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Physical Review A

Nonlinear quantum spin dynamics: Symmetries without conservation laws

Thomas F. Jordan

Published Jun 1, 1994• 6 citations
Publisher

Abstract

Spin examples demonstrate a nonlinear quantum mechanics. The Hamiltonian operator depends on the state. It contains mean values together with operators. Symmetries depend on these mean values. The requirement for a symmetry operator is not simply that it commutes with the Hamiltonian operator. Rotation invariance does not imply that for the angular-momentum operator. The Hamiltonian operator can change as the state changes. There may be no conserved energy. In examples for spin 1/2 and spin 1, the angle between precessing spin and magnetic field changes. This suggests possibilities for new precision tests of linearity.

DOI
10.1103/physreva.49.5086

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Spin examples demonstrate a nonlinear quantum mechanics. The Hamiltonian operator depends on the state. It contains mean values together with operators. Symmetries depend on these mean values. The requirement for a symmetry operator is not simply that it commutes with the Hamiltonian operator. Rotation invariance does not imply that for the angular-momentum operator. The Hamiltonian operator can change as the state changes. There may be no conserved energy. In examples for spin 1/2 and spin 1, the angle between precessing spin and magnetic field changes. This suggests possibilities for new precision tests of linearity.
Quantization of spin and orbital angular momenta in standard quantum mechanics is rooted in the fundamental rotational symmetry of space in conjunction with the results of experiments on atomic and subatomic particles conducted with the Stern-Gerlach apparatus. We explain some of the most important features of spin and orbital angular momenta as inescapable consequences of elementary Stern-Gerlach experiments viewed in light of the rotational symmetry of space. The rotation operator is first derived for spin-½ particles, then extended to spin-1 particles by treating the case of a hydrogen atom in its ground state, where the spin of the proton combines with that of the electron to create a spin-1 triplet state. Along the way, we examine the evolution of a particle’s spin state under an applied magnetic field, where the interaction energy arises from the existence of a magnetic dipole moment for each particle in proportion to its spin angular momentum. Whereas a constant magnetic field B0 causes the particle’s magnetic moment to gyrate around the direction of B0, it will be seen that the presence of a small oscillating magnetic field perpendicular to B0 brings about the so-called Rabi oscillations, which involve periodic flippings of the particle’s spin orientation. In the case of a hydrogen atom in its ground state, the interaction between the magnetic dipole moments of the proton and the electron splits the ground state between a lower energy singlet having a net angular momentum of zero (spin-0 state), and a higher energy triplet having a total angular momentum of ħ (spin-1 state). This hyperfine splitting is the source of the well-known 21-cm line observed in the spectrum of the hydrogen atom, which arises from transitions between the atom’s singlet and triplet states. In the final section, we put forward an argument (originally made by Richard Feynman) that ties the rotational symmetry of space to the conservation of angular momentum in quantum mechanics. The argument is, in fact, quite general, enabling one to deduce other conservation laws from various inherent symmetries of quantum mechanical systems.
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We discuss Hamiltonian symmetries and invariants for quantum systems driven by non-Hermitian Hamiltonians. For time-independent Hermitian Hamiltonians, a unitary or antiunitary transformation AHA†AHA^\daggerAHA† that leaves the Hamiltonian HHH unchanged represents a symmetry of the Hamiltonian, which implies the commutativity [H,A]=0[H,A]=0[H,A]=0, and a conservation law, namely the invariance of expectation values of AAA. For non-Hermitian Hamiltonians, H†H^\daggerH† comes into play as a distinct operator that complements HHH in generalized unitarity relations. The above description of symmetries has to be extended to include also AAA-pseudohermiticity relations of the form AH=H†AAH=H^\dagger AAH=H†A. A superoperator formulation of Hamiltonian symmetries is provided and exemplified for Hamiltonians of a particle moving in one-dimension considering the set of AAA operators forming Klein's 4-group: parity, time-reversal, parity\&time-reversal, and unity. The link between symmetry and conservation laws is discussed and shown to be more subtle for non-Hermitian than for Hermitian Hamiltonians.
The structures are physical systems and/or their mathematical descriptions consisting of elements such as particles, fields, observables, operators etc and of relations between these elements: the equations of motion and the rules of quantum mechanics. Examples of symmetries are reflections, permutations of particles, time reversal. The physical system has a symmetry group means, then, that there is a group of transformations leaving the equations of motion and the rules of quantum mechanics invariant. The discrete symmetries lead to conservation laws frequently expressible in terms of quantum numbers, but sometimes requiring a more elaborate description. The observables corresponding to the super-selection quantum numbers can be measured without disturbing any other measurement; their values are always sharp. The chapter shows that the invariant subspace may be labelled by continuous quantum numbers (for instance momentum) when the direct sum becomes a direct integral.
The equivalence of Schrödinger and Heisenberg pictures is often thought to break down in nonlinear quantum mechanics due to the absence of a state-independent unitary propagator. We show that for Hamiltonians depending on the state through instantaneous expectation values, the equivalence is preserved. While the unitary intertwiner becomes initial-state dependent, it remains well-defined and ensures identical physical predictions in both pictures. We illustrate this with the analytically solvable examples of a nonlinear spin precession and a mean-field harmonic force, as well as in local field theory with mean-field coupling.