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Mathematical Proceedings of the Cambridge Philosophical Society

Note on the Doppler principle and Bohr's frequency condition

P. A. M. Dirac

Published Sep 20, 1924• 8 citations
Publisher

Abstract

When an atomic system emits or absorbs radiation, the frequency of the radiation is connected with the change of energy of the system by Bohr's frequency condition δE = hv. This equation is usually applied to the transition of an atom from one stationary state to another, the frequency of the radiation being measured in a frame of reference in which the atom as a whole is at rest, both before and after the transition. It has been pointed out by Bohr that difficulties arise when no natural frame of reference presents itself in which to measure the frequency, which is the case for non-isolated systems, or even for isolated systems when the process of radiation is connected with a change of momentum.

DOI
10.1017/s0305004100014341

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When an atomic system emits or absorbs radiation, the frequency of the radiation is connected with the change of energy of the system by Bohr's frequency condition δE = hv. This equation is usually applied to the transition of an atom from one stationary state to another, the frequency of the radiation being measured in a frame of reference in which the atom as a whole is at rest, both before and after the transition. It has been pointed out by Bohr that difficulties arise when no natural frame of reference presents itself in which to measure the frequency, which is the case for non-isolated systems, or even for isolated systems when the process of radiation is connected with a change of momentum.
Abstract It is well known that the experimental facts of atomic physics necessitate a departure from the classical theory of electrodynamics in the description of atomic phenomena. This departure takes the form, in Bohr’s theory, of the special assumptions of the existence of stationary states of an atom, in which it does not radiate, and of certain rules, called quantum conditions, which fix the stationary states and the frequencies of the radiation emitted during transitions between them. These assumptions are quite foreign to the classical theory, but have been very successful in the interpretation of a restricted region of atomic phenomena. The only way in which the classical theory is used is through the assumption that the classical laws hold for the description of the motion in the stationary states, although they fail completely during transitions, and the assumption, called the Correspondence Principle, that the classical theory gives the right results in the limiting case when the action per cycle of the system is large compared to Planck’s constant h, and in certain other special cases. In a recent paper Heisenberg puts forward a new theory, which suggests that it is not the equations of classical mechanics that are in any way at fault, but that the mathematical operations by which physical results are deduced from them require modification. All the information supplied by the classical theory can thus be made use of in the new theory.
Bohr's 1913 trilogy marks a turning point in the history of quantum physics for its introduction of the planetary model of the atom and its derivation of the Balmer formula for the hydrogen spectrum. It has been studied in the seminal study 1 and is discussed more recently by 2-4. Famously, Bohr's classical paper made two utterly non-classical assumptions, according to which electrons orbited the nucleus in stationary states without losing energy while they emitted radiation only in transitions between these states. As I will argue in this paper, Bohr's 1913 trilogy made a third crucial major assumption, which entailed key elements of the correspondence principle formulated five years later. This third assumption postulated a relation between the mechanical frequency of a stationary state and the radiation frequency in analogy with classical radiation theory. Though this relation was in direct conflict with the key assumptions of stationary states and transitions, Bohr's reasoning—as I want to show—relied heavily on it, and a major part of his initial work was devoted to clarifying how the connection of radiation and motion, the stationary states and the transitions were interrelated. The main aim of Bohr's 1913 trilogy was to derive the Balmer formula from the newly-proposed atomic model. After the introduction of the stationary states and the frequency condition, the derivation follows a three-step recipe consisting of the calculation of the energy from classical mechanics, the quantization of the energy and finally the calculation of the spectral frequencies via the Planck Relation . Given the simplicity of the system considered and the assumption of the stationary states and the frequency condition, the first and last step did not call for an extended argument and Bohr simply gave the relevant equations. As Bohr explicitly acknowledged, the classical radiation mechanism was replaced entirely by the fundamental assumptions of his model: radiation is produced through a transition between stationary states. Though 1 was in direct conflict with the physical assumptions of his model, Bohr's thinking nonetheless depended crucially on it. This is emphasized by the fact that Bohr knew that he could quantize the orbits on the assumption that the angular momentum of the atom is equal to .1 While 1 could not be interpreted as a description of a physical process in a classical sense, Bohr kept the equation and explored its conceptual significance within his new quantum theory of the atom. This was a vital concern for Bohr, first, because he needed a justification; second, because he hoped for insights on how to develop the theory by investigating which parts of classical radiation theory could still be used within the new model. The investigation of this question loomed large in Bohr's 1913 paper and continued to play an important role in his early work on the quantum theory of the atom. For the preceding argument Bohr justified the radiation-motion relation by means of a comparison between the radiation process and the motion of the electron before and after the radiation process. This justification itself was not very convincing: it rested solely on its empirical success and the questionable mean-value argument, and Bohr decided to give a second derivation of the Balmer formula to add further plausibility to 1. Already his first hand waving argument, however, points to some of the central aspects of his attempt to connect radiation and electronic motion: In light of the missing radiation mechanism in quantum theory, Bohr tried to recover a relation between radiation and electronic motion within quantum theory analogous to the one in classical radiation theory. He refrained from proposing a new hypothetical radiation mechanism and shied away from such assumptions until 1924. Instead he resorted to experimental, mathematical and intertheoretical arguments to construct a formal relation between radiation and matter and aimed to get insights into the properties of a radiation mechanism yet to be found. In order to be equivalent to the empirical Balmer formula this function has to be , as Bohr showed by comparing the frequency of a quantum transition and the orbiting frequencies of the stationary states in the case of high quantum numbers, in which classical electrodynamics and quantum theory predict the same numerical value for the radiation frequency. This result implied the consistency of his major assumptions, the radiation-motion connection and the Balmer formula, which entered as an empirical constraint. For the argument the high quantum number limit plays an important role as it renders the condition for the consistency precisely and shows that the assumption of a relation between radiation and motion within quantum theory leads to the agreement of quantum theory and classical theory in this limit. The possibility of an emission of a radiation of such a frequency may also be interpreted from analogy with ordinary electrodynamics, as an electron rotating round a nucleus in an elliptical orbit will emit a radiation which according to Fourier's theorem can be resolved into homogeneous components, the frequencies of which are [5, 14]. This recapturing of the relation between orbital frequency and the radiation frequency is part of Bohr's conclusion: While classical electrodynamics in general is in contradiction with the basic assumptions of the Bohr model, the classical relation between the frequency of radiation and the mechanical frequency can be established at least in the classical limit as a formal relation. To show this is as important to Bohr as to show that his new model predicts the correct Balmer formula. As such the classical relation between motion and radiation is indispensable for Bohr's early work as a touchstone for his two derivations and it is of vital concern in the attempt to explore the break and the continuity with classical radiation theory. The radiation-motion relation continued to play an important role in Bohr's works following the 1913 trilogy; after he had finished his initial papers Bohr adapted his model to account for the Stark and Zeeman effects. The relation between radiation and motion played a major role in the initial work establishing the Bohr model and its extension to the Stark and Zeeman effect. Stemming from classical radiation theory this relation was in contradiction with the major assumptions of the new model of the atom; nonetheless, Bohr's thinking relied heavily on the radiation-motion connection both in establishing his results and in clarifying the foundations of the new model. Compared with his later statements on the correspondence principle there is a remarkable resemblance between the statements in 1913/1914 and the correspondence idea between 1918 and 1923: In both cases the relation between the orbiting frequency and the frequency of radiation and the asymptotic limit between quantum theory and classical electrodynamics were at the core of Bohr's reasoning. 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The fruitfulness of this new quantization condition led physicists including Bohr to abandon the early quantization procedure. Through this abandonment, the frequency condition became the sole relation of radiation theory, which was needed to determine the series formulae describing atomic spectra. Whereas the loss of the classical radiation mechanism had been a vital concern for Bohr in his early works, this was no longer the case in the development of the quantum theory of the atom. The relation should, however, resurface in Bohr's thinking about the transitions in quantum theory and in this form led to the formulation of the correspondence principle.
An analysis of applying the property of speed instantaneity to electronic transitions (i.e., transitions of the atomic electron that are not instantaneous), instead of quantum jumps (i.e., instantaneous transitions), during a complete oscillation for the process of Bohr’s model of the atom absorbing and emitting electromagnetic radiation (i.e., photon) reveals a discontinuity that is conserved as an emitted electromagnetic radiation (i.e., photon) discontinuity. The frequency of the oscillations of the atomic electron (i.e., electric charge) and induced magnetic field for the transitions of the atomic electron (i.e., electric charge) during the complete oscillation for the absorption and emission process (of Bohr’s atomic model) is conserved as the frequency of the oscillating electric and magnetic fields of the emitted electromagnetic radiation (i.e., photon). The conserved frequency and discontinuity (based on speed instantaneity and electronic transitions that are not instantaneous) of the atomic absorption and emission process (of Bohr’s atomic model) lead to predicting the need for Planck’s constant (i.e., quantum of action) without the use of probability. Planck claimed the interpretation of reality must change if his method of deriving the radiation law stood on a physical concept. Einstein, whom Planck credited as the first to make an advancement in the quantum field, unknowingly introduced a quantized two-dimensional discontinuum geometry that is one of the foundations on which a table of five realities used in physics was developed for making predictions. Using the table of realities, locality is redefined, and entanglement is demystified.
‘At the present state of science it does not seem possible to avoid the formal character of the quantum theory which is shown by the fact that the interpretation of atomic phenomena does not involve a description of the mechanism of the discontinuous processes […]. On the correspondence principle it seems nevertheless possible to […] arrive at a consistent description of optical phenomena by connecting the discontinuous effects occurring in atoms with the continuous radiation field […]’. This announced a turning point in atomic physics research; for the first time there were reasons to assert that discontinuity was not in itself incompatible with the theory's descriptive content, and rational solutions were provided that related a whole set of phenomena dependent on the radiation properties of matter to the continuous picture of the radiation field. This was the conclusion arrived at in a new paper by Bohr which took up and developed the hypothesis put forward by the American physicist John Slater that ‘the atom, even before a process of transition between two stationary states takes place, is capable of communication with distant atoms through a virtual radiation field’ was taken up and developed. The article, ‘The Quantum Theory of Radiation’, signed by Bohr, Kramers and Slater, was published in the Philosophical Magazine in January 1924. Slater had arrived in Copenhagen at the end of the preceding year with the idea that his hypothesis might lead to very different theoretical results.