As an introduction, the states of atoms and molecules are introduced. At room temperature, gaseous atoms and molecules move very fast. We imagine that the gaseous phase is transformed to liquid or solid phase by cooling, but it is possible only with high density of atoms and molecules. With low densities, atoms and molecules also stay in the gaseous state at low temperature. Research using cold atoms and molecules, trapped by electric or magnetic field, give important information to develop new physics.
As an introduction, the states of atoms and molecules are introduced. At room temperature, gaseous atoms and molecules move very fast. We imagine that the gaseous phase is transformed to liquid or solid phase by cooling, but it is possible only with high density of atoms and molecules. With low densities, atoms and molecules also stay in the gaseous state at low temperature. Research using cold atoms and molecules, trapped by electric or magnetic field, give important information to develop new physics.
Introduction This chapter describes remarkable new experiments that have been made possible through recent advances in laser cooling of atoms. Cooling of atoms in a gas by laser light is in itself surprising and this technique is important in a range of applications. In particular the experiments described here take atoms that have been laser cooled and then use other methods to reach even lower temperatures, at which wonderful and fascinating quantum effects occur. As well as revealing new phenomena, these experiments explore the deep analogies between the roles played by light waves in lasers and matter waves. These techniques are widely accessible and enable skilled researchers in laboratories all over the world to explore exciting new physics. The key physics and techniques of laser cooling are described in depth in Chapter 6. What is “temperature”? We use the words “cold” and “hot” every day; for example to refer to the temperature of the air outside. But what do “cold” and “hot” mean for the air’s molecules? Broadly speaking, we can say that atoms in a hot gas move faster than those in a cold gas and that cooling, by taking energy out of the gas, slows the atoms down. In this description of the gas as a collection of atoms behaving like billiard balls, or little hard spheres, the lowest possible temperature occurs when the atoms stop moving but, as we shall see, this picture does not give an accurate description at very low energies, for which quantum effects become important. In this chapter we will look at the fascinating properties of atomic gases cooled to temperatures within one millionth of a degree Kelvin from absolute zero. We shall use the term “ultra-cold” to refer to such extremely low temperatures that have only recently been achieved in experiments on atomic gases. The techniques used to cool liquids and solids have a longer history and have made available a different set of possibilities (see Chapter 8). Note that most of this chapter refers to gases in which the individual particles are atoms, but the general statements about temperature scales apply equally well to gases of molecules, e.g. air, whose major constituents, oxygen and nitrogen, exist as diatomic molecules.
Slowing, cooling, and trapping molecules One of the major achievements in physics during the last two decades of the twentieth century was the ability to cool and trap atoms [1]. Laser cooling can produce previously inconceivable atomic temperatures of less than 1 μK. Atoms with sufficiently low kinetic energy can be trapped in magnetic and optical traps and thus studied for a prolonged time, thereby improving the resolution of spectroscopy by many orders of magnitude as well as reducing Doppler broadening. Furthermore, besides the external degrees of freedom, the internal degrees of freedom of the atoms can also be manipulated, leading to full control of the atoms. One of the holy grails of physics, the achievement of Bose–Einstein condensation in a dilute gas, was achieved mainly because of laser cooling and trapping of atoms. One of the natural extensions of laser cooling and trapping of atoms is the application of the techniques to molecules. Molecules offer a much richer internal structure than atoms, and thus provide extended possibilities to experimentalists. However, atomic laser cooling is based on the repetitive scattering of light and requires a closed, or at least nearly closed, two-level system. Because of the complicated internal structure of molecules, a closed two-level system cannot usually be found because they have many different electronic, vibrational, and rotational states and in general can decay to many different states after absorption of light (see Chap. 16). This requires a complete rethinking of the schemes that are used to cool atoms. Still, because of the extended possibilities cold molecules can offer with respect to cold atoms, there have been a large number of techniques developed to slow, cool, and trap them. These techniques can be divided into two classes, namely direct and indirect cooling. In the first case, molecules at cryogenic or room temperature are directly slowed and cooled. Although many different slowing techniques are used, this chapter focuses on Stark slowing of molecules since it was the first technique developed. Apart from the Stark shift of the molecules, the Zeeman and light shift of molecules can also be used to slow them. The idea behind Stark slowing is to subject the moving molecules to a continuously increasing electric field so that their kinetic energy is converted into potential energy.
The Chemistry of Cold Interstellar Cloud Cores Gas-Phase Reactive Collisions at Very Low Temperatures: Recent Experimental Advances and Perspectives The Study of Cold Collisions Using Ion Guides and Traps Theory of Low-Temperature Gas-Phase Reactions Molecular Spectroscopy at Low Temperatures: A High-Resolution Infrared Perspective The Production and Study of Ultra-Cold Molecular Ions Chemical Dynamics: Inside Superfluid Helium Nanodroplets at 0.37 K Kinematic Cooling of Molecules Manipulation of Molecules with Electric Fields Cold Collisions, Quantum Degenerate Gases, Photoassociation, and Cold Molecules.
Abstract The invention and development of laser methods for cooling and trapping atoms have led to the advent of the physics of ultracold matter. Low-temperature quantum physics has so far dealt with condensed media, wherein quantum phenomena (superfluidity and superconductivity) usually manifest themselves at temperatures of a few kelvin. Laser cooling and trapping of atoms have made it possible to successively attain millikelvin, microkelvin, and nanokelvin temperatures, at which the de Broglie wavelength of the atoms becomes commensurable with the interatomic separation, even in dilute gases. The interaction of atoms in ultracold dilute gases becomes essentially quantum mechanical. The physics of such quantum gases is more akin to the well-developed physics of condensed matter at low temperatures. It is in essence a boundary field between atomic, laser, and condensed-matter physics. Following the first, pioneering experiments on the Bose–Einstein condensation of alkali-metal atoms, this field has continued to develop at a very fast pace, which can be explained by the vast variety of particles (atoms, isotopes, and molecules) that can be laser cooled and trapped under degeneracy conditions. This is much more than physicists had at their disposal previously (3,4He). Moreover, laser radiation and magnetic fields additionally make it possible to control not only the intrinsic quantum state of the interacting ultracold particle species, but also the interaction of the particles. All this makes the research in the field of quantum gases a great breakthrough, both in atomic–molecular physics and in many-body-interaction physics, which heretofore was the prerogative of low-temperature condensed-matter physics.
Until the nineteenth century, the thermodynamic temperature below 10 K was not attained. Superfluidity and superconductivity were discovered after liquid helium was produced. The kinetic temperature below 1 mK was attained after the laser cooling of gaseous atoms was developed. With ultra-low temperature, the wave nature of atoms became significant. Atomic interferometry was observed, and it is applicable for the measurement of a slight shift in potential energy. With ultra-low kinetic energy, the atomic collision cross-section is much larger than that at room temperature. Bose-Einstein condensate and Fermi degeneracy were observed with ultra-low kinetic energy.
Forty years ago, twenty years after the discovery of the laser, physicists were developing laser cooling methods for ions trapped in electromagnetic fields.From the 1980s onwards, these techniques were refined and extended to atoms, thanks to the audacity and inventiveness of a generation of pioneering researchers.Actually, it was necessary to succeed simultaneously in trapping and cooling samples of atomic gases in a vacuum at a distance from any wall.Spectacular results followed and extraordinarily low temperatures were quickly reached, very close to absolute zero.The field of "cold atoms" was born, rewarded by successive Nobel prizes, first of which was awarded in 1997 to William D. Phillips, Steven Chu and Claude Cohen-Tannoudji, last in 2022 to Alain Aspect.Gaseous samples of a few thousand to a few billion atoms can be prepared at a few millionths of a degree above absolute zero, which means that the particles move at extremely low speed, of the order of centimetres per second.At these extreme temperatures, the behaviour of matter changes and its properties can only be described using quantum mechanics and the wave properties of particles.New physical phenomena have been discovered and innovations have followed the theoretical and experimental progress of the research.Initially imagined as a wonderful method for perfecting atomic physics, cold atoms have gradually proved to be powerful tools for research in cross-cutting fields of physics, such as condensed matter and even high-energy physics.These atoms are now referred to as 'quantum gases' at such low temperatures that their collective behaviour is modified by the laws of quantum mechanics.