We study the decay of magnetically trapped doubly spin-polarized atomic hydrogen in the density and temperature regime of the Bose-Einstein phase transition and calculate the temperature and magnetic field dependence of all relevant relaxation rate constants ${G}_{\mathrm{dd}\ensuremath{\rightarrow}\ensuremath{\kappa}\ensuremath{\lambda}}$. At the transition temperature
Tc the rate constants have a discontinuous second derivative with respect to T. Below
Tc they show a pronounced decrease relative to the extrapolated above-
Tc values, the observation of which is a clear signal for the experimental realization of Bose-Einstein condensation.
A calculation is presented of the relaxation rate ${{T}_{1}}^{\ensuremath{-}1}$ between the lowest two hyperfine states of a dilute gas of H atoms in high magnetic field at low temperatures. Dipole-dipole interactions dominate ${{T}_{1}}^{\ensuremath{-}1}$, leading to long relaxation times at low temperatures (${{T}_{1}}^{\ensuremath{-}1}\ensuremath{\approx}{10}^{\ensuremath{-}2}{n}_{\mathrm{H}}{T}^{\frac{1}{2}}$ ${\mathrm{sec}}^{\ensuremath{-}1}$ at $H\ensuremath{\approx}100$ kG). The recombination rate due to wall collisions is much greater than ${{T}_{1}}^{\ensuremath{-}1}$ and can lead to a depletion of the lowest hyperfine state from thermal equilibrium and an effective recombination rate equal to ${{T}_{1}}^{\ensuremath{-}1}$.
We have studied relaxation and recombination processes in compressed, doubly polarized atomic hydrogen at temperatures from 0.13 to 0.60 K and magnetic fields from 3 to 9 T. The gas and surface dipole three-body recombination rate constants at a field of 7.6 T are measured to be, respectively,
Lg=8.9(8)\ifmmode\times\else\texttimes\fi{}${10}^{\mathrm{\ensuremath{-}}39}$
cm6 ${\mathrm{s}}^{\mathrm{\ensuremath{-}}1}$ and
Ls=1.2(4)\ifmmode\times\else\texttimes\fi{}${10}^{\mathrm{\ensuremath{-}}24}$
cm4 ${\mathrm{s}}^{\mathrm{\ensuremath{-}}1}$. They decrease slowly with field and
Ls exhibits no significant angular dependence. The three-body recombination rate due to hyperfine mixing has also been measured. Electronic and nuclear relaxation rates have been measured; the b-c electronic relaxation rate constant in the gas is
Gbc=1.03(7)\ifmmode\times\else\texttimes\fi{}${10}^{\mathrm{\ensuremath{-}}15}$
cm3 ${\mathrm{s}}^{\mathrm{\ensuremath{-}}1}$exp(-
Ebc/
kBT). The temperature and field dependence of the nuclear relaxation rate in the gas are observed to be in excellent agreement with recent theoretical calculations. Three-body surface recombination-rate measurements using $^{3}\mathrm{\ensuremath{-}}^{4}$He surfaces indicate that as little as one monolayer of
3He on the liquid
4He surface appreciably decreases the adsorption energy of atomic hydrogen. Densities achieved include 4.5\ifmmode\times\else\texttimes\fi{}
1018 atoms${\mathrm{?}}^{\mathrm{\ensuremath{-}}3}$ at 0.55 K (pure
4He walls), and 1.4\ifmmode\times\else\texttimes\fi{}
1018 atoms${\mathrm{?}}^{\mathrm{\ensuremath{-}}3}$ at 0.19 K (8 at. ? sup 3---He).
A model of spin-polarized hydrogen (H\ensuremath{\uparrow}) is treated in which interactions between atoms are neglected while the single-atom Zeeman and hyperfine interactions are treated exactly. These magnetic terms in the Hamiltonian are found to affect substantially the Bose-Einstein condensation and the various thermodynamic variables. Computations are discussed of the condensation temperature, condensate density, and specific heat in order to indicate how changes in magnetic field strength might be expected to affect future measurements on this quantum system.