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Mathematical Proceedings of the Cambridge Philosophical Society

A Note on the Equations of Motion in Non-Relativistic Quantum Mechanics

F. C. Powell

Published Apr 1, 1935• 0 citations
Publisher

Abstract

It is well known that the motion of a dynamical system can be pictured in two distinct ways, which Dirac names the Heisenberg picture and the Schrödinger picture. The equations of motion take different forms in the two pictures, but of course have identical physical consequences, since the motion of the system does not depend in any way on which picture we choose. It should therefore be possible to express the equations in an invariant form (independent, that is, of the picture used). It will be shown in this note that not only can this be done (equation (3)), but it can be done in such a way that it is not even necessary to introduce a picture at all (equation (3′)).

DOI
10.1017/s0305004100013414

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It is well known that the motion of a dynamical system can be pictured in two distinct ways, which Dirac names the Heisenberg picture and the Schrödinger picture. The equations of motion take different forms in the two pictures, but of course have identical physical consequences, since the motion of the system does not depend in any way on which picture we choose. It should therefore be possible to express the equations in an invariant form (independent, that is, of the picture used). It will be shown in this note that not only can this be done (equation (3)), but it can be done in such a way that it is not even necessary to introduce a picture at all (equation (3′)).
In non-relativistic quantum mechanics, there exist several different ways of describing the time dependence of dynamics of physical systems. Of particular importance for quantum scattering theory are the Schrodinger, Heisenberg and Dirac pictures. For establishing a connection between quantum mechanical formalisms and classical mechanics, as well as for investigating relativistic solutions, the Heisenberg picture appears to be the most convenient. This picture of quantum mechanics is particularly adapted for the examination of free fields. The customary wave-mechanical version of quantum theory is obtained if we choose, e.g., in the framework of the Schrodinger picture to work with the coordinate representation. Possible results of measurements on a quantum system are called eigenvalues. To each of the latter values corresponds one or more eigenstates. An eigenstate is degenerate when more than one eigenstate correspond to a single eigenvalue.
Some years have passed since the appearance of Dirac's striking interpretation of the Heisenberg-Schroedinger parallelism in the equations of motion, and yet it appears that there still remain obscure points which have led to misunderstanding. Although the Schroedinger method suffices to deal with many practical problems, the flexibility of the Dirac-Jordan representation theory, aside from its intrinsic unity and beauty, recommends it to general theoretical investigation. The present paper considers the invariant form of the equations of motion in relation to the Schroedinger-Heisenberg pictures of quantum mechanics insofar as the latter refer to the "pictured" intrinsic motion of states (vectors) and observables (Hermitian operators). The discussion is divided roughly into 5-sections: Operator and Vector Transforms, Contact Transformations, Heisenberg-Schroedinger Operators, Equations of Motion and Invariant Properties, and the Density Operator and Operator Spur. Where possible, quasi-geometrical diagrams are given to illustrate the relation and transition between the several "pictures of the motion."
This chapter outlines the governing equations in non-relativistic quantum physics. The Schrödinger equation (the Schrödinger picture) looms large. Its intuitive simplicity and elegance render it particularly appealing to aspiring engineers and materials scientists. The other two equivalent pictures presented are the Heisenberg picture and the interaction picture. The Heisenberg picture emphasizes time-dependent operators, and the interaction picture splits the so-called interaction Hamiltonian from the total Hamiltonian of the system considered. Much attention has been paid in this chapter to establish relationships between the pictures, as meaningful as possible at this level of treatment.
It is not possible to use the Schrödinger equation to describe the motion of a particle with relativistic effects since it is not invariant relative to the Lorentz transformation. However, the attempt to generalize quantum mechanics in the relativistic domain on the basis of the one particle theory is somehow difficult. So we find the appropriate equations on the basis of the relativistic invariance. To obtain the non-relativistic equations, we take the limit as the speed of light tends to infinity. This obviously recovers the Schrödinger equation. Under this heading, we extend the non-relativistic Schrödinger equation in the description of particles with speeds comparable with that of light. This extension should be consistent with the Lorentz transformation [ 12 ]. The characteristic feature of the relativistic wave equations is the spin which provides a useful gauge in the applicability of particular equations that describe particular kinds of particles. We have two types of relativistic equations, i.e., the equation with spin-zero due to Schrödinger and spin-half due to Dirac that describes the electron.
The description of the time evolution of systems is technically known as the "Schrodinger picture." An important alternative description is the "Heisenberg picture," which indeed was the one Heisenberg used when he first formulated quantum mechanics. The Schrodinger and Heisenberg pictures represent two different but equivalent sets of rules. In other words, when applied to a given physical situation they lead to the same observable predictions. In some respects, the Heisenberg picture presents definite technical advantages. It is particularly convenient, for instance, in quantum field theory. The chapter discusses work consistently with the equivalent Schrodinger set of rules. For this reason, it describes briefly the Heisenberg formulation. The chapter shows that the expressions used in the Schrodinger picture can be carried over to the Heisenberg picture. It implies, however, that the kets associated with the possible values that can be found upon measurement of an observable are themselves time-dependent kets.
The main aim of this note is to show that the formalism of multi-time equations in quantum mechanics meant to represent a manifestly Lorentz-invariant theory suffers from at least three imperfections: (1) It does not cover those physical systems for which the Schrödinger picture of quantum mechanics does not exist. (2) The integrabiliy condition which has been proposed in the formalism does not imply as necessary that for every partial Hamiltonian there exists a Schrödinger equation. (3) The formalism does not generally allow for interactions even in a non-relativistic multi-particle quantum system.