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Physical Review A

New Green's-Function Method for Canonical Ensembles. I. Interacting Particle-Phonon System

P. C. Kwok, James W. F. Woo

Published Jan 1, 1971• 4 citations
Publisher

Abstract

A new thermodynamic Green's-function method is developed to handle interacting many-body systems containing a small subsystem with a fixed number of particles. The new method involves the use of the canonical ensemble and is more complicated than the usual Green's-function method. But, by means of the functional derivative technique, it is shown that systematic perturbative procedures are available and can be carried out in an entirely straight-forward manner. The example given in the present paper is the system of phonons interacting with a fixed number of fermions. It serves to illustrate the general formulation as well as perturbation calculation in the new method.

DOI
10.1103/physreva.3.437

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Quantum many-body Green-functions: theory, interrelations and applications

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Abstract Green-function techniques are among the most versatile tools for investigating quantum many-body systems at finite temperature. Yet, standard textbook treatments often fragment the formalism—separating bosons and fermions, systems with massless and massive particles, or restricting proofs to special Hamiltonians—thereby obscuring the structural unity of the theory. This work develops a general, Hamiltonian-independent framework for both real- and imaginary-time Green-functions, valid for any combination of bosonic and fermionic degrees of freedom, including mixed systems such as interacting electron–phonon models. The key conceptual advance is the nature index η , which complements the conventional statistical sign ζ . While ζ encodes particle statistics, η distinguishes canonical quantization of systems with massless particles ( η = 0) from second quantization of systems with massive particles ( η = 1). This classification removes ambiguities in chemical-potential terms and unifies the treatment of photons, phonons, electrons, and their mixtures under a single notation. From this basis, we formulate generalized ensemble constructions, generalized Lehmann-representations, and a fluctuation-dissipation theorem valid for arbitrary Hamiltonians. Several results—such as the monotonicity of particle number in the chemical potential, an explicit formula for the quadratic contribution to the internal energy from the retarded Green-function, and the Hartree-contribution to the self-energy in electron–phonon systems—are either absent from, or only sparsely mentioned in, existing literature. We further introduce Green’s Chart, a visual and algebraic map that systematically connects all Green-function types through analytic continuation, Fourier-transforms, and Wick-rotations, enabling all to be generated from the Matsubara Green-function. Applications to both non-interacting and interacting models demonstrate the framework’s ability to compute densities of states, thermodynamic potentials, and spectral functions with a consistent formalism. The results provide a complete and reproducible toolkit for equilibrium many-body theory, consolidating scattered results into a unified structure suitable for both pedagogical and computational purposes.

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Green's-Function Method for Canonical Ensembles. II. Response-Function Calculations

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The calculation of response functions in the Green's-function method for canonical ensembles is illustrated. The example given is the evaluation of the susceptibility of a lattice of magnetic ions in the mean-field approximation.

Physical Review A•Jun 1, 1971•1 citation

Renormalization and Statistical Mechanics in Many-Particle Systems. I. Hamiltonian Perturbation Method

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A general system composed of many weakly interacting bosons and/or fermions is considered. The object is to develop a procedure for renormalizing the single-particle creation operators, so as to remove the interactions to successively higher orders of perturbation. The basic idea is that creation operators ${{\ensuremath{\theta}}_{i}}^{\ifmmode\dagger\else\textdagger\fi{}}$ must satisfy the Hamiltonian commutator equations $[\mathcal{H},{{\ensuremath{\theta}}_{i}}^{\ifmmode\dagger\else\textdagger\fi{}}]={\ensuremath{\omega}}_{i}{{\ensuremath{\theta}}_{i}}^{\ifmmode\dagger\else\textdagger\fi{}}$, where $\mathcal{H}$ is the Hamiltonian and ${\ensuremath{\omega}}_{i}$ are the particle energies. For the many-weakly-interacting-particle system, the zeroth-order boson and fermion creation operators satisfy these equations to zeroth order. It is shown that if the creation operators are renormalized so as to satisfy the Hamiltonian commutator equations to order $m$, and also to satisfy the appropriate boson commutators and fermion anticommutators to order $m$, then the problem is solved to order $m$. In particular, the vectors formed by operating on the ground state with the renormalized creation operators, according to the usual boson and fermion occupation-number representation, are eigenvectors of $\mathcal{H}$ and are orthonormal, all to order $m$. A procedure is otained for finding the ($m+1$)-order contributions to the particle creation energies, in terms of the $m$-order operators. Explicit first-order calculations of these general results are provided for a system of bosons and a system of fermions, and these first-order results are shown to include similar results of Rayleigh-Schr\"odinger perturbation theory, the random-phase approximation, and the method of thermodynamic Green's functions. The problem of anharmonic lattice dynamics is studied in detail, and a method of undetermined coefficients is used to renormalize the phonon creation operators to first order. The phonon energies are calculated to second order, and this calculation shows that the interactions between renormalized phonons cannot be removed in second order. Statistical averages of the phonon energies give the energy shifts and lifetimes which have been calculated previously by various propagator techniques. In addition, the renormalized energies are used to calculate the temperature-dependent part of the Helmholtz free energy correct to second order. As a final example, electron-phonon interactions in a normal metal are studied. The electron and phonon creation operators are renormalized to first order, the particle energies are calculated to second order, and statistical averages of the particle energies recover the usual thermodynamic Green's-function results for energy shifts and lifetimes. These examples show the simplicity by which the renormalization procedure obtains a great amount of detailed information about the single-particle nature of a many-particle system.

Physical Review•Dec 2, 1966•31 citations

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Cambridge University Press eBooks•Jan 2, 2025•0 citations
A new thermodynamic Green's-function method is developed to handle interacting many-body systems containing a small subsystem with a fixed number of particles. The new method involves the use of the canonical ensemble and is more complicated than the usual Green's-function method. But, by means of the functional derivative technique, it is shown that systematic perturbative procedures are available and can be carried out in an entirely straight-forward manner. The example given in the present paper is the system of phonons interacting with a fixed number of fermions. It serves to illustrate the general formulation as well as perturbation calculation in the new method.
Abstract Green-function techniques are among the most versatile tools for investigating quantum many-body systems at finite temperature. Yet, standard textbook treatments often fragment the formalism—separating bosons and fermions, systems with massless and massive particles, or restricting proofs to special Hamiltonians—thereby obscuring the structural unity of the theory. This work develops a general, Hamiltonian-independent framework for both real- and imaginary-time Green-functions, valid for any combination of bosonic and fermionic degrees of freedom, including mixed systems such as interacting electron–phonon models. The key conceptual advance is the nature index η , which complements the conventional statistical sign ζ . While ζ encodes particle statistics, η distinguishes canonical quantization of systems with massless particles ( η = 0) from second quantization of systems with massive particles ( η = 1). This classification removes ambiguities in chemical-potential terms and unifies the treatment of photons, phonons, electrons, and their mixtures under a single notation. From this basis, we formulate generalized ensemble constructions, generalized Lehmann-representations, and a fluctuation-dissipation theorem valid for arbitrary Hamiltonians. Several results—such as the monotonicity of particle number in the chemical potential, an explicit formula for the quadratic contribution to the internal energy from the retarded Green-function, and the Hartree-contribution to the self-energy in electron–phonon systems—are either absent from, or only sparsely mentioned in, existing literature. We further introduce Green’s Chart, a visual and algebraic map that systematically connects all Green-function types through analytic continuation, Fourier-transforms, and Wick-rotations, enabling all to be generated from the Matsubara Green-function. Applications to both non-interacting and interacting models demonstrate the framework’s ability to compute densities of states, thermodynamic potentials, and spectral functions with a consistent formalism. The results provide a complete and reproducible toolkit for equilibrium many-body theory, consolidating scattered results into a unified structure suitable for both pedagogical and computational purposes.
The Green’s function method is among the most powerful and versatile formalisms in physics, and its nonequilibrium version has proved invaluable in many research fields. With entirely new chapters and updated example problems, the second edition of this popular text continues to provide an ideal introduction to nonequilibrium many-body quantum systems and ultrafast phenomena in modern science. Retaining the unique and self-contained style of the original, this new edition has been thoroughly revised to address interacting systems of fermions and bosons, simplified many-body approaches like the GKBA, the Bloch equations, and the Boltzmann equations, and the connection between Green’s functions and newly developed time-resolved spectroscopy techniques. Small gaps in the theory have been filled, and frequently overlooked subtleties have been systematically highlighted and clarified. With an abundance of illustrative examples, insightful discussions, and modern applications, this book remains the definitive guide for students and researchers alike.
The Green’s function method is among the most powerful and versatile formalisms in physics, and its nonequilibrium version has proved invaluable in many research fields. With entirely new chapters and updated example problems, the second edition of this popular text continues to provide an ideal introduction to nonequilibrium many-body quantum systems and ultrafast phenomena in modern science. Retaining the unique and self-contained style of the original, this new edition has been thoroughly revised to address interacting systems of fermions and bosons, simplified many-body approaches like the GKBA, the Bloch equations, and the Boltzmann equations, and the connection between Green’s functions and newly developed time-resolved spectroscopy techniques. Small gaps in the theory have been filled, and frequently overlooked subtleties have been systematically highlighted and clarified. With an abundance of illustrative examples, insightful discussions, and modern applications, this book remains the definitive guide for students and researchers alike.
A general system composed of many weakly interacting bosons and/or fermions is considered. The object is to develop a procedure for renormalizing the single-particle creation operators, so as to remove the interactions to successively higher orders of perturbation. The basic idea is that creation operators ${{\ensuremath{\theta}}_{i}}^{\ifmmode\dagger\else\textdagger\fi{}}$ must satisfy the Hamiltonian commutator equations $[\mathcal{H},{{\ensuremath{\theta}}_{i}}^{\ifmmode\dagger\else\textdagger\fi{}}]={\ensuremath{\omega}}_{i}{{\ensuremath{\theta}}_{i}}^{\ifmmode\dagger\else\textdagger\fi{}}$, where H\mathcal{H}H is the Hamiltonian and ${\ensuremath{\omega}}_{i}$ are the particle energies. For the many-weakly-interacting-particle system, the zeroth-order boson and fermion creation operators satisfy these equations to zeroth order. It is shown that if the creation operators are renormalized so as to satisfy the Hamiltonian commutator equations to order mmm, and also to satisfy the appropriate boson commutators and fermion anticommutators to order mmm, then the problem is solved to order mmm. In particular, the vectors formed by operating on the ground state with the renormalized creation operators, according to the usual boson and fermion occupation-number representation, are eigenvectors of H\mathcal{H}H and are orthonormal, all to order mmm. A procedure is otained for finding the (m+1m+1m+1)-order contributions to the particle creation energies, in terms of the mmm-order operators. Explicit first-order calculations of these general results are provided for a system of bosons and a system of fermions, and these first-order results are shown to include similar results of Rayleigh-Schr\"odinger perturbation theory, the random-phase approximation, and the method of thermodynamic Green's functions. The problem of anharmonic lattice dynamics is studied in detail, and a method of undetermined coefficients is used to renormalize the phonon creation operators to first order. The phonon energies are calculated to second order, and this calculation shows that the interactions between renormalized phonons cannot be removed in second order. Statistical averages of the phonon energies give the energy shifts and lifetimes which have been calculated previously by various propagator techniques. In addition, the renormalized energies are used to calculate the temperature-dependent part of the Helmholtz free energy correct to second order. As a final example, electron-phonon interactions in a normal metal are studied. The electron and phonon creation operators are renormalized to first order, the particle energies are calculated to second order, and statistical averages of the particle energies recover the usual thermodynamic Green's-function results for energy shifts and lifetimes. These examples show the simplicity by which the renormalization procedure obtains a great amount of detailed information about the single-particle nature of a many-particle system.
The Green’s function method is among the most powerful and versatile formalisms in physics, and its nonequilibrium version has proved invaluable in many research fields. With entirely new chapters and updated example problems, the second edition of this popular text continues to provide an ideal introduction to nonequilibrium many-body quantum systems and ultrafast phenomena in modern science. Retaining the unique and self-contained style of the original, this new edition has been thoroughly revised to address interacting systems of fermions and bosons, simplified many-body approaches like the GKBA, the Bloch equations, and the Boltzmann equations, and the connection between Green’s functions and newly developed time-resolved spectroscopy techniques. Small gaps in the theory have been filled, and frequently overlooked subtleties have been systematically highlighted and clarified. With an abundance of illustrative examples, insightful discussions, and modern applications, this book remains the definitive guide for students and researchers alike.