This is the first of a series of papers which describe the functional-integral approach to the study of the statistical and kinetic properties of nonequilibrium quantum fields in flat and curved spacetimes. In this paper we treat a system of self-interacting bosons described by \ensuremath{\lambda}${\ensuremath{\varphi}}^{4}$ scalar fields in flat space. We adopt the closed-time-path (CTP or ``in-in'') functional formalism and use a two-particle irreducible (2PI) representation for the effective action. These formalisms allow for a full account of the dynamics of quantum fields, and put the correlation functions on an equal footing with the mean fields. By assuming a thermal distribution we recover the real-time finite-temperature theory as a special case. By requiring the CTP effective action to be stationary with respect to variations of the correlation functions we obtain an infinite set of coupled equations which is the quantum-field-theoretical generalization of the Bogoliubov-Born-Green-Kirkwood-Yvon (BBGKY) hierarchy. Truncation of this series leads to dissipative characteristics in the subsystem. In this context we discuss the nature of dissipation in interacting quantum fields.To one-loop order in a perturbative expansion of the CTP effective action, the 2PI formalism yields results equivalent to the leading 1/N expansion for an O(N)-symmetric scalar field. To higher-loop order we introduce a two-time approximation to separate the quantum-field effects of radiative correction and renormalization from the statistical-kinetic effects of collisions and relaxation. In the weak-coupling quasiuniform limit, the system of nonequilibrium quantum fields can subscribe to a kinetic theory description wherein the propagators are represented in terms of relativistic Wigner distribution functions. From a two-loop calculation we derive the Boltzmann equation for the distribution function and the gap equation for the effective mass of the quasiparticles. One can define an entropy function for the quantum gas of quasiparticles which satisfies the H theorem. We also calculate the limits to the validity of the binary collision approximation from a three-loop analysis. The theoretical framework established here can be generalized to nonconstant background fields and for curved spacetimes.
This is the first of a series of papers which describe the functional-integral approach to the study of the statistical and kinetic properties of nonequilibrium quantum fields in flat and curved spacetimes. In this paper we treat a system of self-interacting bosons described by \ensuremath{\lambda}\ensuremathφ4 scalar fields in flat space. We adopt the closed-time-path (CTP or ``in-in'') functional formalism and use a two-particle irreducible (2PI) representation for the effective action. These formalisms allow for a full account of the dynamics of quantum fields, and put the correlation functions on an equal footing with the mean fields. By assuming a thermal distribution we recover the real-time finite-temperature theory as a special case. By requiring the CTP effective action to be stationary with respect to variations of the correlation functions we obtain an infinite set of coupled equations which is the quantum-field-theoretical generalization of the Bogoliubov-Born-Green-Kirkwood-Yvon (BBGKY) hierarchy. Truncation of this series leads to dissipative characteristics in the subsystem. In this context we discuss the nature of dissipation in interacting quantum fields.To one-loop order in a perturbative expansion of the CTP effective action, the 2PI formalism yields results equivalent to the leading 1/N expansion for an O(N)-symmetric scalar field. To higher-loop order we introduce a two-time approximation to separate the quantum-field effects of radiative correction and renormalization from the statistical-kinetic effects of collisions and relaxation. In the weak-coupling quasiuniform limit, the system of nonequilibrium quantum fields can subscribe to a kinetic theory description wherein the propagators are represented in terms of relativistic Wigner distribution functions. From a two-loop calculation we derive the Boltzmann equation for the distribution function and the gap equation for the effective mass of the quasiparticles. One can define an entropy function for the quantum gas of quasiparticles which satisfies the H theorem. We also calculate the limits to the validity of the binary collision approximation from a three-loop analysis. The theoretical framework established here can be generalized to nonconstant background fields and for curved spacetimes.
We extend our earlier work on the nonequilibrium dynamics of a Bose-Einstein condensate initially loaded into a one-dimensional optical lattice. From the two-particle-irreducible (2PI) closed-time-path (CTP) effective action for the Bose-Hubbard Hamiltonian we derive causal equations of motion that treat mean-field effects and quantum fluctuations on an equal footing. We demonstrate that these equations reproduce well-known limits when simplifying approximations are introduced. For example, when the system dynamics admits two-time separation, we obtain the Kadanoff-Baym equations of quantum kinetic theory, and in the weakly interacting limit, we show that the local equilibrium solutions of our equations reproduce the second-order corrections to the self-energy of the type originally derived by Beliaev. The derivation of quantum kinetic equations from the 2PI-CTP effective action not only checks the viability of the formalism but also shows it to be a tractable framework for going beyond standard Boltzmann equations of motion.
We present kinetic equations that describe the evolution of O(N)-symmetric real scalar quantum fields out of thermal equilibrium in a systematic nonperturbative approximation scheme. This description starts from the 1/N-expansion of the 2PI effective action to next-to-leading order, which includes scattering and memory effects. From this starting point one is lead to evolution equations for the propagator, which are nonlocal in time. Numerical solutions showed that the propagator depends only very slightly on the center coordinates already after moderate times, and that correlations between earlier and later times are suppressed exponentially, which causes an effective memory loss. Exploiting these two observations, we combine a first order gradient expansion with a Wigner transformation to derive our kinetic equations, which are local in time, from the nonlocal evolution equations. In contrast to standard descriptions based on loop expansions, our kinetic equations remain valid even for nonperturbatively large fluctuations. Additionally, employing a quasi-particle approximation, we eventually arrive at a generalized Boltzmann equation.
We present a theoretical study of thermalization of quantum fields with Kadanoff-Baym (KB) equation. First we introduce a field theoretical technique known as 2 Particle Irreducible (2PI) effective action and review derivation of equation of motion for mean fields and fluctuations, then derive Kadanoff-Baym equation in scalar and gauge theories. In order to analyze thermalization processes we introduce relativistic entropy current based on the first order gradient expansion of Kadanoff-Baym equation. Then we show that in taking into account next-to-leading order (NLO) self-energy of the coupling expansion in φ4 theory (in symmetric phase <φ^> = 0), it is possible to prove the H-theorem within the 1st order gradient expansion. We also show that it is possible to prove the H-theorem for KB equation with NLO self-energy of 1/N expansion in O(N) theory (in symmetric phase). Furthermore we suggest a possibility for H-theorem to be satisfied in KB equation with leading-order (LO) self-energy of the coupling expansion in non-Abelian gauge theory. In d+1 dimensions (d＞2) LO particle number changing processes, such as 0-to-3, 1-to-2 and 2-to-1, which are prohibited in the normal Boltzmann approach with on-shell particles, may contribute to entropy production in KB approach although we must deal with gauge dependence and infrared divergence to complete the proof. Next we perform numerical simulations in spatially homogeneous configurations to investigate thermalization properties of the system in 1+1 and 2+1 dimensions for φ4 theory with NLO self-energy of the coupling expansion and 1+1 dimensions for O(N) theory with NLO self-energy of 1/N expansion. We also estimate the time evolution of the kinetic entropy in the case of scalar φ4 and O(N) theory. Then we find that at later times X0≫1/m, where m represents mass of particles, the kinetic entropy increases monotonically and approaches the equilibrium value, although the limited time interval at the earlier times X0～1/m invalidates the use of it. No thermalization occurs in the simulations with the normal Boltzmann equation with 2-to-2 collision term in 1+1 dimensions, while it occurs in the simulations with KB equation in 1+1 dimensions. It is due to two types of offshell effects: memory effects and spectral functions with the decay width.
In this article, we present a concise and self-contained introduction to nonequilibrium statistical mechanics with quantum field theory by considering an ensemble of interacting identical bosons or fermions as an example. Readers are assumed to be familiar with the Matsubara formalism of equilibrium statistical mechanics such as Feynman diagrams, the proper self-energy, and Dyson's equation. The aims are threefold: (i) to explain the fundamentals of nonequilibrium quantum field theory as simple as possible on the basis of the knowledge of the equilibrium counterpart; (ii) to elucidate the hierarchy in describing nonequilibrium systems from Dyson's equation on the Keldysh contour to the Navier-Stokes equation in fluid mechanics via quantum transport equations and the Boltzmann equation; (iii) to derive an expression of nonequilibrium entropy that evolves with time. In stage (i), we introduce nonequilibrium Green's function and the self-energy uniquely on the round-trip Keldysh contour, thereby avoiding possible confusions that may arise from defining multiple Green's functions at the very beginning. We try to present the Feynman rules for the perturbation expansion as simple as possible. In particular, we focus on the self-consistent perturbation expansion with the Luttinger-Ward thermodynamic functional, i.e., Baym's Phi-derivable approximation, which has a crucial property for nonequilibrium systems of obeying various conservation laws automatically. We also show how the two-particle correlations can be calculated within the Phi-derivable approximation, i.e., an issue of how to handle the "Bogoliubov-Born-Green-Kirkwood-Yvons (BBGKY) hierarchy".
In the framework of real-time Green's functions, the general kinetic equations are investigated in a first-order gradient expansion. Within this approximation, the problem of the reconstruction of the two-time correlation functions from the one-time Wigner function was solved. For the Wigner function, a cluster expansion is found in terms of a quasiparticle distribution function. In equilibrium, this expansion leads to the well-known generalized Beth-Uhlenbeck expression of the second virial coefficient. As a special case, the T-matrix approximation for the self-energy is investigated. The quantum kinetic equation derived thus has, besides the (Markovian) Boltzmann collision integral, additional terms due to the retardation expansion which reflect memory effects. Special interest is paid to the case that bound states exist in the system. It is shown that the bound state contribution, which can be introduced via a bilinear expansion of the two-particle T matrix, follows from the first-order retardation term in the general kinetic equation. The full Wigner function is now a sum of one function describing the unbound particles and another one for the bound state contribution. The latter two functions have to be determined from a coupled set of kinetic equations. In contrast to the quantum Boltzmann equation, energy and density of a nonideal system are conserved. \textcopyright{} 1996 The American Physical Society.
The quantum Boltzmann equation (QBE), originally formulated as the quantum extension of Boltzmann’s classical transport theory by Uehling and Uhlenbeck and subsequently developed within the nonequilibrium Green-function formalisms of Kadanoff–Baym and Keldysh, provides the central kinetic framework for describing relaxation and transport in weakly interacting quantum many-body systems. Although its formal structure is well established, conventional derivations often obscure the microscopic equivalence between operator and nonequilibrium Green-function approaches. Wick factorization is typically applied without explicitly enumerating real-time contractions, while Green-function treatments encode the same physics in Born-level self-energies that conceal their operator origin. In this paper, we present a pedagogical microscopic derivation of the quantum Boltzmann equation that makes this equivalence fully explicit. Starting from the ladder-operator formulation, we enumerate all fifteen Wick pairings of the second-order six-field correlator, identifying three Hartree–Fock contributions and twelve real-time Born scattering channels generated by a quartic, number-conserving interaction Hamiltonian. We then establish a one-to-one correspondence between these twelve operator contractions and the Keldysh components of the second-order Born self-energy, demonstrating explicitly how the Uehling–Uhlenbeck collision integral emerges after Wigner transformation and quasiparticle projection. Under controlled Born–Markov and quasiparticle approximations, this work offers a transparent synthesis of operator and Green-function formulations, and clarifies how kinetic fluctuations can be understood as emergent under coarse-graining.