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Physica B Condensed Matter

Specific heat and magnetic susceptibility of ferromagnetic mixed-spin chain systems

Noboru Fukushima, A. Honecker, Stefan Weßel, Simon Grossjohann, Wolfram Brenig

Published Mar 3, 2005• 7 citations
Publisher
DOI
10.1016/j.physb.2005.01.443

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To investigate the magnetization and the effect of anisotropy on thermal properties in external magnetic field,the transfer matrix method is used to calculate exactly the solution to the magnetization in Ising spin ladder with S=1 and S=3/2 mixed together.It's found that if the closest neighboring interaction is ferromagnetic and the next closest interaction between two spin chains is antiferromagnetic,the plateaus of the magnetization m=1/4 and m=3/4 appear in the system,which are consistent with the positions where the magnetization plateaus are possibly appearing in quantum model.Novel dual-peak is observed on the curves of specific heat and susceptibility.
The magnetization process, the susceptibility, and the specific heat of the spin-1∕21∕21∕2 antiferromagnet (AF)-AF-ferromagnet (F) and F-F-AF trimerized quantum Heisenberg chains have been investigated by means of the transfer matrix renormalization group (TMRG) technique as well as the modified spin-wave (MSW) theory. A magnetization plateau at m=1∕6m=1∕6m=1∕6 for both trimerized chains is observed at low temperature. The susceptibility and the specific heat show various behaviors for different ferromagnetic and antiferromagnetic interactions and in different magnetic fields. The TMRG results of susceptibility and the specific heat can be nicely fitted by a linear superposition of double two-level systems, where two fitting equations are proposed. Three branch excitations, one gapless excitation and two gapful excitations, for both systems are found within the MSW theory. It is observed that the MSW theory captures the main characteristics of the thermodynamic behaviors at low temperatures. The TMRG results are also compared with the possible experimental data.
Thermodynamic properties of a tetrameric bond-alternating Heisenberg spin chain with ferromagnetic-ferromagnetic-antiferromagnetic-antiferromagnetic exchange interactions are studied using the transfer-matrix renormalization group and compared to experimental measurements. The temperature dependence of the uniform susceptibility exhibits typical ferrimagnetic features. Both the uniform and staggered magnetic susceptibilities diverge in the limit $T\ensuremath{\rightarrow}0$, indicating that the ground state has both ferromagnetic and antiferromagnetic long-range orders. A double-peak structure appears in the temperature dependence of the specific heat. Our numerical calculation gives a good account for the temperature and field dependence of the susceptibility, the magnetization, and the specific heat for $\mathrm{Cu}{(3\text{\ensuremath{-}}\mathrm{Clpy})}_{2}{({\mathrm{N}}_{3})}_{2}$ $(3\text{\ensuremath{-}}\mathrm{Clpy}=3\text{\ensuremath{-}}\text{Chloroyridine})$.