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Chemical Physics Letters

Effects of dampings and dephasings in resonance raman spectroscopy

Pier Francesco Fracassi, Leonardo Angeloni, Raffaele Guido Della Valle

Published Apr 1, 1985• 5 citations
Publisher
DOI
10.1016/0009-2614(85)85163-0

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Collision enhanced resonances represent an interesting class of nonlinear-optical processes. They occur because collisional dephasing can rephase quantum mechanical amplitudes that ordinarily cancel out exactly, thereby allowing otherwise unobservable wave-mixing resonances to be seen. This is an especially interesting phenomenon because these resonances are coherent effects that are induced by an incoherent process (collisional dephasing). First predicted1 in the late 1970s and eventually observed2 in 1981, these novel effects have now been seen in a wide variety of four-wave-mixing experiments, ranging from self-focusing to coherent anti-Stokes Raman spectroscopy.