The feature of quantum entanglement in doublet and multiplet systems is briefly described and used to create a new model for the superconducting phase.
The detailed consideration of the relativistic canonical quantum-mechanical model of an arbitrary spin-multiplet is given. The group-theoretical analysis of the algebra of experimentally observables physical quantities for the spin 1/2 doublet is presented. It is shown that both the Foldy-Wouthuysen equation for the fermionic spin 1/2 doublet and the Dirac equation in its local representation are the consequences of the relativistic canonical quantum mechanics of the corresponding doublet. The mathematically well-defined consideration on the level of modern axiomatic approaches to the field theory is provided. The hypothesis of the antiparticle negative mass is discussed briefly in the section conclusions.
Abstract In this study, we investigate the quantum phase transition in a Josephson junction consisting of parallel-connected quantum dots (QDs) with a magnetic flux φ B threading the central region. Employing the surrogate model approach, we discretize the superconducting (SC) electrode into three discrete energy levels, which enables direct diagonalization of the Hamiltonian to determine the system’s ground state. Our calculations demonstrate that when Coulomb interaction is present in only one QD, the system exhibits a phase transition between singlet and doublet states. The magnetic flux exerts a minor influence on the singlet state while substantially affecting the doublet state. When both QDs possess Coulomb interactions, the system undergoes two successive phase transitions as the SC phase difference increases: the ground state evolves from a doublet to a singlet and subsequently to a triplet state at ϕ = π . Enhancement of the magnetic flux suppresses the doublet and triplet phases, ultimately stabilizing the singlet state. Within this regime, increasing the Coulomb interaction strength U does not trigger a singlet-triplet transition; rather, it induces a transition between upper and lower singlet states, resulting in a pronounced peak in the critical current as U increases. Finally, we explore the scenario where the tunneling self-energy Γ between the QDs and SCs exceeds the SC pairing potential Δ. In this case, doublet states prevail, and the system manifests a phase transition exclusively between doublet and triplet states when ϕ B = 0 . Upon application of a magnetic flux, all three states converge, giving rise to a triple point in the ( φ , φ B ) parameter space.
We present a spin-adapted coupled cluster singles and doubles model for the excitation energies of molecular doublets. The entanglement coupled cluster approach represents an unconventional take on the notorious problem of spin adaptation for open-shell species. In this approach, the high-spin open-shell molecular system is coupled to non-interacting bath orbitals to form a total closed-shell system. In entanglement coupled cluster theory, many of the attractive features of the spin-adapted closed-shell coupled cluster are retained: an unambiguous definition of the cluster operator and a terminating Baker-Campbell-Hausdorff expansion. The model produces excitation energies of a quality comparable to that of the closed-shell counterpart. Additionally, some ionized states that cannot be modeled accurately with the alternative equation-of-motion approach for ionized states can be described with the entanglement coupled cluster singles and doubles model.