Abstract We obtain accurate eigenvalues of the one-dimensional Schrödinger equation with a Hamiltonian of the form H g = H + gδ(x), where δ(x) is the Dirac delta function. We show that the well known Rayleigh–Ritz variational method is a suitable approach provided that the basis set takes into account the effect of the Dirac delta on the wavefunction. Present analysis may be suitable for an introductory course on quantum mechanics to illustrate the application of the Rayleigh–Ritz variational method to a problem where the boundary conditions play a relevant role and have to be introduced carefully into the trial function. Besides, the examples are suitable for motivating the students to resort to any computer-algebra software in order to calculate the required integrals and solve the secular equations.
Both single-well and multiwell one-dimensional anharmonic oscillators have provided an extremely fruitful testing ground for various modern techniques of microscopic quantum many-body theory and quantum field theory. They have served both as (0+1)-dimensional field-theory models of their important counterparts in a higher number of dimensions, and as algebraically simple yet highly nontrivial problems on which various approximation or truncation schemes could be tested to very high orders. Such techniques have included perturbation theory and its many possible resummation schemes, and the coupled-cluster method. In the present paper the spotlight is focused on variational methods, and we concentrate on their application to the particularly demanding double-well quartic anharmonic oscillator. We examine in detail both single-state and multistate variational calculations based on either orthogonal (uncorrelated) or nonorthogonal (correlated) basis functions. Particular attention is paid to the question of the sensitivity and accuracy of the results with respect to any nonlinear parameters that characterize the basis states. Practical schemes are suggested for their choice and are shown to be capable of very high accuracy. Use of this simple model also allows detailed comparisons to be made with other techniques of a perturbative or perturbative-variational hybrid character.
The eigenvalue problem in of Schrödinger operators with a polynomial perturbation has been replaced by one corresponding to the system confined in a box with impenetrable walls. It is shown that the Dirichlet and the von Neumann problems in generate upper and lower bounds, respectively, to the eigenvalues of the unbounded system. To illustrate the method, rapidly converging two-sided bounds for the energy levels of two- and three-well oscillators are presented, using simple trigonometric basis functions.
We present a systematic study of the Rayleigh--Ritz variational method for quantum oscillators in the Segal--Bargmann space. We rigorously derive the normalizability condition
∣α∣<21 for generalized Gaussian trial functions
ψ(z)=eαz2+βz through convergence analysis of Gaussian integrals in the complex plane. Applications to the harmonic oscillator demonstrate exact recovery of the ground state in Segal--Bargmann space when the trial family contains the true solution. For the quartic anharmonic oscillator (
H^=−21∂x2+21x2+λx4), adaptive Gaussian ansätze in position space yield a cubic stationarity equation and perturbative energy expansions beyond first order, capturing anharmonic wavefunction narrowing. In contrast, monomial trial functions (
ψn(z)=zn) in the Segal--Bargmann space -- while providing rigorous upper bounds
En=n+21+43λ(2n2+2n+1) for excited states -- lack width adaptability and are limited to first-order accuracy for ground-state calculations. We further analyze displaced Gaussians and displaced monomials for asymmetric potentials (e.g.,
x3+x4), showing that displacement parameters are essential to capture parity breaking and stabilization effects (
E0≈21+43μ−49λ2+⋯).