We use a pseudofermion representation to investigate strong-field anomalies of the magnetic-field (h) dependence of the specific heat (c) of a spin-1/2 XY chain doped with magnetic impurities. If at certain magnetic field the impurity-induced split-off energy levels come sufficiently close to the chemical potential of pseudofermions (zero), then at low temperatures the specific heat of the chain is significantly altered by even a small number of impurities. The impurity-induced peaks of the c(h) dependence correspond to magnetic fields in a range where the specific heat of the ideal spin-1/2 XY chains is exponentially small. They have the same physical origin, but different structure, as compared to the high-field anomalies of longitudinal magnetic susceptibility investigated previously.