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Applied Optics

Characteristics of ruby passive Q switching with a Dy^2+:CaF_2 solid-state saturable absorber

Yen‐Kuang Kuo, Milton Birnbaum

Published Oct 20, 1995• 10 citations
Publisher

Abstract

Characteristics of ruby passive Q switching with a Dy(2+):CaF(2) solid-state saturable absorber are investigated with output couplers of various reflectivities and saturable absorbers of different thicknesses. Numerical simulation is used to investigate the behavior of ruby passive Q switching with a Dy(2+):CaF(2) saturable absorber and to interpret the experimental results.

DOI
10.1364/ao.34.006829

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Dy^2+:CaF_2 saturable-absorber Q switch for the ruby laser

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Techniques for the measurement of non-radiative decay rates between the optically excited states in solid-state laser materials are described. Two crystals have been investigated, ruby (Cr3+:Al2O3) and Sm2+:CaF2. A review of the spectroscopy of these materials is presented with particular emphasis on aspects relevant to non-radiative decay. An experiment is described using a second harmonic Nd3+ Nd:glass Q-switched laser to pump ruby crystals. Limiting non-radiative relaxation times were derived from the rise of fluorescence. Rubies varying in concentration between 0.05% and 0.4% were studied over a range of temperatures, 77 -> 7000 K. 4T2 -> 2E(E + 2A), 4T2 -> 2T1 (Eb) and 4T2 -> 2T1 (2A + Ea) non-radiative relaxations were all found to be <4ns in good agreement with the experimental results of other workers. Two experiments employing a ruby laser to pump Sm2+ :CaF2 are described. The first used a Q-switched laser and, apart from some improvements was similar to the ruby experiment. An upper limit of 4f5 5d pump -> metastable non-radiative decay of 2ns was found for Sm2+:CaF2, The fluorescence decay constant at 295 K was also measured to be 63ns. The second experiment employed a mode-locked laser and the Sm2+:CaF2 non-radiative decay time was <0.5ns. A new effect - provisionally called 'surface emission' - discovered during the ruby measurements, has been examined in detail and the results of this investigation are presented. A phase-shift technique for the measurement of non-radiative decay times is examined in detail. A pilot experiment using a self-mode-locked He-Ne laser at 633 nm to pump Sm2+:CaF2 is described. The non-radiative relaxation time found by this method was <33ps. Suggestions for improved experiments, both pulsed and phase-shifts, are made and the application of the techniques to other materials is discussed.

•Jan 1, 1971•0 citations
Characteristics of ruby passive Q switching with a Dy(2+):CaF(2) solid-state saturable absorber are investigated with output couplers of various reflectivities and saturable absorbers of different thicknesses. Numerical simulation is used to investigate the behavior of ruby passive Q switching with a Dy(2+):CaF(2) saturable absorber and to interpret the experimental results.
In a laser with a saturable absorber (LSA), two spatially separated cells are placed in the laser cavity as shown in Figure 8.1. The roles of the two cells are quite different: one of them is pumped so that the atoms have a positive population inversion (active or amplifying medium); the other one is left with a negative population inversion (passive or absorbing medium). As these two media are in general different, they saturate at different power levels. The most interesting case corresponds to the situation where the absorber saturates more easily than the active medium, introducing nonlinear losses inside the cavity. This new nonlinearity is responsible for two phenomena. An LSA may exhibit optical bistability, i.e. two distinct stable steady states may coexist for a range of values of a parameter. It may also produce pulsating intensity oscillations which have been called “passive Q-switching” (PQS) in contrast to “active Q-switching” experiments such as the “gain switching” experiments discussed in Section 1.3.2. The interest in LSAs varied very much over time, with peaks in the late 1960s for their large intensity pulses, in the mid 1980s for their chaotic outputs, and in the late 1990s for the design of compact microlasers. Historically, physicists trying to explain the irregular intensity pulses delivered by the ruby laser suspected the possible destabilizing role of a saturable absorber. Shimoda proposed that the nonlinear losses generated by a saturable absorber could explain this phenomenon.
Measurements of the saturated transmission and the undepleted ground-state population density of both Cr(4+):YAG crystals and dye films as saturable absorbers have been experimentally attempted to understand the additional unsaturated losses in a high Q state. The saturated transmission of a saturable absorber is less than its maximum at a high saturation fluence because of the undepleted ground-state population density. Higher saturated transmission and lower undepleted ground-state population density have been observed for Cr(4+):YAG crystals than have been observed for dye films at high optical densities.
Techniques for the measurement of non-radiative decay rates between the optically excited states in solid-state laser materials are described. Two crystals have been investigated, ruby (Cr3+:Al2O3) and Sm2+:CaF2. A review of the spectroscopy of these materials is presented with particular emphasis on aspects relevant to non-radiative decay. An experiment is described using a second harmonic Nd3+ Nd:glass Q-switched laser to pump ruby crystals. Limiting non-radiative relaxation times were derived from the rise of fluorescence. Rubies varying in concentration between 0.05% and 0.4% were studied over a range of temperatures, 77 -> 7000 K. 4T2 -> 2E(E + 2A), 4T2 -> 2T1 (Eb) and 4T2 -> 2T1 (2A + Ea) non-radiative relaxations were all found to be <4ns in good agreement with the experimental results of other workers. Two experiments employing a ruby laser to pump Sm2+ :CaF2 are described. The first used a Q-switched laser and, apart from some improvements was similar to the ruby experiment. An upper limit of 4f5 5d pump -> metastable non-radiative decay of 2ns was found for Sm2+:CaF2, The fluorescence decay constant at 295 K was also measured to be 63ns. The second experiment employed a mode-locked laser and the Sm2+:CaF2 non-radiative decay time was <0.5ns. A new effect - provisionally called 'surface emission' - discovered during the ruby measurements, has been examined in detail and the results of this investigation are presented. A phase-shift technique for the measurement of non-radiative decay times is examined in detail. A pilot experiment using a self-mode-locked He-Ne laser at 633 nm to pump Sm2+:CaF2 is described. The non-radiative relaxation time found by this method was <33ps. Suggestions for improved experiments, both pulsed and phase-shifts, are made and the application of the techniques to other materials is discussed.