate,) to include some obscurities which could perhaps be removed. To some extent this is owing to the development of the equation, as a matter of historical necessity, having come about by successive extensions to classical mechanics; so that some difficulties have been produced by the fundamental relativity considerations having been introduced into the theory at a late stage, instead of in their proper place at the beginning. In what follows, by treating the problem from the beginning as a four-dimensional one, a deduction of the wave equation free from empirical steps is, I think, obtained, while also certain new features of the equation are brought to light. 2. The Principle of Action.—The method of four-dimensional mechanics is to assume that the motions of bodies in the world can be represented by “tracks,” or curved lines, in a “fourfold.” (This last term will be used here to mean a four-dimensional manifold with Euclidian geometry, i. e., in which ds2 = dxi2 (i = 1, . . . 4).) (1) Uniform motion in the world is represented by straight line tracks in the fourfold, and the “classical relativity” laws of motion are derived by formulating the simplest mathematical specification of curved tracks which will represent the non-uniform motions of bodies that are usually observed in the world.
Till 1925 the idea of what the quantum theory would be was unknown. During 1925 three different but equivalent versions of quantum theory were proposed – Schrödinger-proposed wave mechanics; Heisenberg-developed matrix mechanics and Dirac-introduced operator theory. Considering the de Broglie’s matter waves Erwin Schrödinger, an Austrian physicist, argued that if a particle like an electron behaves as a wave then the equation of wave motion could be successfully applied to it. He postulated a function varying in both space and time in a wave-like manner (hence called wave function and denoted it as ψ). This function is generally complex and assumed to contain information about a system. Schrödinger set up a linear and time-dependent wave-like equation, called Schrödinger wave equation, to describe the wave aspect of a particle taking account of de Broglie’s relation for wavelength. Physically, |ψ(X, t)|2, where ψ(X, t) is the solution of the Schrödinger equation, is interpreted as position probability density. That is, |ψ(X, t)|2 is the probability density of observing a particle at position X at time t. ψ does not give exact outcomes of observations but helps us to know all possible events and their probabilities . Further, the probability interpretation allows us to find the average or expected result of a set of measurements on a quantum system.
In this article, we discard the bra-ket notation and its correlative definitions, given by Paul Dirac. The quantum states are only described by the wave functions. The fundamental concepts and definitions in quantum mechanics is simplified. The operator, wave functions and square matrix are represented in the same expression which directly corresponds to the system of equations without additional introduction of the matrix representation of operator. It can make us to convert the operator relations into the matrix relations. According to the relations between the matrices, the matrix elements will be determined. Furthermore, the first order differential equations will be given to find the solution of equations. As a result, we unified the descriptions of the matrix mechanics and the wave mechanics.