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Journal of Physics A Mathematical and General

Fully coupled model versus rotating-wave approximation in the asymptotic time evolution of spin systems

Marcelo A. Despósito, E. Susana Hernández

Published Feb 21, 1995• 6 citations
Publisher

Abstract

In the frame of the generalized master equation (GME) approach, an analysis of the asymptotic spin relaxation is made for different j values. The fully coupled (FC) model and the rotating-wave approximation (RWA) for the system-reservoir coupling are considered and it is seen that they give rise to structurally different GMEs. In particular, we examine the evolution of the diagonal and off-diagonal matrix elements of the density operator, the mean values of the relevant observables and the equilibrium solution for both coupling models and display their significant differences. Particularly the spin j=1 case is examined.

DOI
10.1088/0305-4470/28/4/007

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In the frame of the generalized master equation (GME) approach, an analysis of the asymptotic spin relaxation is made for different j values. The fully coupled (FC) model and the rotating-wave approximation (RWA) for the system-reservoir coupling are considered and it is seen that they give rise to structurally different GMEs. In particular, we examine the evolution of the diagonal and off-diagonal matrix elements of the density operator, the mean values of the relevant observables and the equilibrium solution for both coupling models and display their significant differences. Particularly the spin j=1 case is examined.
A quantum statistical model for the relaxation of two strongly coupled spin 1/2 particles toward thermal equilibrium is formulated microscopically using a master equation. Raman-type dissipation mechanisms are introduced in addition to the usual bilinear coupling between the coupled system and the reservoir. The effects of two different rotating wave approximations to derive the master equation are investigated. Decoherence is considered as a process toward thermal equilibrium for the dissipative system and is studied by observing the phase and energy relaxation.
We study the stochastic dynamics of a two-level quantum system interacting with a stochastic magnetic field, and a single frequency electromagnetic field, with and without making the rotating wave approximation (RWA). The transformation to the rotating frame does not commute with the stochastic Hamiltonian if the stochastic field has nonvanishing components in the transverse direction. Hence, making the RWA modifies the stochastic terms in the Hamiltonian. Modification of the decay terms is also required in a master equation approach (i.e., the Liouville--von Neumann density matrix equation) for describing the dynamics. For isotropic Gaussian white noise, the RWA dynamics remains Markovian, although the Lindblad terms in the master equation for the density matrix become time-dependent when the non-commutation of the RWA transformation and the noise Hamiltonian is properly accounted for. We also treat Ornstein--Uhlenbeck noise, and find, in contra-distinction to the white noise case, a significant difference in the dynamics calculated with the RWA when the non-commutation of the RWA transformation and the noise Hamiltonian is taken into account. These findings are applicable to the modeling of any open quantum system coupled to an electromagentic field.
The time-convolution as well as the time-convolutionless generalized master equations (GME) are rewritten in a simple form permitting an exact formal solution. Using this form, it is argued that possible approximations must be performed consistently on both sides of the GME in order to control deviations of the emerging approximate solution from the exact one. Arguments are given that after such consistent approximations, the initial-condition term can no longer in general be taken as proportional to (scrI-scrD0{\mathit{scrD}}_{0}scrD0​)\ensuremath{\Vert}${\mathrm{\ensuremath{\rho}}}_{0}$) (with scrD0{\mathit{scrD}}_{0}scrD0​ being the projector used in GME). These conclusions are illustrated for the asymptotic-time symmetry-breaking problem of the spin-boson model. Although standard approximate GME approaches do indicate a possible symmetry breaking, we argue that these results are strongly influenced by the inconsistency of the approximations used. To support this statement we prove the absence of any asymptotic-time symmetry breaking in the zero-bias spin-boson model with a partial site-occupation relaxation.
We analyze the irreversible behavior of a quantum harmonic oscillator immersed in an arbitrary thermal reservoir. For the fully coupled (FC) model, i.e., the coupling between subsystems linear in the coordinate of the oscillator, we construct a generalized master equation for the reduced density operator of the oscillator. We apply the rotating-wave approximation (RWA) and investigate its connection with the FC master equation. By means of the Wigner distribution, we obtain the corresponding Fokker-Planck equations in the semiclassical representation. We find that, when the RWA is not imposed, the correct classical limit is obtained (Kramer's equation). Then, we establish the conditions for the equivalence between the FC Fokker-Planck equation and that obtained in the RWA. Quantum maps for a kicked oscillator immersed in a heat bath are obtained in both cases. These maps are studied in the classical and semiclassical limits, and it is shown that they coincide for low kicking frequency compared to the damping rate.
Most traditional discussions of the Markoffian Born approximation of relaxation phenomena (e.g., Bloch equations) are based on the assumption of widely separated time scales in the non-Markoffian weak coupling generalized master equation. By exploiting the physically reasonable Gaussian factorization property of multitime correlation functions which enter through the system reservoir interaction, recent work has shed significant new light on the relationship between the Markoffian-Born approximation and the exact generalized master equation (GME) describing the evolution of the relaxing subsystem. Two limits for which the GME becomes the Born approximation relaxation equation arc discussed: (1) the Van Hove (λ2t) limit rigorously discussed for open systems by Davies, (2) the zero memory (white noise) suggested by Middleton—Schieve and recently discussed for open systems by Gorini—Kossakawsky and Palmer. We have outlined the proof of this limit. We then discuss the physical meaning of these two exact limits in the context of the general theory of kinetic equations of Resibois. The dominant pole contributions are isolated to all orders by means of an expansion in which the terms are in norm proportional to powers of the ratio of the time scales τc/τB where τc is the two point correlation memory time and τB the relaxation time in the Born approximation. Each of the above exact limits corresponds to the vanishing of this ratio. Comments are made on nonexponential decay.