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Physical review. B, Condensed matter

Low-temperature properties of a two-level system interacting with conduction electrons: An application of the overcompensated multichannel Kondo model

Pedro D Sacramento, P. Schlottmann

Published Jun 1, 1991• 115 citations
Publisher

Abstract

We consider an atom in a double-well potential [parametrized by a two-level system (TLS)] interacting with screened conduction electrons. The tunneling of the TLS is assisted by the Fermi gas. Close to the strong-coupling fixed point the renormalization-group equations for the noncommutative model in the case of spinless fermions, but an arbitrary number of relevant orbital channels, lead to the n-channel Kondo problem with S=1/2. By solving the thermodynamic Bethe-ansatz equations for the n-channel Kondo problem numerically in the presence of a magnetic field, we discuss the low-temperature properties of the TLS close to the fixed point. The Zeeman splitting corresponds to the energy difference between the two positions of the tunneling atom. The atom is not localized at one of the potential minima. The susceptibility diverges as H\ensuremath{\rightarrow}0 and T\ensuremath{\rightarrow}0, indicating that the symmetric TLS is unstable against a local lattice deformation via coupling to phonons. The lattice distortion disappears above a critical temperature ${\mathit{T}}_{\mathit{c}}$. The ground-state equilibrium situation of the TLS corresponds to H\ensuremath{\ne}0 and a Fermi-liquid picture applies. The values for the specific heat become very large as H\ensuremath{\rightarrow}0. For small fields the specific heat shows a double-peak structure, which is particularly pronounced for n=2.

DOI
10.1103/physrevb.43.13294

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We consider an atom in a double-well potential [parametrized by a two-level system (TLS)] interacting with screened conduction electrons. The tunneling of the TLS is assisted by the Fermi gas. Close to the strong-coupling fixed point the renormalization-group equations for the noncommutative model in the case of spinless fermions, but an arbitrary number of relevant orbital channels, lead to the n-channel Kondo problem with S=1/2. By solving the thermodynamic Bethe-ansatz equations for the n-channel Kondo problem numerically in the presence of a magnetic field, we discuss the low-temperature properties of the TLS close to the fixed point. The Zeeman splitting corresponds to the energy difference between the two positions of the tunneling atom. The atom is not localized at one of the potential minima. The susceptibility diverges as H\ensuremath{\rightarrow}0 and T\ensuremath{\rightarrow}0, indicating that the symmetric TLS is unstable against a local lattice deformation via coupling to phonons. The lattice distortion disappears above a critical temperature Tc{\mathit{T}}_{\mathit{c}}Tc​. The ground-state equilibrium situation of the TLS corresponds to H\ensuremath{\ne}0 and a Fermi-liquid picture applies. The values for the specific heat become very large as H\ensuremath{\rightarrow}0. For small fields the specific heat shows a double-peak structure, which is particularly pronounced for n=2.
We review analytical and numerical results derived from the Bethe ansatz solution of the n-channel Kondo model of arbitrary spin S as a function of temperature, external field, impurity spin S and the number of channels n. Three situations have to be distinguished: (i) If n = 2S the conduction electrons exactly compensate the impurity spin into a singlet at low temperatures, (ii) if n < 2S the impurity spin is only partially compensated (undercompensated), and (iii) if n > 2S the impurity spin is said to be overcompensated giving rise to critical behaviour. The results are discussed in the context of magnetic impurities, e.g. Fe, Cr and Tm in simple metals, the quadrupolar Kondo effect, an impurity spin embedded in the Takhtajan-Babujian Heisenberg model and electron assisted-tunnelling of an atom in a double-well potential.
We construct and solve numerically the thermodynamic Bethe-ansatz equations for the spin-anisotropic two-channel Kondo model in arbitrary external field h. At high temperatures the specific heat and the susceptibility show power-law dependence. For $\stackrel{\ensuremath{\rightarrow}}{h}0$ and at temperatures below the Kondo temperature TK{T}_{K}TK​ a two-channel Kondo effect develops characterized by a Wilson ratio 8/3,8/3,8/3, and a logarithmic divergence of the susceptibility and the linear specific-heat coefficient. A finite magnetic field, h>0,h>0,h>0, drives the system to a Fermi-liquid fixed point with an unusual Wilson ratio which depends sensitively on h.
The two-channel Kondo (2CK) effect with its exotic ground state properties has remained difficult to realize in physical systems. At low energies, a quantum impurity with orbital degree of freedom, like a proton bound in an interstitial lattice space, comprises a 3-level system with a unique ground state and (at least) doubly degenerate rotational excitations with excitation energy Delta0Delta_0Delta0​. When immersed in a metal, electronic angular momentum scattering induces transitions between any two of these levels (couplings JJJ), while the electron spin is conserved. We show by extensive numerical renormalization group (NRG) calculations that without fine-tuning of parameters this system exhibits a 2CK fixed point, due to Kondo correlations in the excited-state doublet whose degeneracy is stabilized by the host lattice parity, while the channel symmetry (electron spin) is guaranteed by time reversal symmetry. We find a pronounced plateau in the entropy at S(TK<T<Delta0)=kBln2S(T_K < T < Delta_0) = k_B ln 2S(TK​<T<Delta0​)=kB​ln2 between the high-TTT value, S(TggDelta0)=kBln3S(T gg Delta_0) = k_B ln 3S(TggDelta0​)=kB​ln3, and the 2CK ground state value, S(0)=kBlnsqrt2S(0) = k_B lnsqrt{2}S(0)=kB​lnsqrt2. This indicates a downward renormalization of the doublet below the non-interacting ground state, thus realizing the 2CK fixed point, in agreement with earlier conjectures. We mapped out the phase diagram of the model in the J−Delta0J-Delta_0J−Delta0​ plane. The Kondo temperature TKT_KTK​ shows non-monotonic JJJ-dependence, characteristic for 2CK systems.newline indent Beside the two-channel Kondo effect of the model, we also study the single-channel version, which is realized by applying a strong magnetic field to the conduction band electrons so that their degeneracy is lifted and consequently having only one kind of electrons scattering off the impurity. This single-channel case is easier to analyze since the Hilbert space is not as large as that of the 2CK. We equally find a downward renormalization of the excited state energy by the Kondo correlations in the SU(2) doublet. In a wide range of parameter values this stabilizes the single-channel Kondo fixed point and a phase diagram is also mapped out for the model. In the single-channel version a plateau is found in the entropy at S(TK<T<Delta0)=kBln2S(T_K < T < Delta_0) = k_B ln 2S(TK​<T<Delta0​)=kB​ln2 between high-TTT value, S(TggDelta0)=kBln3S(T gg Delta_0) = k_B ln 3S(TggDelta0​)=kB​ln3, and the single-channel Kondo ground state value, S(0)=kBln1S(0) = k_B ln 1S(0)=kB​ln1.
The Kondo problem, which describes the interaction of a spin sss magnetic impurity with a free Fermi gas, is a classic example of strongly coupled physics. Historically, the problem has been solved by Wilson's numerical renormalization group and later by Bethe ansatz. In this paper, we present an alternate analytic solution of the Kondo problem that combines an expansion in 1/s1/s1/s with the renormalization group. We study both the case of an impurity interacting with a single channel K=1K=1K=1 of fermions in the s→∞s \rightarrow \inftys→∞ limit and the case with KKK channels in the double-scaling limit K→∞K \rightarrow \inftyK→∞, s→∞s \to \inftys→∞, K/sK/sK/s fixed. Our approach allows us to describe analytically intermediate scales of the Kondo problem at large sss and compute thermodynamic observables such as the impurity entropy and susceptibility. We find these observables to agree with the Bethe ansatz results. We also compute the impurity spectral function, finite temperature resistivity and the Kondo screening cloud profile, properties that are not easily accessible from Bethe ansatz. Notably, in the regime K>2sK > 2sK>2s we access the "non-Fermi-liquid" overscreened fixed point of the multichannel Kondo problem.
The numerical solution of the Bethe ansatz equations of the n-channel Kondo problem is presented. The thermodynamics of the impurity is obtained as a function of temperature, external field, impurity spin S and the number of channels. Three situations have to be distinguished: (i) If n=2S the conduction electrons exactly compensate the impurity spin into a singlet at low temperatures, (ii) if n<2S the impurity spin is only partially compensated (undercompensated), and (iii) if n>2S the impurity spin is said to be overcompensated giving rise to critical behaviour. The results are briefly discussed in the context of magnetic impurities, the quadrupolar Kondo effect, an impurity spin embedded in the Takhtajan-Babujian model and a two-level system interacting with conduction electrons.
We study triangular clusters of three spin-1/2 Kondo or Anderson impurities that are coupled to two conduction leads. In the case of Kondo impurities, the model takes the form of an antiferromagnetic Heisenberg ring with Kondo-type exchange coupling to continuum electrons. We show that this model exhibits many types of the behavior found in various simpler one- and two-impurity models, thereby enabling the study of crossovers between a number of Fermi-liquid (FL) and non-Fermi-liquid (NFL) fixed points. In particular, we explore a direct crossover between the two-impurity Kondo-model NFL fixed point and the two-channel Kondo-model NFL fixed point. We show that the concept of the two-stage Kondo effect applies even in the case when the first-stage Kondo state is of NFL type. In the case of Anderson impurities, we consider the transport properties of three coupled quantum dots. This class of models includes, as limiting cases, the familiar serial double quantum dot and triple quantum dot nanostructures. By extracting the quasiparticle scattering phase shifts, we compute the low-temperature conductance as a function of the interimpurity tunneling coupling. We point out that due to the existence of exponentially low-temperature scales, there is a parameter range where the stable ``zero-temperature'' fixed point is essentially never reached (not even in numerical renormalization group calculations). The zero-temperature conductance is then of no interest and it may only be meaningful to compute the conductance at finite temperature. This illustrates the perils of studying the conductance in the ground state and considering thermal fluctuations only as a small correction.