The DME without truncation leads to a Wigner transform with the same moments as the exact transform. Using a harmonic oscillator model for the magic nuclei we obtain analytic expressions for these moments and compare with those of various truncated DME's.
Abstract The main objective of this research paper is to develop an approach within phase-space quantum mechanics for the pseudo-harmonic oscillator potential, enabling the derivation of analytical expressions for the Wigner distribution function and the formulation of a general expression for the moments associated with higher-order position and momentum operators. This approach also allows for the identification of a key dimensionless parameter α in the phase-space transformations. This parameter contributes to improving the general analytical expression for the energy levels. These energy levels are evaluated numerically and show strong agreement with existing numerical results reported in the literature for various diatomic molecular systems. Furthermore, it has been verified that our results are accurate and satisfy both the Heisenberg-Born-Jordan-Dirac commutation relation and the Heisenberg uncertainty principle.
A density matrix evolution (DME) method (Berendsen, H. J. C., and Mavri, J., 1993, J. phys. Chem., 97, 13464) to simulate the dynamics of quantum systems embedded in a classical environment is applied to study the inelastic collisions of a classical particle with a five level quantum harmonic oscillator. The results are compared with the exact quantum calculations of Secrest, D., and Johnson, B. R., 1966, J. chem. Phys., 45, 4556, and with the results of classical mechanics. The DME results are between the results of the full quantum treatment and classical mechanics but closer to the latter. Furthermore, we demonstrate the time reversibility of the DME equations of motion and discuss the importance for the time reversibility of the quantum phase described by the off-diagonal elements of the density matrix.
We obtain analytic solutions to various models of dissipation of the quantum harmonic oscillator, employing a simple method in the Wigner function Fourier transform description of the system; and study as an exemplification, the driven open quantum harmonic oscillator. The environmental models we use are based on optical master equations for the zero and finite temperature bath and whose open dynamics are described by a Lindblad master equation, and also we use the Caldeira-Leggett model for the high temperature limit, in the the under damped an the over damped case. Under the Wigner Fourier transform or chord function as it has been called, it becomes particularly simple to solve the dynamics of the open oscillator in the sense that the dynamics of the system are reduced to the application of an evolution matrix related to the damped motion of the oscillator.