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Journal of Modern Physics

The Quantum Oscillatory Modulated Potential Ⅰ- The Hydrogen Atom

Waldemar Wolney Filho

Published Jan 1, 2012• 0 citations
Publisher

Abstract

In this work we are presenting a modified Coulomb potential function to describe the interaction between two micro-scopic electric charges. In particular, concerning the interaction between the proton and the electron in the hydrogen atom. The modified potential function is the product of the classical Coulomb potential and an oscillatory function dependent on a quantized phase factor. The oscillatory function picks up only selected points along the Coulomb potential, creating potential wells and barriers around the nucleus of the atom. The new potential reveals us new features of the hydrogen atom. Searching for a manner to determine the phase factor, we are using the concept of the de Broglie particle wavelike behavior and the quantum analogue of the virial theorem for describing the bound motion of a particle in a central force field. This procedure is a kind of feedback action, where we are making use of well established concepts of the quantum mechanics aiming to determine the phase factor of the new interaction potential.

DOI
10.4236/jmp.2012.37081

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In this work we are presenting a modified Coulomb potential function to describe the interaction between two micro-scopic electric charges. In particular, concerning the interaction between the proton and the electron in the hydrogen atom. The modified potential function is the product of the classical Coulomb potential and an oscillatory function dependent on a quantized phase factor. The oscillatory function picks up only selected points along the Coulomb potential, creating potential wells and barriers around the nucleus of the atom. The new potential reveals us new features of the hydrogen atom. Searching for a manner to determine the phase factor, we are using the concept of the de Broglie particle wavelike behavior and the quantum analogue of the virial theorem for describing the bound motion of a particle in a central force field. This procedure is a kind of feedback action, where we are making use of well established concepts of the quantum mechanics aiming to determine the phase factor of the new interaction potential.
In this work we are formulating a new theory for describing the waving nature of a microscopic electric particle. Based on the predictions of the Quantum Oscillatory Modulated Potential—QOMP, for describing the interaction between two microscopic electric particles, electron-electron, for instance, we are postulating that the waving behavior of these particles may be an attribute of the charges of the particles and not their masses as currently accepted. For a microscopic electric charge, we are presenting new arguments showing that the electric field in the vicinity of a microscopic charge is spatially waving and can be determined as the gradient per unit of charge of this new quantum interaction potential, with use of an appropriated phase factor to account for the behavior of an unbound electron. Differently of what is predicted by the classical Coulomb electric field, when a charged particle is moving under the action of a potential of V volts, the new electric field existing around the charge has the form of a wave packet. For typical values of the potential V, the wavelength of the waving electric field is in very good agreement with those experimentally observed with diffraction of electrons in crystalline solids.
The purpose of this work is to show the stability of the hydrogen atom with the use the Quantum Oscillatory Modulated Potential and the Heisenberg equations of motion, postulating that the electron in the hydrogen atom is behaving as a quantum harmonic oscillator. With the electron confined between two potential barriers, created by the new potential function, we are considering that at absolute temperature the power absorbed or emitted by the electron per unit of time can be used to determine the zero point energy of the oscillator. Assuming that electron is only exchanging energy with the nucleus of the atom we are making use of the operators of creation and annihilation of a photon to explain how the energy between the proton and the electron can be exchanged to keep the atom a stable system.
de Broglie’s concept of particles as sources of phase is extended to the analysis of systems in which the potential is not constant. The treatment assumes that the phase information propagates as waves according to classical electrodynamics including reflection with phase changes from potential energy barriers. The energies and weighting functions in such cases are obtained by comparison of the phase of the accelerated particle relative to the phases of reflections from the change in potential. Application to the chemically interesting systems of the harmonic oscillator and hydrogen atom are considered using the time evolution of the relative phases of the reflected de Broglie phase waves, whereby the weighting functions are obtained from the distance dependence of the phase differences between the reflections and the source. This is accomplished conveniently by taking time derivatives of the relative de Broglie phases and considering the periodicity of the motion. Optimum trajectories are determined by minimization of the action 2i(mv2-r∂V/∂r)/ħγ which depends on the potential V and the velocity v. The treatment leads to the Newtonian force law for circular orbits and affords the same energies as derived using the Schrödinger equation.
The hydrogen atom with the Coulomb interaction is one of the exactly solvable non-relativistic quantum models. Unlike many other exactly solvable models it describes a real physical object providing the formulas for energy levels and stationary state wave functions of a real hydrogen atom. In this paper we modify the model replacing the Coulomb interaction by the interaction of the proton and the electron with the classical electromagnetic field serving as an intermediary transmitting the electromagnetic interaction of these two charged quantum particles.
Even after nine decades of successful run of the Quantum Mechanics (QM), different viewpoints on foundational problems of Quantum Physics are still being actively debated. That is because mathematical logic of QM often defies the physical intuition which constitutes the main spirit of Physics. De Broglie’s hypothesis of matter waves implied that the dynamic characteristics of a micro particle in motion, can be ascribed to the wave characteristics of the wavelet accompanying the particle. The Schrödinger equation models the matter-wave interactions through wavefunction ψ and effectively serves as the foundation of QM. Even though mathematical structure of the Schrödinger equation is sound and elegant, here we show a conceptual mistake in the development of this equation wherein the physical situation has not been correctly modeled in the equation. The Coulomb potential energy of the proton electron pair in Hydrogen atom is essentially the negative interaction energy between their superposed electrostatic fields which is inversely proportional to their instantaneous separation distance. Assuming the proton to be relatively fixed at the origin of an appropriate coordinate system, the potential energy of the orbiting electron will be a function of instantaneous position coordinates of the electron. This has not been properly modeled in the Schrödinger equation. The resulting errors in the solution have been quantitatively demonstrated in this paper. We have stressed the necessity of incorporating a specific correction in the potential energy term of the Schrödinger equation, after which it may facilitate the adoption of Bohmian QM.
The hydrogen atom has historically played a foundational role in the development of quantum mechanics, where its discrete energy spectrum is conventionally derived from solutions of the Schrödinger wave equation. In this work we present an alternative formulation in which the hydrogen spectrum emerges without invoking the Schrödinger equation. We consider a semi-quantum framework in which the electron is treated as a classical particle governed by Poisson-bracket dynamics while interacting with a quantized electromagnetic field described using second quantization. The electron moves in the Coulomb potential generated by the proton and simultaneously couples to quantized electromagnetic modes through minimal coupling. The Coulomb system possesses a hidden dynamical symmetry characterized by the Runge–Lenz vector, which enlarges the rotational symmetry to an group for bound states. Within this framework, interactions between the classical particle and the quantized field induce an effective commutation structure in the particle’s phase space. Once this structure emerges, the algebra of the conserved quantities associated with the Runge–Lenz vector becomes identical to the operator algebra used in Pauli’s symmetry-based derivation of the hydrogen spectrum. Consequently, the discrete hydrogen energy levels arise naturally from the combined effects of Coulomb symmetry and particle–field interaction, offering a physically transparent interpretation of atomic quantization and suggesting that wave–particle duality may arise dynamically from interactions with quantized electromagnetic fields.