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The Journal of Chemical Physics

Non-Markovian effects on quantum optimal control of dissipative wave packet dynamics

Yukiyoshi Ohtsuki

Published Jun 30, 2003• 40 citations
Publisher

Abstract

Optimal control within the density matrix formalism is applied to the creation of a specified superposition state in condensed phases. The primary system modeled by a displaced harmonic oscillator is surrounded by a boson heat bath, the dynamics of which is described by a non-Markovian master equation. A newly developed monotonically convergent algorithm is used to solve the pulse design equations. The control mechanisms are strongly dependent on the bath correlation time that is characterized by the inverse of an exponential decay constant, γ. If the correlation time is shorter than the temporal width of a typical subpulse involved in an optimal pulse, the solution is reduced to that in the Markovian case. If we assume a longer correlation time, by weighing less physical significance on the penalty due to pulse fluence, an optimal pulse with high intensity is obtained, the temporal width of which approaches ∼1/γ. We also see considerable changes in the shape of the optimal pulse with increasing intensity, suggesting that strong fields open up control mechanisms that are qualitatively different from those in weak fields.

DOI
10.1063/1.1576385

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Optimal control within the density matrix formalism is applied to the creation of a specified superposition state in condensed phases. The primary system modeled by a displaced harmonic oscillator is surrounded by a boson heat bath, the dynamics of which is described by a non-Markovian master equation. A newly developed monotonically convergent algorithm is used to solve the pulse design equations. The control mechanisms are strongly dependent on the bath correlation time that is characterized by the inverse of an exponential decay constant, γ. If the correlation time is shorter than the temporal width of a typical subpulse involved in an optimal pulse, the solution is reduced to that in the Markovian case. If we assume a longer correlation time, by weighing less physical significance on the penalty due to pulse fluence, an optimal pulse with high intensity is obtained, the temporal width of which approaches ∼1/γ. We also see considerable changes in the shape of the optimal pulse with increasing intensity, suggesting that strong fields open up control mechanisms that are qualitatively different from those in weak fields.
An efficient optimal-control theory based on the Krotov method is introduced for a non-Markovian open quantum system with a time-nonlocal master equation in which the control parameter and the bath correlation function are correlated. This optimal-control method is developed via a quantum dissipation formulation that transforms the time-nonlocal master equation to a set of coupled linear time-local equations of motion in an extended auxiliary Liouville space. As an illustration, the optimal-control method is applied to find the control sequences for high-fidelity ZZZ gates and identity gates of a qubit embedded in a non-Markovian bath. ZZZ gates and identity gates with errors less than ${10}^{\ensuremath{-}5}$ for a wide range of bath decoherence parameters can be achieved for the non-Markovian open qubit system with control over only the ${\ensuremath{\sigma}}_{z}$ term. The control-dissipation correlation and the memory effect of the bath are crucial in achieving the high-fidelity gates.
Optimal control theory is implemented with fully converged hierarchical equations of motion (HEOM) describing the time evolution of an open system density matrix strongly coupled to the bath in a spin-boson model. The populations of the two-level sub-system are taken as control objectives; namely, their revivals or exchange when switching off the field. We, in parallel, analyze how the optimal electric field consequently modifies the information back flow from the environment through different non-Markovian witnesses. Although the control field has a dipole interaction with the central sub-system only, its indirect influence on the bath collective mode dynamics is probed through HEOM auxiliary matrices, revealing a strong correlation between control and dissipation during a non-Markovian process. A heterojunction is taken as an illustrative example for modeling in a realistic way the two-level sub-system parameters and its spectral density function leading to a non-perturbative strong coupling regime with the bath. Although, due to strong system-bath couplings, control performances remain rather modest, the most important result is a noticeable increase of the non-Markovian bath response induced by the optimally driven processes.
A Markovian master equation describing the evolution of open quantum systems in the presence of a time-dependent external field is derived within the Bloch-Redfield formalism. It leads to a system-bath interaction which depends on the control field. Optimal control theory is used to select control fields which allow accelerated or decelerated system relaxation, or suppression of relaxation (dissipation) altogether, depending on the dynamics we impose on the quantum system. The control-dissipation correlation and the nonperturbative treatment of the control field are essential for reaching this goal. The optimal control problem is formulated within Pontryagin's minimum principle and the resulting optimal differential system is solved numerically. As an application, we study the dynamics of a spin-boson model in the strong coupling regime under the influence of an external control field. We show how trapping the system in unstable quantum states and transfer of population can be achieved by optimized control of the dissipative quantum system. We also used optimal control theory to find the driving field that generates the quantum ZZZ gate. In several cases studied, we find that the selected optimal field which reduces the purity loss significantly is a multicomponent low-frequency field including higher harmonics, all of which lie below the phonon cutoff frequency. Finally, in the undriven case we present an analytic result for the Lamb shift at zero temperature.
Referring to a Fano-type model qualitative analogy we develop a comprehensive basic mechanism for the laser control of the non-Markovian bath response and fully implement it in a realistic control scheme, in strongly coupled open quantum systems. Converged hierarchical equations of motion are worked out to numerically solve the master equation of a spin-boson Hamiltonian to reach the reduced electronic density matrix of a heterojunction in the presence of strong terahertz laser pulses. Robust and efficient control is achieved increasing by a factor of 2 the non-Markovianity measured by the time evolution of the volume of accessible states. The consequences of such fields on the central system populations and coherence are examined, putting the emphasis on the relation between the increase of non-Markovianity and the slowing down of decoherence processes.
The precise characterization of dynamics in open quantum systems often presents significant challenges, leading to the introduction of various approximations to simplify a model. One commonly used strategy involves Markovian approximations, assuming a memoryless environment. In this study, such approximations are not used and an analytical dynamical depiction of an open quantum system is provided. The system under consideration is an oscillator that is surrounded by a bath of oscillators. The resulting dynamics are characterized by a second-order complex coefficient linear differential equation, which may be either homogeneous or inhomogeneous. Moreover, distinct dynamical regions emerge, depending on certain parameter values. Notably, the steady-state average excitation number (AEN) of the system shows rapid escalation with increasing non-Markovianity, reflecting the intricacies of real-world dynamics. In cases where there is detuning between the system frequency and the environmental central frequency within a non-Markovian regime, the AEN maintains its initial value for an extended period. Furthermore, the application of pulse control can effectively protect the quantum system from decoherence effects without using approximations. The pulse control can not only prolong the relaxation time of the oscillator, but can also be used to speed up the relaxation process, depending on the specifications of the pulse. By employing a kick pulse, the Mpemba effect can be observed in the non-Markovian regime in a surprisingly super-cooling-like effect.
The problem of optimal control of non-Markovian open quantum system via weak measurement is presented. Based on the non-Markovian master equation, we evaluate exactly the non-Markovian effect on the dynamics of the system of interest interacting with a dissipative reservoir. We find that the non-Markovian reservoir has dual effects on the system: dissipation and backaction. The dissipation exhausts the coherence of the quantum system, whereas the backaction revives it. Moreover, we design the control Hamiltonian with the control laws attained by the stochastic optimal control and the corresponding optimal principle. At last, we considered the exact decoherence dynamics of a qubit in a dissipative reservoir composed of harmonic oscillators, and demonstrated the effectiveness of our optimal control strategy. Simulation results showed that the coherence will completely lost in the absence of control neither in non-Markovian nor Markovian system. However, the optimal feedback control steers it to a stationary stochastic process which fluctuates around the target. In this case the decoherence can be controlled effectively, which indicates that the engineered artificial reservoirs with optimal feedback control may be designed to protect the quantum coherence in quantum information and quantum computation.