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Chemical Physics Letters

Multiple quantum coherences in liquid state NMR and nonlinear optics: collective vs local origin

Shaul Mukamel, Andreas Tortschanoff

Published May 1, 2002• 20 citations
Publisher
DOI
10.1016/s0009-2614(02)00408-6

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It is shown that in nuclear magnetic resonance, multiple-quantum (MQ) coherences can be detected "instantly" by exploiting the principle of quantum-mechanical projective measurement. Therefore, the mixing period, which involves collective multispin dynamics and converts MQ coherences into observable single-quantum coherence (magnetization), is not necessary. The experimental examples are given for two finite clusters: benzene in liquid crystal and liquid crystal 4'-n-pentyl-4-cyanobiphenyl, and for solid adamantane with an infinite network of dipolar couplings.