Optical Emission from the Interaction of Fast Electrons with Metallic Films Containing a Circular Aperture: A Study of Radiative Decoherence of Fast Electrons
Light emission resulting from the interaction of swift electrons with a distant material is shown to produce an unexpectedly large fraction of decoherence in the moving charges. The decoherence probability diverges for an electron passing through a hole drilled in a perfectly conducting metal film, regardless of the size of the opening. This divergence, which is logarithmic in the ratio of film radius to aperture radius, originates in an infrared catastrophe that differs from other sources of decoherence (e.g., bremsstrahlung radiation). Our results provide new avenues for controlling and assessing the role of coherence during electron acceleration (for example, in transmission electron microscopes) and for exploiting partial quantum interference of fast electrons.
Light emission resulting from the interaction of swift electrons with a distant material is shown to produce an unexpectedly large fraction of decoherence in the moving charges. The decoherence probability diverges for an electron passing through a hole drilled in a perfectly conducting metal film, regardless of the size of the opening. This divergence, which is logarithmic in the ratio of film radius to aperture radius, originates in an infrared catastrophe that differs from other sources of decoherence (e.g., bremsstrahlung radiation). Our results provide new avenues for controlling and assessing the role of coherence during electron acceleration (for example, in transmission electron microscopes) and for exploiting partial quantum interference of fast electrons.
The coherence of free electrons sets fundamental limits on the resolution and contrast of phase-sensitive electron microscopy because coherence is lost whenever the electron leaves a distinguishing excitation in its environment. We develop a quantitative theory of fast-electron decoherence in two canonical geometries: a cylindrical hole drilled through a realistic metal and a circular aperture in a thin perfectly conducting film. By combining an electromagnetic Green-tensor formulation with the fluctuation--dissipation theorem while fully retaining retardation, we obtain the decoherence probability and elastic phase as functions of the electron trajectory, temperature, and material response. For the cylindrical hole, we obtain a closed-form, azimuthally resolved expression that separates the dependences on path position, temperature, and conductivity. In the high-conductivity and high-temperature limits, this result reduces to a universal expression that is linear in temperature and independent of both conductivity and electron velocity. For the circular aperture, which we solve using a cylindrical-wave modal expansion, the energy-loss probability diverges as 1/ω at low frequency, whereas the decoherence probability remains finite and reaches a maximum when the aperture radius is comparable to the relevant electromagnetic wavelength. Because the interaction is spatially localized, aperture-induced decoherence is generally weaker than that produced by a cylindrical hole, except for sufficiently large apertures at high temperature. Finally, we show that, for sufficiently large holes, decoherence can dominate the spatial broadening of a focused electron probe and must therefore be incorporated into the design of coherent electron-beam instruments.
Surface plasmon polaritons are charge density waves of electrons in a metal, which are coupled to an electromagnetic field at a metal-dielectric interface. The electro- magnetic field associated with surface plasmons is confined, resulting in increased field intensities near the interface. Optical emitters placed near a metal film interact strongly with the surface plasmon modes present, not only modifying the radiation rates, but also the radiation profile. These emitters may be used to store and process information, and understanding their behaviour in the presence of a lossy metal film is important in determining the advantages and limitations of using surface plasmons. In this thesis, we wish to understand how we can optically control atoms by exploring two physical phenomena: first, the influence of surface plasmons on collective effects in an ensemble of emitters. Secondly, the single photon excitation of an emitter near a metal film. In the first case, we analyze the collective radiative behaviour of multiple classical emitters near a metal film that radiatively couple to the far-field through surface plasmon modes. We demonstrate that the contributions of dipolar image charges within the metal film significantly affect the cooperative emission of nearby sources, generating sub- and super-radiant emission that can be controlled with a suitably detuned external driving field. In the second case, we determine the excitation probability of an atom near a metal film by a single photon pulse that is time reversed. Using a quantum electro- dynamic description of absorbing dielectrics, we show that non-radiative decay will limit the excitation probability to about half of the maximum that could be achieved in the absence of losses.
Quantum physics rules the dynamics of small objects as they interact over microscopic length scales. Nevertheless, quantum correlations involving macroscopic distances can be observed between entangled photons as well as in atomic gases and matter waves at low temperatures. The long-range nature of the electromagnetic coupling between charged particles and extended objects could also trigger quantum phenomena over large distances. Here, we reveal a manifestation of quantum mechanics that involves macroscopic distances and results in a nearly complete depletion of coherence associated with which-way free-electron interference produced by electron-radiation coupling in the presence of distant extended objects. This is a ubiquitous effect that we illustrate through a rigorous theoretical analysis of a two-path electron beam interacting with a semi-infinite metallic plate and find the inter-path coherence to vanish proportionally to the path separation at zero temperature and exponentially at finite temperature. The investigated regime of large distances originates in the coupling of the electron to radiative modes assisted by diffraction at material structures but without any involvement of material excitations. Besides the fundamental interest of this macroscopic quantum phenomenon, our results suggest an approach to measuring the vacuum temperature and nondestructively sensing the presence of distant objects.
Electron microscopes provide a powerful platform for exploring physical phenomena with nanoscale resolution, based on the interaction of free electrons with the excitations of a sample such as phonons, excitons, bulk plasmons, and surface plasmons. The interaction usually results in the absorption or emission of such excitations, which can be detected directly through cathodoluminescence or indirectly through electron energy loss spectroscopy (EELS). However, as we show here, the underlying interaction of a free electron and an arbitrary optical excitation goes beyond what was predicted or measured so far, due to the interplay of entanglement and decoherence of the electron-excitation system. The entanglement of electrons and optical excitations can provide new analytical tools in electron microscopy. For example, it can enable measurements of optical coherence, plasmonic lifetimes, and electronic length scales in matter (such as the Bohr radius of an exciton). We show how these can be achieved using common configurations in electron diffraction and EELS, revealing significant changes in the electron’s coherence, as well as in other quantum information theoretic measures such as purity. Specifically, we find that the purity after interaction with nanoparticles can only take discrete values, versus a continuum of values for interactions with surface plasmons. We quantify the post-interaction density matrix of the combined electron-excitation system by developing a framework based on macroscopic quantum electrodynamics. The framework enables a quantitative account of decoherence due to excitations in any general polarizable material (optical environment). This framework is thus applicable beyond electron microscopy. Particularly in electron microscopy, our work enriches analytical capabilities and informs the design of quantum information experiments with free electrons, allowing control over their quantum states and their decoherence by the optical environment.
Open system dynamics of an electron is studied in the presence of radiation field, confined between two parallel conducting pates. It has been suggested in previous works that the quantized zero-point modes of this field lead to finite decoherence effects, possibly due to the Casimir force. However, in this work it is shown that the decoherence found in previous works is due to the sudden switching on of the system-environment interaction and due to the acceleration of the electron enforced by the background paths whose superposition was analyzed. The work discusses important theoretical aspects of the setup and shows that, while coherence might be lost due to bremsstrahlung induced by an external or the image potential, it cannot be lost due to the mere presence of the quantum vacuum fluctuations between the plates.
The processes of radiation damping and decoherence in Quantum Electrodynamics are studied from an open system's point of view. Employing functional techniques of field theory, the degrees of freedom of the radiation field are eliminated to obtain the influence phase functional which describes the reduced dynamics of the matter variables. The general theory is applied to the dynamics of a single electron in the radiation field. From a study of the wave packet dynamics a quantitative measure for the degree of decoherence, the decoherence function, is deduced. The latter is shown to describe the emergence of decoherence through the emission of bremsstrahlung caused by the relative motion of interfering wave packets. It is argued that this mechanism is the most fundamental process in Quantum Electrodynamics leading to the destruction of coherence, since it dominates for short times and because it is at work even in the electromagnetic field vacuum at zero temperature. It turns out that decoherence trough bremsstrahlung is very small for single electrons but extremely large for superpositions of many-particle states.