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Journal of Applied Spectroscopy

Determination of the populations of the (32P1/2, 32P3/2) levels with laser excitation of sodium vapor

S. Ya. Putninya, Zh. L. Shvegzhda, M. L. Yanson

Published May 1, 1984• 1 citation
Publisher
DOI
10.1007/bf00661454

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IEEE Journal of Quantum Electronics•Feb 1, 1978•23 citations
Coherence transfer accompanying 32P1/2 → 32P3/2 excitation transfer in sodium, induced in collisions with noble gas atoms, has been investigated using methods of sensitized fluorescence. Oriented 32P1/2 sodium atoms were produced by irradiating a mixture of sodium vapor and a noble gas with D1σ+ resonance radiation, and their subsequent collisions with the buffer gas atoms resulted in the simultaneous transfer of coherence and excitation from the 2P1/2 state to the 2P3/2 state. Measurements of the ratio of circular polarizations of the D2 sensitized fluorescence and D1 resonance fluorescence resulted in the following cross sections for coherence transfer. Na–He : 7.1 ± 0.7 Å2; Na–Ne : 6.2 ± 0.6 Å2; Na–Ar : 12.0 ± 1.2 Å2; Na–Kr : 6.8 ± 0.7 Å2; Na–Xe : 6.9 ± 0.7 Å2.
The new method of atomic fluorescence detection, called saturated optical nonresonant emission spectroscopy (SONRES), has been modeled for a three-level atom, and experiments on sodium have been conducted that support the model. A rate equation analysis yielded expressions for excited-state atomic populations and saturation intensity. The detection of sodium in buffer gases that promote collisional transfer of excitation between 32P1/2→ 32p3/2both without quenching the fluorescence emission and with quenching was considered. Experimental results are presented for sodium in argon. At -25°C, approximately 180 atoms/cm3were monitored with a S/N of ∼ 15 representing detection at the level of one part in 1017. The signal at this temperature was generated by less than a single atom in the laser beam.