The Journal of Chemical Physics
Local and nonlocal approximation for a simple quantum system
Markus A. Palenberg, R. Silbey, Ch. Warns, P. Reineker
Abstract
We apply two commonly used approximation schemes to the problem of a symmetric dimer with dynamic diagonal disorder. Since the exact analytical solution for this simple dissipative quantum system is known, we are in position to test the range of validity and the quality of the approximations and to derive guidelines for the application of the approximations to more complex systems.