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Physical Review Letters

Phase diagram of systems with pairing of spatially separated electrons and holes

S. I. Shevchenko

Published May 16, 1994• 78 citations
Publisher

Abstract

The unusual mechanism of superconductivity, which was predicted earlier and is due to the pairing of spatially separated electrons and holes, is dramatically dependent on interband transitions capable of fixing the order parameter phase and thus eliminating superfluidity. In this paper the conditions are found under which the interband transitions do not prohibit superfluidity of pairs. A phase diagram is plotted for the corresponding systems.

DOI
10.1103/physrevlett.72.3242

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The unusual mechanism of superconductivity, which was predicted earlier and is due to the pairing of spatially separated electrons and holes, is dramatically dependent on interband transitions capable of fixing the order parameter phase and thus eliminating superfluidity. In this paper the conditions are found under which the interband transitions do not prohibit superfluidity of pairs. A phase diagram is plotted for the corresponding systems.
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An important question about unconventional superconductors is how attractions can emerge in a purely repulsive electronic system. Here, the authors study comprehensively one such electronic mechanism, where pairing is induced by a third electron undergoing a virtual interband transition. Their exact solution of an illustrative Hubbard model establishes superconductivity due to interband polarization in both the weak and strong coupling regimes. Relevance of this pairing mechanism for twisted bilayer graphene is also discussed.
Our previous mean-field study concerning superconducting pairings in the extended Hubbard model with on-site repulsive and intersite attractive interaction and arbitrary electron density is extended to include the effects of nearest-neighbor exchange (JJJ) and correlated hopping (KKK) interaction. Detailed numerical analysis of sss-, ppp-, and ddd-wave pairing solutions is performed for the two-dimensional square lattice with nearest- (ttt) and next-nearest- (t2{t}_{2}t2​) neighbor hopping, and the resulting mutual stability phase diagrams are given as a function of band filling and the interaction parameters. Antiferromagnetic exchange can enhance both the ddd-wave and the extended sss-wave pairing. If it prevails over the repulsive intersite density-density interaction, such a term can be a leading mechanism for superconductivity. However, its effects strongly depend on the band filling and the t2t\frac{{t}_{2}}{t}tt2​​ ratio, giving in particular for t2=0{t}_{2}=0t2​=0 sss-wave (ddd-wave) pairing as most favorable in the low (high) density limit, but increasing t2{t}_{2}t2​ can even reverse this tendency. The correlated hopping term which breaks the electron-hole symmetry affects sss-wave pairing mostly. A condensation transition (phase separation), possible in the presence of the attractive density-density interaction, is also analyzed within the random-phase approximation, and stability conditions of such an electron droplet phase with respect to other types of ordering are determined as a function of the band filling for the two-dimensional square lattice.
We study an exchange coupled system of itinerant electrons and localized fermion pairs resulting in a resonant pairing formation. This system inherently contains resonating fermion pairs on bonds that lead to a superconducting phase, provided that long-range phase coherence between their constituents can be established. The prerequisite is that the resonating fermion pairs can become itinerant. This is rendered possible through the emergence of two kinds of bond fermions: individual and composite fermions made of one individual electron attached to a bound pair on a bond. If the strength of the exchange coupling exceeds a certain value, then the superconducting ground state undergoes a quantum phase transition into an insulating pair-bond liquid state. The gap of the superfluid phase thereby goes over continuously into a charge gap of the insulator. The changeover from the superconducting to the insulating phase is accompanied by a corresponding qualitative modification of the dispersion of the two kinds of fermionic excitations. Using a bond operator formalism, we derive the phase diagram of such a scenario together with the elementary excitations characterizing the various phases as a function of the exchange coupling and the temperature.
Various BCS-like pairing theories are still invariably used to describe the unusual superconducting/superfluid states and properties of condensed matters without clarifying the fermionic or bosonic nature of Cooper pairs and the relevant mechanisms of superconductivity and superfluidity. We show that the bosonization of Cooper pairs and the novel superconductivity and superfluidity resulting from the condensation of an attractive Bose gas of Cooper pairs into a superfluid state in high-Tc cuprates and other exotic systems occur under the condition εF≲2εA (where εF is the Fermi energy, εA is the energy of the effective attraction between fermions). We argue that the simple BCS criterion (i.e. formation of an energy gap on the Fermi surface) is insufficient for the occurrence of unconventional superconductivity (superfluidity) and the superconducting/superfluid transition in attractive Bose systems is more λ-like than the usual Bose–Einstein condensation. The new and specific criteria for unconventional superconductivity and superfluidity are formulated. Mean-field theory of the three- and two-dimensional superfluid Bose condensates of Cooper pairs describes reasonably well the novel superconducting states (i.e., two distinct superconducting phases below the bulk superconducting transition temperature Tc and a vortex-like state above Tc) and properties (such as λ-like transition at Tc, first-order phase transition and gapless bosonic excitations somewhat below Tc or even far below Tc) of high-Tc cuprates in full agreement with the experimental findings. The unusual superconducting/superfluid states and properties of heavy-fermion and organic compounds, Sr2RuO4, 3He, 4He and atomic Fermi gases are explained more clearly by this theory.