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International Journal of Quantum Chemistry

Dissipative and fluctuation phenomena in quantum mechanics with applications

Robert F. O’Connell

Published Jan 1, 1996• 17 citations
Publisher

Abstract

Classical dissipative and fluctuation phenomena have a long history beginning with the experimental work on Brownian motion in 1827 and its theoretical explanation by Einstein in 1905, followed by Langevin's elegant explanation in 1908 when he introduced the idea of a stochastic differential equation. While we briefly review this history, our emphasis is on stochastic phenomena requiring quantum mechanics. We discuss many problems in a variety of areas and point out the merits of a quantum generalized Langevin equation in providing a universal framework for the solution of such problems. As an example, we analyze in detail the problem of radiation reaction in quantum electrodynamics. © 1996 John Wiley & Sons, Inc.

DOI
10.1002/(sici)1097-461x(1996)58:6<569::aid-qua3>3.0.co;2-w

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arXiv:quant-ph/0509058•Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE•May 23, 2005•1 citation
Classical dissipative and fluctuation phenomena have a long history beginning with the experimental work on Brownian motion in 1827 and its theoretical explanation by Einstein in 1905, followed by Langevin's elegant explanation in 1908 when he introduced the idea of a stochastic differential equation. While we briefly review this history, our emphasis is on stochastic phenomena requiring quantum mechanics. We discuss many problems in a variety of areas and point out the merits of a quantum generalized Langevin equation in providing a universal framework for the solution of such problems. As an example, we analyze in detail the problem of radiation reaction in quantum electrodynamics. © 1996 John Wiley & Sons, Inc.
Abstract General concepts in the theory of fluctuations and dissipation are reviewed and applied to examples in quantum optics. Brownian motion, Fokker-Planck and Langevin equations, and the Wiener-Khintchine theorem are reviewed, followed by a derivation and discussion of the fluctuation-dissipation theorem. The general problem of an oscillator coupled to a heat bath is revisited, as is the nonrelativistic theory of radiation reaction. The general ideas about fluctuations and dissipation developed in the first part of the chapter are then applied to the theory of the fundamental laser linewidth, the photon statistics of linear amplifiers and attenuators, the noise figure, amplified spontaneous emission, and the quantum theory of the beam slitter and homodyne detection.
A simple scheme of unified description of different physical phenomena by using the Langevin type equations is reviewed. Within this approach much attention is being paid to the study of Brownian and quantum motions. Stochastic equations with a white noise term give all characteristics of the Brownian motion. Some generalization of the Langevin type equations allows us to obtain nonlinear equations of particles' motion, which are formally equivalent to the Schrödinger equation. Thus, we establish Nelson's stochastic mechanics on the basis of the Langevin equation.
A model independent generalization of quantum mechanics, including the usual as well as the dissipative quantum systems, is proposed. The theory is developed deductively from the basic principles of the standard quantum theory, the only new qualitative assumption being that we allow the wave operator at time t of a quantum system to be non-differentiable (in t) in the usual sense, but only in an appropriately defined (Sec. 5) stochastic sense. The resulting theory is shown to lead to a natural generalization of the usual quantum equations of motion, both in the form of the Schrödinger equation in interaction representation (Sec. 6) and of the Heisenberg equation (Sec. 8). The former equation leads in particular to a quantum fluctuation-dissipation relation of Einstein’s type. The latter equation is a generalized Langevin equation, from which the known form of the generalized master equation can be deduced via the quantum Feynmann-Kac technique (Secs. 9 and 10). For quantum noises with increments commuting with the past the quantum Langevin equation defines a closed system of (usually nonlinear) stochastic differential equations for the observables defining the coefficients of the noises. Such systems are parametrized by certain Lie algebras of observables of the system (Sec. 10). With appropriate choices of these Lie algebras one can deduce generalizations and corrections of several phenomenological equations previously introduced at different times to explain different phenomena. Two examples are considered: the Lie algebra [q, p]=i (Sec. 12), which is shown to lead to the equations of the damped harmonic oscillator; and the Lie algebra of SO(3) (Sec. 13) which is shown to lead to the Bloch equations. In both cases the equations obtained are independent of the model of noise. Moreover, in the former case, it is proved that the only possible noises which preserve the commutation relations of p, q are the quantum Brownian motions, commonly used in laser theory and solid state physics.
In the frames of classical mechanics the generalized Langevin equation is derived for an arbitrary mechanical subsystem coupled to the harmonic bath of a solid. A time-acting temperature operator is introduced for the quantum Klein-Kramers and Smoluchowski equations, accounting for the effect of the quantum thermal bath oscillators. The model of Brownian emitters is theoretically studied and the relevant evolutionary equations for the probability density are derived. The Schrodinger equation is explained via collisions of the target point particles with the quantum force carriers, transmitting the fundamental interactions between the point particles. Thus, electrons and other point particles are no waves and the wavy chapter of quantum mechanics originated for the force carriers. A stochastic Lorentz-Langevin equation is proposed to describe the underlaying Brownian-like motion of the point particles in quantum mechanics. Considering the Brownian dynamics in the frames of the Bohmian mechanics, the density functional Bohm-Langevin equation is proposed, and the relevant Smoluchowski-Bohm equation is derived. A nonlinear master equation is proposed by proper quantization of the classical Klein-Kramers equation. Its equilibrium solution in the exact canonical Gibbs density operator, while the well-known Caldeira-Leggett equation is simply a linearization at high temperature. In the case of a free quantum Brownian particles, a new law for the spreading of the wave packet it discovered, which represents the quantum generalization of the classical Einstein law of Brownian motion. A new projector operator is proposed for the collapse of the wave function of a quantum particle moving in a classical environment. Its application results in dissipative Schrodinger equations, as well as in a new form of dissipative Liouville equation in classical mechanics.
Abstract This review provides a brief and quick introduction to the quantum Langevin equation for an oscillator, while focusing on the steady-state thermodynamic aspects. A derivation of the quantum Langevin equation is carefully outlined based on the microscopic model of the heat bath as a collection of a large number of independent quantum oscillators, the so-called independent-oscillator model. This is followed by a discussion on the relevant ‘weak-coupling’ limit. In the steady state, we analyze the quantum counterpart of energy equipartition theorem which has generated a considerable amount of interest in recent literature. The free energy, entropy, specific heat, and third law of thermodynamics are discussed for one-dimensional quantum Brownian motion in a harmonic well. Following this, we explore some aspects of dissipative diamagnetism in the context of quantum Brownian oscillators, emphasizing upon the role of confining potentials and also upon the environment-induced classical-quantum crossover. We discuss situations where the system-bath coupling is via the momentum variables by focusing on a gauge-invariant model of momentum-momentum coupling in the presence of a vector potential; for this problem, we derive the quantum Langevin equation and discuss quantum thermodynamic functions. Finally, the topic of fluctuation theorems is discussed (albeit, briefly) in the context of classical and quantum cyclotron motion of a particle coupled to a heat bath.
A wide variety of dissipative and fluctuation problems involving a quantum system in a heat bath can be described by the independent-oscillator (IO) model Hamiltonian. Using Heisenberg equations of motion, this leads to a generalized quantum Langevin equation (QLE) for the quantum system involving two quantities which encapsulate the properties of the heat bath. Applications include: atomic energy shifts in a blackbody radiation heat bath; solution of the problem of runaway solutions in QED; electrical circuits (resistively shunted Josephson barrier, microscopic tunnel junction, etc.); conductivity calculations (since the QLE gives a natural separation between dissipative and fluctuation forces); dissipative quantum tunneling; noise effects in gravitational wave detectors; anomalous diffusion; strongly driven quantum systems; decoherence phenomena; analysis of Unruh radiation and entropy for a dissipative system.