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Nature Physics

From atoms to molecules

Andreas H. Trabesinger

Published Oct 1, 2010• 1 citation
Publisher
DOI
10.1038/nphys1815

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We report on the preparation of a quantum degenerate mixture of 23Na40K^{23}\mathrm{Na}\phantom{\rule{0.16em}{0ex}}^{40}\mathrm{K}23Na40K molecules and 40K^{40}\mathrm{K}40K atoms. A deeply degenerate atomic mixture of 23Na^{23}\mathrm{Na}23Na and 40K^{40}\mathrm{K}40K atoms with a large number ratio (${N}_{F}/{N}_{B}\ensuremath{\approx}6$) is prepared in a large-volume optical dipole trap. About $3.0\ifmmode\times\else\texttimes\fi{}{10}^{4}\phantom{\rule{0.16em}{0ex}}^{23}\mathrm{Na}\phantom{\rule{0.16em}{0ex}}^{40}\mathrm{K}$ ground-state molecules are created through magnetoassociation followed by stimulated Raman adiabatic passage. The pure molecular gas is in the moderately degenerate regime. In the atom-molecule mixture, the elastic collisions provide a thermalization mechanism for the molecules. The calculated thermalization time constant is smaller than the lifetime of the molecules in the atom-molecule mixture. This indicates that the molecules may reach thermal equilibrium due to elastic atom-molecule collisions before notable losses take place. In a few tens of milliseconds, the degeneracy of the molecules is maintained. This time interval is long enough for the study of strongly interacting atom-molecule mixtures and the production of ultracold triatomic molecular gases.
We present measurements of the loss-rate coefficients Kam{K}_{\mathit{am}}Kam​ and Kmm{K}_{\mathit{mm}}Kmm​ caused by inelastic atom-molecule and molecule-molecule collisions. A thermal cloud of atomic 87Rb^{87}\mathrm{Rb}87Rb is prepared in an optical dipole trap. A magnetic field is ramped across the Feshbach resonance at 1007.4G1007.4\phantom{\rule{0.3em}{0ex}}\mathrm{G}1007.4G. This associates atom pairs to molecules. A measurement of the molecule loss at 1005.8G1005.8\phantom{\rule{0.3em}{0ex}}\mathrm{G}1005.8G yields ${K}_{\mathit{am}}=2\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}10}\phantom{\rule{0.3em}{0ex}}{\mathrm{cm}}^{3}∕\mathrm{s}$. Additionally, the atoms can be removed with blast light. In this case, the measured molecule loss yields ${K}_{\mathit{mm}}=3\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}10}\phantom{\rule{0.3em}{0ex}}{\mathrm{cm}}^{3}∕\mathrm{s}$.
As an introduction, the states of atoms and molecules are introduced. At room temperature, gaseous atoms and molecules move very fast. We imagine that the gaseous phase is transformed to liquid or solid phase by cooling, but it is possible only with high density of atoms and molecules. With low densities, atoms and molecules also stay in the gaseous state at low temperature. Research using cold atoms and molecules, trapped by electric or magnetic field, give important information to develop new physics.